Plasma-Induced Water Splitting Using Single Cooled Electrode

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Solution Overview

Problem

Conventional water splitting methods face challenges such as high energy consumption, electrode corrosion, contamination of treated water, and the need for pre-purified water, limiting efficiency and increasing costs.

Innovation Solution

A method using plasma-induced water splitting with a single flat, cooled plasma electrode at atmospheric pressure, applying high-frequency alternating voltage to dissociate water into hydrogen and oxygen without direct electrode contact, employing a non-thermal plasma process that allows dissociative electron attachments and excitations, enabling efficient hydrogen production using various water types without pre-cleaning.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If conventional electrolysis is used to split water, then hydrogen can be produced, but electrode corrosion and contamination of treated water occur

Engineering Contradiction:
Improveelectrode stabilityVSAvoidcontamination of treated water
Core Design Contradiction:
ReliabilityVSObject-generated harmful factors

Solution Approach 1:

The patent introduces a plasma field as an intermediary between the electrode and water. Instead of direct contact between electrode and water causing corrosion and contamination, the plasma field mediates the water splitting process, allowing hydrogen production without electrode-water contact. The plasma acts as a reactive medium that enables dissociation while preventing direct electrochemical corrosion.

Inventive Principle:
Principle #24Intermediary (Mediator)

Solution Approach 2:

The patent replaces the conventional electrochemical mechanism with a plasma-based mechanism. Instead of using electrical current directly to drive electrolysis at electrode surfaces, the system uses a plasma field to generate reactive species that facilitate water splitting. This substitution eliminates the mechanical/electrochemical contact that causes corrosion and contamination.

Inventive Principle:
Principle #28Mechanics substitution (Replace mechanical system)

2Productivity

If electrolysis is used for water splitting, then hydrogen can be produced, but high energy consumption and high costs occur

Engineering Contradiction:
Improvehydrogen production efficiencyVSAvoidenergy consumption
Core Design Contradiction:
ProductivityVSUse of energy by moving object

Solution Approach 1:

The patent changes the fundamental parameters of the water splitting process by transitioning from thermal/electrochemical methods to plasma-based methods. The plasma field creates a different reaction environment with higher energy density and more efficient charge transfer, enabling water splitting at lower overall energy consumption while maintaining or improving hydrogen production rates.

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent employs periodic application of voltage to generate plasma. By using pulsed or alternating voltage patterns, the system efficiently sustains the plasma field without continuous high energy input. The periodic activation allows the plasma to reach stable reactive states while minimizing average energy consumption compared to continuous electrolysis.

Inventive Principle:
Principle #19Periodic action

3Adaptability or versatility

If conventional water splitting methods are used, then hydrogen can be produced, but pre-purified water is required

Engineering Contradiction:
Improvewater source flexibilityVSAvoidpre-purification requirement
Core Design Contradiction:
Adaptability or versatilityVSDevice complexity

Solution Approach 1:

The plasma-based system is self-service in its ability to handle various water types directly. The plasma field's high reactivity allows it to process raw water without requiring pre-purification, as the plasma can accommodate different water compositions and impurity levels while maintaining effective water splitting. This eliminates the need for complex pre-treatment systems.

Inventive Principle:
Principle #25Self-service

4Productivity

If two electrodes are used for water splitting, then hydrogen and oxygen can be produced, but electrode contamination and corrosion occur

Engineering Contradiction:
Improvehydrogen and oxygen productionVSAvoidelectrode service life
Core Design Contradiction:
ProductivityVSReliability

Solution Approach 1:

The patent extracts the water splitting function from the electrode surfaces themselves and relocates it to the plasma field. By removing the direct electrode-water interface, the system eliminates the source of corrosion and contamination while maintaining hydrogen and oxygen production capabilities. The electrodes become passive components that merely generate the plasma field rather than actively participating in the water splitting reaction.

Inventive Principle:
Principle #2Taking out (Extraction)

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

This approach achieves higher efficiency and cost-effectiveness by avoiding electrode contamination, allowing the use of diverse water sources and reducing energy consumption, resulting in a stable and efficient hydrogen production process.

Implementation Method 1

a plasma is formed in the high-frequency field between the plasma electrode and a surface of the water

Methodology Applied
Scientific EffectPlasma: Plasma

Implementation Method 2

Applying a high-frequency alternating voltage at atmospheric pressure to exactly one flat, cooled plasma electrode

Methodology Applied
Scientific EffectHigh-frequency alternating voltage: Electromagnetic Induction

Implementation Method 3

This enables dissociative electron attachments and dissociative excitations of the water

Methodology Applied
Scientific EffectDissociative electron attachments: Electron Impact Desorption

Implementation Method 4

The invention uses a so-called plasma electrolysis, ie a non-thermal plasma that initiates processes induced by electron impact

Methodology Applied
Scientific EffectNon-thermal plasma: Plasma

Data Source

PatentEP3710153B1Method and device for plasma-induced water splitting
Publication Date: 2021.09.08 GRAFORCE GMBH
  • EP3710153B1 patent drawingFigure 1~2

AI summary

The invention relates to a method for plasma-induced splitting of water. The particular feature in the invention resides in the fact that the provision of water with a predetermined filling level in an ungrounded water reservoir within a reaction chamber, the application of exactly one flat, cooled plasma electrode with a high-frequency alternating voltage arranged at a predetermined distance over the filling level of the water reservoirat atmospheric pressure, in such a way as a plasma forms in the high-frequency field between the plasma electrode and a surface of the water, in which plasma water disassociates to form hydrogen and oxygen and the collection of the hydrogen and of the oxygen in a common output gas line from the reaction chamber are comprised.