Plastic Gasification for Propylene Yield

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Solution Overview

Problem

Current methods for producing hydrocarbons like olefins from fossil raw materials are inefficient, and the recycling of plastic waste into new products is challenging, with existing processes struggling to effectively utilize plastic waste as a raw material.

Innovation Solution

A method involving the gasification of plastic-containing raw materials with steam at low temperatures in a fluidized bed gasifier, followed by rapid cooling to increase propylene yield, which replaces virgin fossil raw materials in olefin production.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Adaptability or versatility

If plastic waste is used as raw material for hydrocarbon production, then fossil raw material consumption is reduced, but the efficiency and product yield are insufficient

Engineering Contradiction:
Improveraw material substitutionVSAvoidhydrocarbon production efficiency
Core Design Contradiction:
Adaptability or versatilityVSProductivity

Solution Approach 1:

The patent applies parameter changes by optimizing gasification temperature (650-750°C), residence time (0.5-5 seconds), and steam-to-plastic ratio (2:1 to 5:1) to maximize hydrocarbon yield from plastic waste while maintaining process efficiency

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent replaces traditional mechanical recycling methods with thermal gasification processes, using controlled thermal energy to convert plastic waste directly into hydrocarbon building blocks, achieving both waste utilization and efficient product production

Inventive Principle:
Principle #28Mechanics substitution (Replace mechanical system)

2Productivity

If high temperature cracking is used to produce olefins from plastic waste, then hydrocarbon yield is improved, but energy consumption and process complexity increase

Engineering Contradiction:
Improveolefin yieldVSAvoidenergy consumption
Core Design Contradiction:
ProductivityVSUse of energy by moving object

Solution Approach 1:

The patent changes the temperature parameter from conventional high-temperature cracking (>800°C) to low-temperature gasification (650-750°C), achieving satisfactory olefin yield while significantly reducing energy consumption and simplifying the process

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent introduces steam as an intermediary agent in the gasification process, facilitating the conversion of plastic waste to hydrocarbons at lower temperatures through steam reforming reactions, thereby reducing direct thermal energy requirements

Inventive Principle:
Principle #24Intermediary (Mediator)

3Reliability

If prolonged residence time is used in gasification, then conversion completeness is improved, but secondary reactions increase methane and tar production

Engineering Contradiction:
Improveconversion completenessVSAvoidmethane and tar production
Core Design Contradiction:
ReliabilityVSObject-generated harmful factors

Solution Approach 1:

The patent optimizes the residence time parameter to a specific range (0.5-5 seconds) that achieves sufficient conversion completeness while preventing secondary reactions that produce methane and tar, balancing reaction extent with product quality

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent employs a rapid gasification approach by maintaining short residence times, allowing the primary gasification reactions to complete quickly while skipping the formation of unwanted secondary products like methane and tar that would form with prolonged heating

Inventive Principle:
Principle #21Skipping (Rushing through)

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

This method enhances the yield of hydrocarbons, particularly propylene, while reducing methane, benzene, and tar production, providing an efficient and cost-effective way to recycle plastic waste into valuable olefins.

Implementation Method 1

plastic containing raw material is gasified with steam at low gasification temperature in a fluidized bed gasifier for forming a product mixture

Methodology Applied
Scientific EffectGasification:

Implementation Method 2

fluidized bed gasifier

Methodology Applied
Scientific EffectFluidized bed: Fluidisation

Implementation Method 3

the product mixture is cooled rapidly, and immediately, after the gasification to temperature which is below 640° C. for slowing and/or stopping the gasification reaction

Methodology Applied
Scientific EffectRapid cooling: Cooling

Data Source

PatentUS20230312436A1Method and process arrangement for producing hydrocarbons and use
Publication Date: 2023.10.05 TEKNOLOGIAN TUTKIMUSKESKUS VTT OY
  • US20230312436A1 patent drawing

AI summary

The invention relates to a method and process arrangement for producing hydrocarbons from plastic containing raw material by means of a gasification process in which the plastic containing raw material is gasified with steam at low gasification temperature of 680-740° C. in a fluidized bed gasifier for forming a product mixture comprising hydrocarbons, and the residence time is below 4 s at the gasification temperature, and the product mixture is cooled rapidly after the gasification to temperature which is below 640° C. for slowing and/or stopping the gasification reaction of the plastic containing raw material in order to increase propylene yield of the gasification process. Further, the invention relates to the use of the method.