Plasma Probe for Neutral Radical Diagnostics

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Solution Overview

Problem

Current plasma diagnostics tools cannot measure the type, density, and energy of neutral radicals effectively, which is crucial for controlling reactions in plasma processes like semiconductor processing and thin film synthesis, where ion bombardment leads to defects.

Innovation Solution

A portable plasma probe with a transparent dielectric sleeve and a biased metallic rod, combined with an insulated thermocouple junction, allows for in-situ diagnostics of neutral radicals by measuring equilibrium temperature and analyzing optical emission spectra and electron energy distribution.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Measurement precision

If market-available plasma diagnostics tools (OES and QMS) are used, then some plasma parameters can be measured, but they are not capable of measuring all three parameters (type, density, and energy) of neutral radicals simultaneously

Engineering Contradiction:
Improvemeasurement capability of neutral radicalsVSAvoiddiagnostics system complexity
Core Design Contradiction:
Measurement precisionVSDevice complexity

Solution Approach 1:

The patent combines multiple diagnostic functions (optical emission spectroscopy, electron energy distribution measurement, and temperature measurement via thermocouple) into a single integrated probe. This allows simultaneous measurement of neutral radical type, density, and energy that would otherwise require separate instruments, resolving the contradiction between measurement capability and device complexity.

Inventive Principle:
Principle #5Merging (Combining)

Solution Approach 2:

The probe is designed as a multi-functional diagnostic tool that can measure multiple plasma parameters (optical emission spectra, electron energy distribution, and temperature) simultaneously through a single device. This universal approach enables comprehensive neutral radical characterization without requiring multiple specialized instruments.

Inventive Principle:
Principle #6Universality (Multi-functionality)

2Productivity

If ion bombardment is used in plasma processes, then plasma processing can be performed, but high density of defects (dangling bonds, micro-defects) are formed on the surface and in the bulk of processing pieces

Engineering Contradiction:
Improveplasma processing efficiencyVSAvoiddefect density in processing pieces
Core Design Contradiction:
ProductivityVSObject-affected harmful factors

Solution Approach 1:

The diagnostic probe provides real-time feedback on plasma parameters (neutral radical type, density, and energy) during processing. This enables deterministic control of plasma conditions to optimize the balance between processing efficiency and defect reduction by adjusting plasma parameters based on measured neutral radical characteristics.

Inventive Principle:
Principle #23Feedback

Solution Approach 2:

By measuring and controlling plasma parameters (particularly neutral radical energy and density) through the diagnostic probe, the system can adjust processing conditions to reduce ion bombardment damage while maintaining processing productivity. This involves optimizing plasma power, pressure, and gas flow based on real-time diagnostics.

Inventive Principle:
Principle #35Parameter changes

3Manufacturing precision

If deterministic control of reactions involving neutral radicals is achieved, then plasma processing quality improves, but accurate measurement of type, density, and energy of neutral radicals is required which current tools cannot provide

Engineering Contradiction:
Improveplasma processing control accuracyVSAvoidneutral radical parameter measurement capability
Core Design Contradiction:
Manufacturing precisionVSMeasurement precision

Solution Approach 1:

The probe integrates multiple measurement capabilities (optical emission spectroscopy for radical type and density, electron energy distribution measurement, and thermocouple-based temperature measurement) into a single instrument. This provides comprehensive neutral radical characterization data necessary for deterministic control of plasma reactions.

Inventive Principle:
Principle #5Merging (Combining)

Solution Approach 2:

The probe acts as an intermediary diagnostic tool that indirectly measures neutral radical parameters through related measurements (optical emission spectra, electron energy distribution) and uses these to infer neutral radical type, density, and energy, enabling deterministic control without direct neutral radical detection.

Inventive Principle:
Principle #24Intermediary (Mediator)

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

Enables one-step determination of the type, density, and energy of neutral radicals, facilitating deterministic control of soft plasma processing and improving the quality of plasma-based manufacturing by reducing defects.

Implementation Method 1

a transparent dielectric sleeve made of large bandgap material, such as quartz, for transmission of light from plasma

Methodology Applied
Scientific EffectLight transmission through dielectric material: Refraction

Implementation Method 2

an insulated thermocouple junction capsulated inside the metallic rod for measurement of equilibrium temperature of the probe

Methodology Applied
Scientific EffectThermal conduction: Conduction (thermal)

Implementation Method 3

a metallic rod, such as a tungsten rod, biased by alternating current (AC) voltage for diagnostics of electron energy distribution and control of the ion and electron heating in plasma

Methodology Applied
Scientific EffectJoule heating: Joule Heating

Implementation Method 4

neutral radicals can be characterized qualitatively and quantitatively through analysis of electron impact excitation of neutral radicals from the measured optical mission spectra

Methodology Applied
Scientific EffectElectron impact excitation: Photoionisation

Data Source

PatentUS9930766B2Apparatus and method for determining the type, density and temperature of neutral radicals in plasma
Publication Date: 2018.03.27 NANYANG TECH UNIV
  • US9930766B2 patent drawing
  • US9930766B2 patent drawing
  • US9930766B2 patent drawing

AI summary

An apparatus for diagnostics of neutral radicals in plasma, the apparatus comprising: a portable probe configured to be attached to and extend into a plasma chamber to obtain information from plasma contained in the plasma chamber, the probe comprising a metallic rod configured to be biased with an alternating current voltage applied to the probe to obtain current measurements; a transparent dielectric sleeve having a large bandgap configured to allow light transmission to obtain optical emission spectra from the plasma; and an insulated thermocouple junction provided in the metallic rod, the thermocouple junction configured to measure equilibrium temperature of the probe.