Plasma-Sprayed Polymer Mold Coating for Thermoplastic Composite Adhesion

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Solution Overview

Problem

Thermoplastic composite materials face challenges in adhering to complex mold surfaces during lay-up processes due to lack of tackiness, leading to difficulties in initial ply placement and subsequent removal of composite parts from the mold, which limits their use in aerospace and high-performance applications.

Innovation Solution

A non-porous metal mold tool with a textured surface and a releasably adhered surface layer polymer coating, preferably thermoplastic particles applied by plasma spraying, enhances adhesion of the first ply of fiber-reinforced thermoplastic composite materials while allowing easy separation of the composite part, and can include a release film to maintain dimensional accuracy and facilitate removal.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Productivity

If thermoplastic composite materials are used for fiber-reinforced structures, then processing speed and production rate are improved, but adhesion to mold surfaces during lay-up deteriorates due to lack of tackiness

Engineering Contradiction:
Improveprocessing speedVSAvoidadhesion to mold surface
Core Design Contradiction:
ProductivityVSReliability

Solution Approach 1:

A plasma-sprayed polymer coating layer is applied to the mold surface to act as an intermediary between the thermoplastic composite material and the mold. This coating provides the necessary tackiness for initial ply adhesion during automated tape placement, enabling thermoplastic materials to be processed at high speeds without compromising adhesion to the mold surface.

Inventive Principle:
Principle #24Intermediary (Mediator)

2Reliability

If thermoplastic particles are plasma sprayed to form a surface layer coating, then adhesion of first ply is improved, but processing complexity increases

Engineering Contradiction:
Improveadhesion of first plyVSAvoidprocessing complexity
Core Design Contradiction:
ReliabilityVSDevice complexity

Solution Approach 1:

The plasma-sprayed polymer coating is applied to the mold surface in advance, before the automated tape placement process begins. This preliminary action prepares the mold surface with the necessary adhesion properties, allowing subsequent high-speed thermoplastic composite processing without requiring complex real-time adhesion control during manufacturing.

Inventive Principle:
Principle #10Preliminary action

3Reliability

If a surface layer polymer coating is applied to enhance adhesion, then first ply placement is improved, but removal of composite parts from mold becomes difficult

Engineering Contradiction:
Improveadhesion of first plyVSAvoidremoval from mold
Core Design Contradiction:
ReliabilityVSEase of manufacture

Solution Approach 1:

The plasma-sprayed polymer coating provides localized adhesion enhancement only at the mold surface interface where it is needed for initial ply placement. The coating's properties are optimized to provide sufficient tackiness for adhesion during processing while maintaining ease of part removal after curing, achieving both requirements through targeted surface modification.

Inventive Principle:
Principle #3Local quality

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The solution improves the adhesion and processing efficiency of thermoplastic composite materials, reducing material de-bonding and processing time, and enables the production of high-quality composite parts with improved interlaminar properties and reduced capital and facility costs.

Implementation Method 1

The surface layer polymer coating is preferably thermoplastic particles applied by plasma spraying to the mold tool or prepreg to form a substantially fused layer of thermoplastic particles

Methodology Applied
Scientific EffectPlasma spray: Plasma Spray

Data Source

PatentUS11214019B2Surface engineering of thermoplastic materials and tooling
Publication Date: 2022.01.04 CYTEC IND INC
  • US11214019B2 patent drawing
  • US11214019B2 patent drawing
  • US11214019B2 patent drawing

AI summary

A prepared mold tool having a thermoplastic surface layer polymer coating on the mold surface of the mold tool or prepared prepreg having a thermoplastic surface layer polymer coating on the surface of the thermoplastic fiber reinforced prepreg are described that enhance first ply laydown of thermoplastic fiber reinforced composite prepregs onto mold tools for prepreg forming or in situ tape placement. Resulting thermoplastic fiber reinforced composite parts from a thermoplastic fiber reinforced thermoplastic composite material having structural reinforcement fibers with one or more high performance polymers, and a thermoplastic surface layer polymer coating which forms a polymer blend with the high performance polymers of the thermoplastic fiber reinforced composite material thereby imparting improved properties, and methods for making and using same, are provided herein.