Plasma-Enhanced Poly(p-xylylene) Deposition for Uniform Coating

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Solution Overview

Problem

Existing methods for applying poly(p-xylylene) films to components with complex geometries face challenges in achieving uniform coatings due to dust formation and inefficiencies in material deposition, leading to defects and increased downtime for chamber cleaning.

Innovation Solution

An apparatus utilizing a radio-frequency electrical power supply, a deposition chamber with a conductive platen, and controlled heating elements to generate a plasma that ionizes and activates poly(p-xylylene) monomers, allowing for uniform deposition on conductive and insulating components with complex shapes while minimizing monomer deposition on chamber walls.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Manufacturing precision

If carrier gases are used to improve coating uniformity, then coating uniformity is improved, but dust formation increases leading to defects

Engineering Contradiction:
Improvecoating uniformityVSAvoiddust formation
Core Design Contradiction:
Manufacturing precisionVSObject-affected harmful factors

Solution Approach 1:

The patent changes the physical and chemical parameters of the deposition environment by introducing a plasma field (electrical parameter) and controlling monomer concentration and temperature. This transforms the deposition mechanism from simple physical vapor deposition to plasma-enhanced chemical vapor deposition, achieving uniform coating without carrier gases and thus avoiding dust formation

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent replaces the mechanical/physical method of using carrier gases to transport and distribute monomers with a plasma-based activation method. The plasma field directly activates monomers and drives their deposition, eliminating the need for carrier gases and the associated dust formation problem

Inventive Principle:
Principle #28Mechanics substitution (Replace mechanical system)

2Loss of substance

If monomer is deposited on chamber walls, then material waste increases and cleaning downtime increases, but this is an unavoidable side effect of the deposition process

Engineering Contradiction:
Improvemonomer wasteVSAvoidcleaning downtime
Core Design Contradiction:
Loss of substanceVSLoss of time

Solution Approach 1:

The patent applies local quality by creating a non-uniform plasma field and monomer distribution that is concentrated around the component surface. The plasma activation and monomer deposition are localized to the component vicinity, reducing stray deposition on chamber walls and minimizing material waste and cleaning requirements

Inventive Principle:
Principle #3Local quality

Solution Approach 2:

The component itself serves as the target that defines the deposition zone. By using the component's geometry and position to guide plasma and monomer distribution, the system naturally directs material where needed (on the component) and away from where it is not needed (chamber walls), reducing waste without additional active control

Inventive Principle:
Principle #25Self-service

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The solution enables efficient, uniform coating of complex components with reduced dust formation and increased deposition speed, minimizing material waste and downtime for chamber cleaning.

Implementation Method 1

the electrical power supply is configured to apply electrical power to the electrically conductive component supported by the platen at a power of between 0.0001 Watts/cm2 and 10 Watt/cm2 such that a plasma is generated that surrounds the component and ionizes and/or activates the poly(p-xylylene) monomer

Methodology Applied
Scientific EffectPlasma: Plasma

Implementation Method 2

a plasma is generated that surrounds the component and ionizes and/or activates the poly(p-xylylene) monomer

Methodology Applied
Scientific EffectIonization: Ionisation

Implementation Method 3

a pyrolysis oven, comprising a first heating element configured to heat the pyrolysis oven to a first elevated temperature sufficient to cause pyrolysis of a poly(p-xylylene) dimer

Methodology Applied
Scientific EffectPyrolysis: Pyrolysis

Implementation Method 4

a vaporiser oven, comprising a second heating element configured to heat the vaporiser oven to a second elevated temperature sufficient to cause evaporation of the poly(p-xylylene) dimer

Methodology Applied
Scientific EffectEvaporation: Evaporation

Implementation Method 5

Poly(p-xylylene) polymer deposition takes place inside a vacuum chamber, where the components to be coated are placed. For this, the chamber is evacuated

Methodology Applied
Scientific EffectVacuum: Vacuum

Data Source

PatentEP3774077B1Apparatus and method for depositing a poly(p-xylylene) film on a component
Publication Date: 2023.06.07 AIRBUS DEFENCE & SPACE GMBH
  • EP3774077B1 patent drawingFigure 1~2
  • EP3774077B1 patent drawingFigure 3~4
  • EP3774077B1 patent drawingFigure 5

AI summary

The disclosure provides an apparatus (2) for depositing poly(p- xylylene) onto a component (4). The apparatus comprises (i) a platen (20), (ii) an electrode (10), and (iii) a first feed means (16). The platen comprises an electrically conductive material, is electrically connected to an electrical power supply (24) and is configured to support a component. The electrode is electrically insulated from the platen. The first feed means is configured to feed a poly(p- xylylene) monomer to the platen. Furthermore, the component either comprises an electrically conductive material or consists of an electrically insulating material. If the component consists of an electrically insulating material the electrical power supply is an alternating current (AC) power supply and generated an alternating electrical field which couples to the component, and is thereby able to penetrate through the component to create the plasma.