Plasma Reactor Converts Methane to Aromatics

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Solution Overview

Problem

The transportation of methane from remote locations is challenging without direct pipeline access, often leading to feedstock misutilization through gas flaring and venting, necessitating improved methods for on-site conversion to condensable and transportable liquids like olefins and aromatics.

Innovation Solution

A system and method involving a reactor with a catalyst bed, inner and outer electrodes, and temperature regulation to generate a plasma in a reaction zone, processing methane gas streams and producing aromatic compounds by contacting the gas with a catalyst material and applying a voltage to create a non-thermal plasma.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Quantity of substance

If methane is transported from remote locations without pipeline access, then feedstock availability is improved, but transportation difficulty increases and leads to gas flaring and venting

Engineering Contradiction:
Improvemethane feedstock availabilityVSAvoidtransportation difficulty
Core Design Contradiction:
Quantity of substanceVSEase of operation

Solution Approach 1:

The patent replaces the mechanical/physical transportation system with a chemical conversion system. Instead of transporting methane gas through pipelines or other mechanical means, the invention converts methane chemically into liquid aromatic compounds (benzene, toluene, xylene) that can be easily transported and stored. This substitution of transportation method with chemical transformation resolves the contradiction between feedstock availability and transportation difficulty

Inventive Principle:
Principle #28Mechanics substitution (Replace mechanical system)

Solution Approach 2:

The patent changes the physical and chemical parameters of methane through plasma-assisted catalytic conversion. By applying plasma energy and catalysts, methane molecules are transformed into different chemical compounds with different physical properties (from gas to liquid, different molecular structure). This parameter change enables the feedstock to become transportable without requiring pipeline infrastructure

Inventive Principle:
Principle #35Parameter changes

2Productivity

If conventional thermal processes are used for methane conversion, then conversion capability is improved, but energy consumption increases and temperature control becomes difficult

Engineering Contradiction:
Improvemethane conversion capabilityVSAvoidenergy consumption
Core Design Contradiction:
ProductivityVSUse of energy by moving object

Solution Approach 1:

The patent substitutes conventional high-temperature thermal processes with plasma-based conversion. Instead of using large amounts of thermal energy to break methane bonds, the invention uses plasma (ionized gas with high-energy electrons) to directly activate and convert methane molecules at lower bulk temperatures. This substitution dramatically reduces energy consumption while maintaining high conversion capability

Inventive Principle:
Principle #28Mechanics substitution (Replace mechanical system)

Solution Approach 2:

The patent changes the energy delivery mechanism from thermal heating to plasma excitation. By introducing plasma as the energy carrier, the system achieves methane activation through electron impact and radical reactions rather than bulk thermal heating. This parameter change in energy delivery method enables efficient conversion with lower overall energy input and better temperature control

Inventive Principle:
Principle #35Parameter changes

3Productivity

If plasma is generated in the reaction zone, then methane conversion efficiency is improved, but system complexity increases

Engineering Contradiction:
Improvemethane conversion efficiencyVSAvoidsystem complexity
Core Design Contradiction:
ProductivityVSDevice complexity

Solution Approach 1:

The patent designs the plasma reactor to serve multiple functions simultaneously: plasma generation for methane activation, catalyst support for selective conversion, and reaction zone for product formation. The reactor structure integrates these functions in a single device, avoiding the need for separate plasma generation equipment, catalyst reactors, and product separation systems. This multi-functionality reduces overall system complexity while maintaining high conversion efficiency

Inventive Principle:
Principle #6Universality (Multi-functionality)

Solution Approach 2:

The patent introduces a catalyst as an intermediary substance that mediates between plasma and methane. The catalyst absorbs plasma energy and transfers it to methane molecules, facilitating conversion. This intermediary role simplifies the direct plasma-methane interaction and enables selective production of desired aromatic products, reducing the complexity of controlling plasma reactions

Inventive Principle:
Principle #24Intermediary (Mediator)

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

This approach effectively converts methane into condensable aromatic compounds, addressing the challenge of methane utilization and transportation by generating valuable products while reducing flaring and venting.

Implementation Method 1

providing a voltage to an inner electrode disposed within the reaction zone, thereby generating a plasma in the reaction zone across a discharge gap

Methodology Applied
Scientific EffectPlasma: Plasma

Implementation Method 2

contacting the gas stream with a catalyst material in a reaction zone of the reactor

Methodology Applied
Scientific EffectCatalysis: Catalysis

Implementation Method 3

maintaining a temperature in the reaction zone of no less than 300° C. and no greater than 700° C.

Methodology Applied
Scientific EffectThermal heating: Heating

Data Source

PatentUS20240010582A1Systems and Methods for Processing Gas Streams
Publication Date: 2024.01.11 UNIV OF NOTRE DAME DU LAC
  • US20240010582A1 patent drawing
  • US20240010582A1 patent drawing
  • US20240010582A1 patent drawing

AI summary

Exemplary systems and methods process gas streams comprising methane. Exemplary reactors receive a gas stream and comprise catalyst material in a reaction zone. Non-thermal plasma may be generated in the reaction zone. A temperature of the reaction zone may be maintained within a predetermined temperature range. Products may be collected from a reactor outlet.