Thermal Plasma Calcination of Shell Powder for Antibacterial Resins

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Solution Overview

Problem

Current methods for producing fine-particle powders of calcium oxide or calcium hydroxide with high antibacterial activity are limited by large particle sizes, high production costs, and the need for wet slurry processes, which affect the transparency and strength of resin products and require additional steps like drying and waste liquid treatment.

Innovation Solution

A method involving the thermal plasma treatment of pulverized shell or eggshell powders to produce fine particles with sizes ranging from 5 nm to 300 nm, eliminating the need for solutions and simplifying the production process, allowing for high-temperature calcination in a short time without using a slurry or solution.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If conventional high-temperature sintering at 700-1000°C for several hours is used to produce calcined shell powder with antibacterial activity, then the antibacterial effect is achieved, but the production time is long and energy consumption is high

Engineering Contradiction:
Improveantibacterial effectVSAvoidproduction time
Core Design Contradiction:
ReliabilityVSLoss of time

Solution Approach 1:

The invention uses plasma phase transition technology to convert calcium carbonate shell powder directly into calcium oxide fine particles through plasma-induced decomposition, bypassing the conventional slow sintering process. The plasma provides intense energy to achieve rapid phase transformation from CaCO3 to CaO, reducing production time from several hours to minutes while maintaining antibacterial activity

Inventive Principle:
Principle #36Phase transitions

Solution Approach 2:

The invention changes the fundamental processing parameters from conventional thermal sintering (700-1000°C for hours) to plasma treatment (high-energy particle bombardment for minutes). This parameter change enables rapid calcination with much shorter processing time while achieving the same or better antibacterial effect through plasma-generated reactive species and localized high-energy zones

Inventive Principle:
Principle #35Parameter changes

2Reliability

If the particle size of antibacterial material is decreased to enhance antibacterial effect, then the antibacterial activity increases, but the production cost increases and transparency requirements become more difficult to meet

Engineering Contradiction:
Improveantibacterial activityVSAvoidproduction cost
Core Design Contradiction:
ReliabilityVSEase of manufacture

Solution Approach 1:

The invention replaces conventional mechanical ball milling or jet milling methods with plasma-based particle size reduction. Plasma provides direct energy to particles for fragmentation and size reduction without requiring extensive mechanical processing, achieving fine particle sizes (sub-micron to nanometer range) more efficiently and cost-effectively while maintaining particle morphology suitable for transparency applications

Inventive Principle:
Principle #28Mechanics substitution (Replace mechanical system)

3Manufacturing precision

If wet slurry process is used to produce fine-particle powder, then the particle size can be controlled, but additional steps like drying and waste liquid treatment are required

Engineering Contradiction:
Improveparticle size controlVSAvoidprocess steps
Core Design Contradiction:
Manufacturing precisionVSDevice complexity

Solution Approach 1:

The invention extracts and eliminates the liquid slurry medium from the processing system entirely. By using dry plasma treatment, the process directly treats solid shell powder without requiring water or other liquids, thereby removing the need for drying steps and waste liquid treatment while still achieving precise particle size control through plasma parameter optimization

Inventive Principle:
Principle #2Taking out (Extraction)

Solution Approach 2:

The plasma process inherently provides both particle size reduction and surface activation/functionalization in a single step without requiring separate processing stages. The reactive plasma species simultaneously fragment particles and modify surfaces, achieving multiple objectives (size control, antibacterial enhancement, surface activation) without additional process steps

Inventive Principle:
Principle #25Self-service

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

This method effectively produces fine-particle powders with high antibacterial activity, reducing production costs and simplifying material treatment, while maintaining transparency and enhancing the antibacterial effect in resin products.

Implementation Method 1

introducing the pulverized powder of shells or eggshells into a controlled atmosphere, vaporizing the pulverized powder under thermal plasma and then solidifying the pulverized powder in a gas phase

Methodology Applied
Scientific EffectThermal plasma: Plasma

Implementation Method 2

vaporizing the pulverized powder under thermal plasma and then solidifying the pulverized powder in a gas phase

Methodology Applied
Scientific EffectGas phase solidification: Condensation

Data Source

PatentUS20230331573A1Fine-particle powder containing calcium oxide or calcium hydroxide and production method for same
Publication Date: 2023.10.19 PANASONIC INTELLECTUAL PROPERTY MANAGEMENT CO LTD
  • US20230331573A1 patent drawing
  • US20230331573A1 patent drawing
  • US20230331573A1 patent drawing

AI summary

A method for producing a fine-particle powder containing calcium oxide or calcium hydroxide includes: preparing a pulverized powder of shells or eggshells; introducing the pulverized powder of shells or eggshells into a controlled atmosphere, vaporizing the pulverized powder under thermal plasma and then solidifying the pulverized powder in a gas phase to produce fine particles containing calcium oxide or calcium hydroxide; and collecting a powder of the fine particles containing calcium oxide or calcium hydroxide produced with the thermal plasma.