Plasma-Sprayed Catalyst Particulates for Rocket Propulsion

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Solution Overview

Problem

Traditional rocket propulsion systems face challenges in increasing specific impulse (Isp) and safety due to the use of toxic propellants like hydrazine, which require costly and hazardous handling, and have limitations in thrust efficiency and catalyst life.

Innovation Solution

Introducing a flow of catalyst particulates into a plasma flow field and reacting them with a propellant within the plasma flow field to enhance specific impulse, using low-concentration hydrogen peroxide and silver catalysts, and employing a plasma sprayer to deliver catalysts into the reaction chamber, where they mix with the propellant in a supersonic plasma stream to improve decomposition efficiency.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Productivity

If traditional catalyst-activated propulsion systems use fixed catalyst screens, then the system structure is simple, but the specific impulse is limited and catalyst life is short due to slow consumption and erosion

Engineering Contradiction:
Improvespecific impulseVSAvoidcatalyst life
Core Design Contradiction:
ProductivityVSDuration of action of stationary object

Solution Approach 1:

The patent transitions from a static fixed catalyst screen to a dynamic system where catalyst particles are continuously injected into the plasma flow. This dynamic approach allows fresh catalyst to be supplied continuously, maintaining high reactivity throughout operation and extending effective catalyst life while improving specific impulse through optimized catalyst-plasma interaction.

Inventive Principle:
Principle #15Dynamics

Solution Approach 2:

The patent changes the physical state and delivery method of the catalyst from a fixed solid screen to injected particles in a plasma flow. This parameter change enables better catalyst utilization, higher surface area exposure to propellant, and improved specific impulse while allowing for continuous replenishment to extend operational life.

Inventive Principle:
Principle #35Parameter changes

2Power

If high concentration hydrogen peroxide (over 80%) is used to achieve adequate thruster performance, then the heat of decomposition increases, but the risk of explosive decomposition becomes very hazardous

Engineering Contradiction:
Improveheat of decompositionVSAvoidexplosive decomposition hazard
Core Design Contradiction:
PowerVSObject-affected harmful factors

Solution Approach 1:

The patent introduces plasma as an intermediary energy source to initiate and sustain the decomposition of hydrogen peroxide. Instead of relying solely on the propellant's chemical energy (which requires high concentration and poses explosion risks), the plasma provides controlled energy input that enables safe decomposition of lower concentration peroxide while achieving adequate thrust performance.

Inventive Principle:
Principle #24Intermediary (Mediator)

Solution Approach 2:

The patent replaces the purely chemical decomposition mechanism (which requires high peroxide concentration) with a plasma-assisted decomposition process. This substitution allows the use of safer, lower concentration hydrogen peroxide while maintaining or improving thruster performance through the added energy from plasma.

Inventive Principle:
Principle #28Mechanics substitution (Replace mechanical system)

3Productivity

If arcjet engines electrically energize the propellant flow to increase specific impulse, then the efficiency improves, but the thrust is much lower than pure chemical thrusters due to the electrical energy required

Engineering Contradiction:
Improvespecific impulseVSAvoidelectrical energy consumption
Core Design Contradiction:
ProductivityVSPower

Solution Approach 1:

The patent creates a composite energy system combining chemical energy from hydrogen peroxide decomposition and electrical energy from plasma. This composite approach leverages the high energy density of chemical reactions while using a controlled amount of electrical energy to enhance decomposition efficiency and increase specific impulse, achieving a balance between thrust and efficiency.

Inventive Principle:
Principle #40Composite materials

Solution Approach 2:

The patent merges chemical propulsion (hydrogen peroxide decomposition) with electrical propulsion (plasma energization) into a hybrid system. This combination allows the chemical reaction to provide the primary energy source for thrust while the electrical plasma input optimizes the decomposition process, achieving higher specific impulse without the excessive electrical energy consumption of pure arcjet engines.

Inventive Principle:
Principle #5Merging (Combining)

4Productivity

If toxic propellants like hydrazine are used to achieve high specific impulse, then the propulsion performance is excellent, but the handling safety deteriorates and infrastructure costs increase

Engineering Contradiction:
Improvespecific impulseVSAvoidhandling safety
Core Design Contradiction:
ProductivityVSEase of operation

Solution Approach 1:

The patent converts the historical use of toxic propellants into an opportunity to adopt safer alternatives. By using plasma-assisted decomposition technology originally developed for other applications, the system achieves high specific impulse with non-toxic or less toxic hydrogen peroxide, turning the limitation of safer propellants into a non-issue through technological innovation.

Inventive Principle:
Principle #22Blessing in disguise (Convert harm into benefit)

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

This approach significantly increases the specific impulse of the rocket engine, reduces catalyst consumption, and allows for safer handling of propellants by using less toxic hydrogen peroxide, achieving thrust comparable to hydrazine systems while minimizing the risks associated with handling hazardous materials.

Implementation Method 1

introducing a flow of catalyst particulates into a plasma flow field and reacting them with a propellant in the plasma flow field

Methodology Applied
Scientific EffectPlasma: Plasma

Implementation Method 2

reacting the catalyst particulates with a propellant in the plasma flow field

Methodology Applied
Scientific EffectCatalysis: Catalysis

Implementation Method 3

the decomposition produces a 1000° C. gas that is a mixture of nitrogen, hydrogen, and ammonia

Methodology Applied
Scientific EffectDecomposition: Decomposition (biological)

Implementation Method 4

an exothermic reaction that disassociates the propellant into one or more high temperature products

Methodology Applied
Scientific EffectExothermic Reaction: Exothermic Reaction

Implementation Method 5

the decomposition produces a 1000° C. gas that is a mixture of nitrogen, hydrogen, and ammonia

Methodology Applied
Scientific EffectThermal expansion: Thermal Expansion

Data Source

PatentUS9505503B2Reactants sprayed into plasma flow for rocket propulsion
Publication Date: 2016.11.29 LOCKHEED MARTIN CORP
  • US9505503B2 patent drawing
  • US9505503B2 patent drawing
  • US9505503B2 patent drawing

AI summary

Specific impulse and rocket engine efficiency can be improved by injecting reactants, e.g., a propellant combination or a monopropellant and a catalyst, into a plasma flow of a rocket engine. In some aspects, a catalyst or a propellant is carried by plasma formed by passing a flow of a feed gas through an electrical arc. In some aspects, reactants are combusted in supersonic plasma flow to generate combustion ionization in the plasma flow.