Plasmonic Up-Converter Nanofeature Arrays for Infrared Conversion

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Solution Overview

Problem

Conventional up-conversion materials are inefficient in converting infrared electromagnetic radiation to visible light, with many only achieving about 1.5% efficiency, necessitating the development of more effective techniques for applications in displays, projection TVs, and other technologies.

Innovation Solution

A plasmonic up-converter apparatus utilizing an array of nanofeatures, such as nanoparticles or nanoholes, is designed to produce an emission spectrum with intensities at second or third harmonic frequencies approximately equal to the fundamental harmonic frequency, enhancing the conversion of infrared radiation to visible or soft ultraviolet frequencies through Mie resonance and collective electronic oscillations.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Ease of manufacture

If conventional up-conversion materials are used, then the device structure can be simple, but the conversion efficiency is very low (only about 1.5%)

Engineering Contradiction:
Improvesimplicity of device structureVSAvoidup-conversion efficiency
Core Design Contradiction:
Ease of manufactureVSLoss of energy

Solution Approach 1:

The patent changes the physical parameters of the up-conversion material by reducing its dimension to the nanoscale (nanoparticles, nanoshells, nanorods, nanowires) and arranging them in periodic arrays. This dimensional and structural parameter change enables plasmonic resonances and enhances the up-conversion efficiency from 1.5% to potentially much higher values, while maintaining relative structural simplicity through self-assembly or direct fabrication of periodic patterns.

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent employs composite structures combining metal nanoparticles (plasmonic materials) with dielectric matrices or other functional materials. These composite nanofeatures exhibit both plasmonic properties for field enhancement and up-conversion properties for frequency conversion, achieving high efficiency through the synergistic interaction of different materials at the nanoscale.

Inventive Principle:
Principle #40Composite materials

2Quantity of substance

If conventional up-conversion materials are used, then the material composition can be simple, but the conversion efficiency remains low

Engineering Contradiction:
Improvematerial composition simplicityVSAvoidconversion efficiency
Core Design Contradiction:
Quantity of substanceVSProductivity

Solution Approach 1:

The patent transforms simple material compositions into high-performance up-converters by changing their physical parameters: reducing size to nanoscale, creating periodic arrangements, and controlling aspect ratios. These parameter changes enable plasmonic resonances and field enhancements that dramatically improve conversion efficiency without requiring complex multi-component material systems.

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent transitions from bulk or thin-film up-conversion materials to three-dimensional periodic arrays of nanofeatures with controlled geometries (spheres, shells, rods, wires). This dimensional change from 2D/3D bulk to structured 0D/1D nanofeatures enables exploitation of plasmonic resonances and size-dependent optical properties to enhance efficiency.

Inventive Principle:
Principle #17Another dimension (Dimensionality change)

3Loss of energy

If higher conversion efficiency is achieved through nanofeature arrays, then the device complexity increases, but this resolves the low efficiency problem

Engineering Contradiction:
Improveup-conversion efficiencyVSAvoidstructural complexity of nanofeature arrays
Core Design Contradiction:
Loss of energyVSDevice complexity

Solution Approach 1:

The patent divides the up-conversion function into discrete nanofeatures (individual nanoparticles, nanoshells, etc.) arranged in periodic arrays. Each nanofeature acts as an independent unit with specific plasmonic and up-conversion properties, and their collective periodic arrangement creates additional photonic band structure effects. This segmentation enables precise control of optical response while maintaining modular simplicity.

Inventive Principle:
Principle #1Segmentation

Solution Approach 2:

The patent manages structural complexity by systematically varying key parameters (particle size, inter-particle spacing, array periodicity, aspect ratio) rather than creating arbitrarily complex structures. These controlled parameter changes allow tuning of plasmonic resonances and up-conversion efficiency through well-understood physical relationships, making the complex structures predictable and manufacturable.

Inventive Principle:
Principle #35Parameter changes

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The plasmonic up-converter apparatus achieves significant up-conversion efficiency, with approximately 40% to 50% of excitation radiation being converted to visible or soft ultraviolet frequencies, significantly improving upon conventional materials' efficiency.

Implementation Method 1

enhancing the conversion of infrared radiation to visible or soft ultraviolet frequencies through Mie resonance and collective electronic oscillations

Methodology Applied
Scientific EffectMie resonance:

Implementation Method 2

The emission spectrum has an intensity at a second harmonic frequency or a third harmonic frequency approximately equal to an intensity at a fundamental harmonic frequency

Methodology Applied
Scientific EffectSecond harmonic generation: Second Harmonic Generation

Implementation Method 3

The emission spectrum has an intensity at a second harmonic frequency or a third harmonic frequency approximately equal to an intensity at a fundamental harmonic frequency

Methodology Applied
Scientific EffectThird harmonic generation:

Data Source

PatentUS7560707B2Apparatuses and methods for up-converting electromagnetic radiation
Publication Date: 2009.07.14 HEWLETT PACKARD ENTERPRISE DEV LP
  • US7560707B2 patent drawing
  • US7560707B2 patent drawing
  • US7560707B2 patent drawing

AI summary

As disclosed herein, a plasmonic up-converter apparatus includes an excitation source operable to emit electromagnetic radiation at an excitation frequency and at least one array of nanofeatures. The at least one array of nanofeatures is configured to produce an emission spectrum responsive to irradiation by the electromagnetic radiation. The emission spectrum has an intensity at a second harmonic frequency or a third harmonic frequency approximately equal to an intensity at a fundamental harmonic frequency, with the fundamental harmonic frequency being approximately equal to the excitation frequency. Additional aspects are directed to a display that utilizes any of the disclosed plasmonic up-converter apparatuses, a laser in which a laser medium is optically pumped using electromagnetic radiation produced by one of the disclosed plasmonic up-converter apparatuses, and methods of up-converting electromagnetic radiation.