Plasma Process for Structured Particle Production

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Solution Overview

Problem

Existing methods for producing core-shell structured nanoparticles suffer from large particle size distribution and low production rates, limiting their effectiveness and efficiency.

Innovation Solution

A process involving a plasma torch to generate a high field zone for decomposing a first precursor, which is then used to coat a second precursor in an afterglow region, allowing for the creation of structured particles with precise control over size and composition, including core-shell nanoparticles with narrow size distributions and high production rates.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Productivity

If conventional methods are used to produce core-shell structured nanoparticles, then production can proceed with existing technology, but large particle size distribution and low production rates result

Engineering Contradiction:
Improveproduction rateVSAvoidparticle size distribution
Core Design Contradiction:
ProductivityVSManufacturing precision

Solution Approach 1:

The process segments the nanoparticle production into distinct stages: core formation in the plasma afterglow region, followed by separate shell material introduction and deposition. This segmentation allows independent optimization of each stage, achieving narrow size distribution during core formation while maintaining high production rates through continuous processing.

Inventive Principle:
Principle #1Segmentation

Solution Approach 2:

The core nanoparticles are formed in advance in the plasma afterglow region before shell material is introduced. This preliminary action establishes a narrow size distribution foundation that enables subsequent shell deposition without compromising size uniformity, while the continuous nature of the process maintains high productivity.

Inventive Principle:
Principle #10Preliminary action

2Manufacturing precision

If methods are used to achieve narrow particle size distribution, then manufacturing precision improves, but production rate decreases

Engineering Contradiction:
Improveparticle size distributionVSAvoidproduction rate
Core Design Contradiction:
Manufacturing precisionVSProductivity

Solution Approach 1:

The process replaces conventional mechanical or chemical synthesis methods with plasma-based synthesis. The plasma afterglow provides controlled energy input that promotes uniform nucleation and growth, achieving narrow size distribution through physical-chemical control rather than mechanical mixing or slow chemical reactions, thereby maintaining high production rates.

Inventive Principle:
Principle #28Mechanics substitution (Replace mechanical system)

Solution Approach 2:

The process utilizes plasma parameters (temperature, energy density, gas composition) to control nanoparticle formation kinetics. By optimizing these parameters in the afterglow region, uniform particle sizes are achieved while the continuous plasma generation maintains high production throughput.

Inventive Principle:
Principle #35Parameter changes

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

This process enables the production of structured particles with consistent size and composition, such as core-shell nanoparticles, suitable for applications like electroactive materials and catalysts, with improved production rates and reduced particle size distribution, enhancing their performance and utility.

Implementation Method 1

The first precursor, which can be in the form of a dry precursor powder, a precursor liquid, a precursor vapor of a liquid and/or a precursor gas is passed through a high field zone of a plasma generated by the plasma torch with at least part of the first precursor undergoing decomposition

Methodology Applied
Scientific EffectPlasma decomposition: Plasma

Implementation Method 2

The decomposed first precursor then deposits onto the second precursor to form a coating layer

Methodology Applied
Scientific EffectPhysical vapor deposition: Physical Vapour Deposition

Data Source

PatentUS8642139B2Process to make structured particles
Publication Date: 2014.02.04 STC UNM
  • US8642139B2 patent drawing
  • US8642139B2 patent drawing
  • US8642139B2 patent drawing

AI summary

Disclosed is a process for making a composite material that contains structured particles. The process includes providing a first precursor in the form of a dry precursor powder, a precursor liquid, a precursor vapor of a liquid and/or a precursor gas. The process also includes providing a plasma that has a high field zone and passing the first precursor through the high field zone of the plasma. As the first precursor passes through the high field zone of the plasma, at least part of the first precursor is decomposed. An aerosol having a second precursor is provided downstream of the high field zone of the plasma and the decomposed first material is allowed to condense onto the second precursor to from structured particles.