Plasma Oxidized Transition Metal Oxide Memory Cell

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Solution Overview

Problem

Conventional resistance memory cells using materials like PrCaMnO, nickel oxide, or titanium oxide face challenges with complex processes, high deposition temperatures, high switching voltages, and short data retention times.

Innovation Solution

A memory cell with a transition metal oxide layer formed through a plasma oxidation step, which reduces switching voltage and enhances data retention time, while maintaining high product quality and reducing manufacturing costs.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If conventional materials like PrCaMnO, nickel oxide, or titanium oxide are used for the data storage layer, then the memory cell can store data, but the deposition temperature is high (approximately 300°C) and the process is complicated

Engineering Contradiction:
Improvedata storage capabilityVSAvoiddeposition temperature
Core Design Contradiction:
ReliabilityVSTemperature

Solution Approach 1:

The patent changes the material parameter from conventional oxide materials to transition metal materials (Ti, Co, Ni, Cu, Zn) that can form oxide layers through plasma oxidation. This parameter change enables the data storage layer to be formed at lower temperatures while maintaining data storage capability, directly resolving the contradiction between reliability and deposition temperature

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent replaces the conventional thermal deposition process with a plasma oxidation process. Instead of directly depositing oxide materials at high temperatures, the method uses plasma treatment to oxidize transition metal layers in situ, substituting a chemical plasma-based process for the traditional thermal mechanical deposition process, thereby reducing the required deposition temperature

Inventive Principle:
Principle #28Mechanics substitution (Replace mechanical system)

2Reliability

If conventional materials like_prCaMnO, nickel oxide, or titanium oxide are used for the data storage layer, then the memory cell can store data, but the switching voltage is high (approximately 10V)

Engineering Contradiction:
Improvedata storage capabilityVSAvoidswitching voltage
Core Design Contradiction:
ReliabilityVSUse of energy by moving object

Solution Approach 1:

The patent changes the material composition parameter to transition metal oxide layers formed through plasma oxidation, which exhibit different electrical properties compared to conventional oxide materials. This material parameter change results in lower switching voltage requirements (reducing from approximately 10V to lower values), thereby resolving the contradiction between data storage capability and energy consumption

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent employs composite structure consisting of transition metal layer and its oxide layer formed through plasma oxidation. This composite material system combines the advantages of both metallic and oxide phases, enabling efficient data storage with reduced switching voltage, thus resolving the contradiction between reliability and energy use

Inventive Principle:
Principle #40Composite materials

3Reliability

If conventional materials like_prCaMnO, nickel oxide, or titanium oxide are used for the data storage layer, then the memory cell can store data, but the data retention time is short

Engineering Contradiction:
Improvedata storage capabilityVSAvoiddata retention time
Core Design Contradiction:
ReliabilityVSDuration of action of stationary object

Solution Approach 1:

The patent changes the material parameter from conventional oxide materials to plasma-formed transition metal oxide layers, which exhibit enhanced stability and longer data retention characteristics. This material parameter modification directly addresses the contradiction by improving data retention time while preserving data storage capability

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent replaces conventional deposition-based oxide layer formation with plasma oxidation processing. This process substitution creates oxide layers with superior structural and electrical properties that contribute to extended data retention time, thereby resolving the contradiction between data storage capability and data retention duration

Inventive Principle:
Principle #28Mechanics substitution (Replace mechanical system)

4Reliability

If conventional materials like_prCaMnO, nickel oxide, or titanium oxide are used for the data storage layer, then the memory cell can store data, but the process is complicated and development cost is high

Engineering Contradiction:
Improvedata storage capabilityVSAvoidmanufacturing process complexity
Core Design Contradiction:
ReliabilityVSDevice complexity

Solution Approach 1:

The patent replaces the complex multi-step conventional deposition process with a simplified plasma oxidation process. This process substitution eliminates the need for separate oxide material deposition steps, reducing manufacturing process complexity while maintaining data storage capability

Inventive Principle:
Principle #28Mechanics substitution (Replace mechanical system)

Solution Approach 2:

The patent employs a self-service approach where the transition metal layer serves as the precursor material that is oxidized in situ through plasma treatment. This eliminates the need for separate oxide material deposition processes, simplifying the manufacturing process and reducing development costs while preserving data storage functionality

Inventive Principle:
Principle #25Self-service

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The plasma oxidation process lowers the switching voltage to approximately 1.5V, increases data retention time, and improves conductivity, resulting in a more stable and cost-effective memory cell production.

Implementation Method 1

a plasma oxidation step is performed to the transition metal layer to form a transition metal oxide layer

Methodology Applied
Scientific EffectPlasma oxidation: Oxidation

Data Source

PatentUS8722469B2Memory cell and process for manufacturing the same
Publication Date: 2014.05.13 MACRONIX INTERNATIONAL CO LTD
  • US8722469B2 patent drawing
  • US8722469B2 patent drawing
  • US8722469B2 patent drawing

AI summary

A memory cell and a process for manufacturing the same are provided. In the process, a first electrode layer is formed on a conductive layer over a substrate, and then a transition metal layer is formed on the first electrode layer. After that, the transition metal layer is subjected to a plasma oxidation step to form a transition metal oxide layer as a precursor of a data storage layer, and a second electrode layer is formed on the transition metal oxide layer. A memory cell is formed after the second electrode layer, the transition metal oxide layer and the first electrode layer are patterned into a second electrode, a data storage layer and a first electrode, respectively.