Plasma Surface Modification With Humidity Control for Substrate Bonding

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Solution Overview

Problem

The decrease in bonding strength between substrates due to the gradual reduction of moisture in the processing vessel during surface modification processes, leading to inadequate plasma state changes and potential delamination issues.

Innovation Solution

A surface modifying method that adjusts the moisture level in the processing vessel by supplying a humidified gas, ensuring the plasma state is maintained optimally during the modification of bonding surfaces, thereby suppressing the decrease in bonding strength between substrates.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Strength

If surface modification is performed by plasma in a processing vessel, then substrate bonding strength is improved through hydrophilization, but moisture in the processing vessel gradually reduces leading to decreased bonding strength

Engineering Contradiction:
Improvebonding strengthVSAvoidmoisture amount
Core Design Contradiction:
StrengthVSQuantity of substance

Solution Approach 1:

The patent applies preliminary action by adjusting the moisture content in the processing vessel before performing plasma surface modification. By pre-establishing the appropriate moisture environment, the method ensures optimal bonding strength is achieved during the subsequent plasma treatment, preventing the gradual reduction of bonding strength that occurs when moisture is not properly controlled from the outset.

Inventive Principle:
Principle #10Preliminary action

Solution Approach 2:

The patent implements parameter changes by actively controlling and adjusting the moisture content parameter in the processing vessel during plasma surface modification. This involves monitoring and regulating the water vapor concentration to maintain it within a specific range, thereby optimizing the plasma treatment conditions and ensuring consistent bonding strength throughout the process.

Inventive Principle:
Principle #35Parameter changes

2Stability of the object's composition

If plasma processing gas is used for surface modification, then substrate surfaces are hydrophilized, but nitridated portions form on substrate surfaces reducing bonding quality

Engineering Contradiction:
Improvesurface hydrophilicityVSAvoidnitridated portions
Core Design Contradiction:
Stability of the object's compositionVSObject-generated harmful factors

Solution Approach 1:

The patent applies parameter changes by controlling the moisture content parameter to suppress the formation of nitridated portions on substrate surfaces. By adjusting the water vapor concentration in the processing vessel during plasma treatment, the method modifies the chemical environment to favor hydrophilization while minimizing unwanted nitrogen incorporation into the substrate surface.

Inventive Principle:
Principle #35Parameter changes

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

This approach effectively maintains the bonding strength by reducing the formation of nitridated portions on the substrate surfaces, allowing for stable hydrogen bonding and van der Waals forces, thus preventing delamination and ensuring robust substrate bonding.

Implementation Method 1

modifies the surface of the accommodated substrate with plasma of a processing gas

Methodology Applied
Scientific EffectPlasma: Plasma

Implementation Method 2

supplying a humidified gas into the processing vessel

Methodology Applied
Scientific EffectEvaporation: Evaporation

Implementation Method 3

the modified surfaces of the substrates are hydrophilized, and the hydrophilized substrates are bonded by a Van der Waals force and a hydrogen bond

Methodology Applied
Scientific EffectVan der Waals force: Van der Waals Force

Implementation Method 4

the hydrophilized substrates are bonded by a Van der Waals force and a hydrogen bond

Methodology Applied
Scientific EffectHydrogen bond: Chemical Bonding

Data Source

PatentUS20240079214A1Surface modifying method and surface modifying apparatus
Publication Date: 2024.03.07 TOKYO ELECTRON LTD
  • US20240079214A1 patent drawing
  • US20240079214A1 patent drawing
  • US20240079214A1 patent drawing

AI summary

A surface modifying method of modifying a bonding surface of a substrate to be bonded to another substrate by plasma of a processing gas includes an adjusting process and a modifying process. In the adjusting process, an amount of moisture in a processing vessel is adjusted by supplying a humidified gas into the processing vessel allowed to accommodate the substrate therein. In the modifying process, the bonding surface of the substrate is modified by forming the plasma of the processing gas in the processing vessel in a state that the amount of moisture in the processing vessel is adjusted.