Atmospheric Plasma Jet Deposition for 3D Printed Electronics

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Solution Overview

Problem

Current metallization techniques for 3D interconnects and flexible electronics are substrate-dependent, requiring multiple processes for different materials and applications, and lack the ability to tailor physical, chemical, and electronic properties, especially for low glass transition temperature plastics and porous structures needed for high throughput processing.

Innovation Solution

A substrate-independent atmospheric pressure plasma jet deposition process that uses an aerosol containing conducting materials, delivered through nozzles connected to a high voltage power supply, allowing for in situ control of morphological and chemical modification of materials during and after deposition, enabling tailored physical, chemical, and mechanical characteristics.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Adaptability or versatility

If conventional metallization techniques are used, then deposition on specific substrates is achieved, but the process is substrate-dependent and requires multiple different processes for different materials

Engineering Contradiction:
Improvesubstrate compatibilityVSAvoidnumber of processes
Core Design Contradiction:
Adaptability or versatilityVSDevice complexity

Solution Approach 1:

The plasma jet deposition process is designed to work with multiple substrate types (flexible plastics, low glass transition temperature materials, porous structures) using a single unified process, eliminating the need for multiple specialized deposition techniques for different substrates

Inventive Principle:
Principle #6Universality (Multi-functionality)

Solution Approach 2:

The process enables in situ control of deposition parameters including morphology, porosity, and oxidation state through plasma process parameters, allowing the same deposition process to produce different material properties for different applications without changing the fundamental process

Inventive Principle:
Principle #35Parameter changes

2Manufacturing precision

If inkjet printing with copper nanoparticles is used, then conductive patterns are printed, but post deposition annealing is required which limits low glass transition temperature plastics and adds processing steps

Engineering Contradiction:
Improveconductive pattern qualityVSAvoidprocessing steps
Core Design Contradiction:
Manufacturing precisionVSDevice complexity

Solution Approach 1:

The plasma jet deposition process combines material deposition and post-deposition treatment (annealing, oxidation control) into a single integrated process step, eliminating the need for separate post-deposition annealing that would be required by inkjet printing methods

Inventive Principle:
Principle #5Merging (Combining)

Solution Approach 2:

The plasma process enables control of material properties through plasma parameters rather than thermal annealing, allowing deposition on low glass transition temperature plastics that would be damaged by high-temperature post-deposition treatment

Inventive Principle:
Principle #35Parameter changes

3Ease of manufacture

If screen printing is used, then planar objects are printed, but resolution is limited and organic contaminants are present requiring post print thermal treatment

Engineering Contradiction:
Improveplanar printing capabilityVSAvoidresolution
Core Design Contradiction:
Ease of manufactureVSManufacturing precision

Solution Approach 1:

The plasma jet deposition process replaces the mechanical screen printing method with a plasma-based deposition process, enabling higher resolution patterns without the limitations of screen mesh geometry and eliminating organic contaminants from screen printing materials

Inventive Principle:
Principle #28Mechanics substitution (Replace mechanical system)

4Productivity

If thermal spray is used, then industrial coating is achieved, but high oxygen concentration and high porosity result in difficulty controlling microstructure

Engineering Contradiction:
Improveindustrial coating capabilityVSAvoidmicrostructure control
Core Design Contradiction:
ProductivityVSManufacturing precision

Solution Approach 1:

The plasma jet deposition process enables precise control of microstructure parameters including porosity and oxidation state through adjustment of plasma process parameters, overcoming the inability of thermal spray to control microstructure despite its high productivity

Inventive Principle:
Principle #35Parameter changes

5Manufacturing precision

If thermal annealing is used for copper oxidation, then oxide derived nano crystalline copper surface is achieved, but additional processing steps are required

Engineering Contradiction:
Improvesurface morphologyVSAvoidprocessing steps
Core Design Contradiction:
Manufacturing precisionVSDevice complexity

Solution Approach 1:

The plasma jet deposition process combines copper deposition and oxidation into a single process step by controlling the plasma chemistry, eliminating the need for separate thermal annealing steps required to create oxide-derived nano crystalline copper surfaces

Inventive Principle:
Principle #5Merging (Combining)

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

This process allows for the deposition of conducting materials with tailored properties on various substrates, including flexible electronics and 3D printed components, enhancing interconnect performance and electrocatalysis efficiency by controlling morphology, porosity, and oxidation state, while reducing the need for additional post-processing steps.

Implementation Method 1

A substrate-independent atmospheric pressure plasma jet deposition process that uses an aerosol containing conducting materials, delivered through nozzles connected to a high voltage power supply

Methodology Applied
Scientific EffectPlasma deposition: Plasma Enhanced Chemical Vapour Deposition

Implementation Method 2

allowing for in situ control of morphological and chemical modification of materials during and after deposition

Methodology Applied
Scientific EffectPlasma treatment: Plasma

Data Source

PatentUS11773491B2In situ tailoring of material properties in 3D printed electronics
Publication Date: 2023.10.03 UNIVERSITIES SPACE RES ASSOC
  • US11773491B2 patent drawing
  • US11773491B2 patent drawing
  • US11773491B2 patent drawing

AI summary

Systems and methods for highly reproducible and focused plasma jet printing and patterning of materials using appropriate ink containing aerosol through nozzles with narrow orifice and tubes with controlled dielectric constant connected to high voltage power supply, in the presence of electric field and plasma, that enables morphological and/or bulk chemical modification and/or surface chemical modification of the material in the aerosol and/or the substrate prior to printing, during printing and post printing.