Plastic Lens Coating with Scratch-Resistant Hardcoat

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Solution Overview

Problem

Plastic optical lenses are susceptible to mechanical damage, particularly scratching, which can compromise their optical clarity and antireflection properties, as existing coatings may themselves be prone to scratching and not provide adequate protection.

Innovation Solution

A coating system for plastic optical lenses comprising a hardcoat layer adjacent to the lens element, a superhydrophobic layer at the surface, and high-refractive-index layers with a total thickness of less than 40 nm, applied using PVD or other thin-layer processes, to enhance mechanical durability and antireflection properties.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If a conventional coating with thick anti-reflective layers is applied to plastic lenses, then antireflection properties are improved, but the coating becomes susceptible to mechanical damage and scratching

Engineering Contradiction:
Improveantireflection propertiesVSAvoidscratch resistance
Core Design Contradiction:
ReliabilityVSStrength

Solution Approach 1:

The coating is divided into multiple functional layers: a hardcoat layer (1-10 μm thick) providing mechanical protection, and thin anti-reflective layers (totaling less than 40 nm) providing optical functionality. This segmentation allows each layer to optimize its specific function without compromising the other.

Inventive Principle:
Principle #1Segmentation

Solution Approach 2:

Different regions of the coating system have different properties: the hardcoat layer provides high hardness and scratch resistance, while the anti-reflective layers provide low reflectance. The superhydrophobic layer provides water beading. Each layer is positioned to provide its specific function at the appropriate location in the coating structure.

Inventive Principle:
Principle #3Local quality

2Strength

If the anti-reflective layers are made thinner to reduce scattering, then mechanical durability is improved, but antireflection performance may be compromised

Engineering Contradiction:
Improvemechanical durabilityVSAvoidantireflection performance
Core Design Contradiction:
StrengthVSReliability

Solution Approach 1:

The patent specifies precise thickness parameters for the anti-reflective layers (less than 40 nm total) and for the hardcoat layer (1-10 μm). By optimizing these parameters, the coating achieves both mechanical durability and adequate antireflection performance. The superhydrophobic layer thickness is also controlled to provide water beading without compromising other properties.

Inventive Principle:
Principle #35Parameter changes

3Strength

If a hardcoat layer is applied to protect against scratching, then scratch resistance is improved, but the coating complexity increases

Engineering Contradiction:
Improvescratch resistanceVSAvoidcoating structure
Core Design Contradiction:
StrengthVSDevice complexity

Solution Approach 1:

The hardcoat layer and anti-reflective layers are combined into a single integrated coating system applied to the lens. The hardcoat layer serves as both a protective layer and a substrate for the anti-reflective layers, merging mechanical protection with optical functionality in one coating structure rather than separate applications.

Inventive Principle:
Principle #5Merging (Combining)

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The coating system significantly reduces light scattering during mechanical tests, achieving high Bayer values (>17) while maintaining excellent antireflection properties with minimal reflectance (<2.5%) and improved water beading, thus enhancing the mechanical and optical performance of plastic lenses.

Implementation Method 1

the plurality of layers comprising at least one high-refractive-index layer... for the purpose of preventing disruptive reflections

Methodology Applied
Scientific EffectRefraction: Refraction

Implementation Method 2

anti-reflective layers on the optical lenses, for the purpose of preventing disruptive reflections

Methodology Applied
Scientific EffectAnti-reflective coating: Anti-Reflective Coating

Implementation Method 3

a superhydrophobic layer concludes the coating... improved water beading

Methodology Applied
Scientific EffectHydrophobe: Hydrophobe

Implementation Method 4

applied using PVD or other thin-layer processes

Methodology Applied
Scientific EffectPhysical Vapour Deposition: Physical Vapour Deposition

Data Source

PatentUS9817155B2Optical lens with scratch-resistant anti-reflective layer
Publication Date: 2017.11.14 CARL ZEISS VISION INTERNATIONAL GMBH
  • US9817155B2 patent drawing
  • US9817155B2 patent drawing
  • US9817155B2 patent drawing

AI summary

The present invention relates to an optical lens having a lens element produced of plastic, more particularly of plastic which is transparent in a visible spectral range, and having a coating comprising a plurality of layers, the plurality of layers comprising at least one high-refractive-index layer. Furthermore, a hardcoat layer is formed adjacent to the lens element, and a superhydrophobic layer concludes the coating in opposition to the lens element. The at least one high-refractive-index layer has a thickness of less than 40 nm, and the coating overall has a thickness of more than about 380 nm.