Polylactic Acid Composition Pulverization Promoter

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Solution Overview

Problem

Polylactic acid compositions used in drilling applications face challenges with low hydrolysable capability and high costs due to difficulties in pulverization, as existing solutions either lack effective pulverizability or impair hydrolysable properties.

Innovation Solution

A polylactic acid composition with a low crystallinity matrix (≤40%) incorporating an organically modified polysaccharide or swollen lamellar silicate as a pulverization promoter, optimized for mechanical pulverization to enhance both hydrolysable and pulverizable properties.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Object-affected harmful factors

If polylactic acid is used as a dispersion solution for drilling, then environmental compatibility is improved, but pulverizability deteriorates

Engineering Contradiction:
Improveenvironmental compatibilityVSAvoidpulverizability
Core Design Contradiction:
Object-affected harmful factorsVSEase of manufacture

Solution Approach 1:

The patent creates a composite material system combining polylactic acid with specific additives (silane coupling agents, nucleating agents, and pulverization promoters) to achieve both environmental compatibility and improved pulverizability. The composite structure allows the polylactic acid to maintain its biodegradable properties while the added components enhance its mechanical pulverization characteristics, resolving the contradiction between environmental friendliness and manufacturability.

Inventive Principle:
Principle #40Composite materials

Solution Approach 2:

The patent modifies the physical and chemical parameters of polylactic acid through controlled crystallization processes and additive incorporation. By adjusting crystallinity levels and incorporating specific promoters, the material's pulverization characteristics are enhanced without compromising its biodegradable nature, thus improving ease of manufacture while maintaining environmental compatibility.

Inventive Principle:
Principle #35Parameter changes

2Ease of manufacture

If polylactic acid is pulverized repeatedly to achieve atomization, then pulverizability is improved, but manufacturing cost increases

Engineering Contradiction:
ImprovepulverizabilityVSAvoidmanufacturing cost
Core Design Contradiction:
Ease of manufactureVSProductivity

Solution Approach 1:

The patent incorporates pulverization promoters and nucleating agents during the initial material synthesis stage, which pre-condition the polylactic acid for easier pulverization. This preliminary action eliminates the need for repeated pulverization cycles, allowing the material to be atomized in fewer steps and significantly reducing manufacturing costs while maintaining excellent pulverizability.

Inventive Principle:
Principle #10Preliminary action

Solution Approach 2:

The patent introduces intermediary substances (pulverization promoters and silane coupling agents) that act as mediators between the polylactic acid matrix and the pulverization process. These intermediaries facilitate easier breakdown of the material during pulverization, reducing the number of processing steps required and lowering overall manufacturing costs.

Inventive Principle:
Principle #24Intermediary (Mediator)

3Strength

If highly crystalline polylactic acid is used, then mechanical strength is improved, but hydrolysable capability deteriorates

Engineering Contradiction:
Improvemechanical strengthVSAvoidhydrolysable capability
Core Design Contradiction:
StrengthVSReliability

Solution Approach 1:

The patent applies local quality by creating regions of different crystallinity within the polylactic acid material. By incorporating nucleating agents and controlling crystallization locally, the material exhibits enhanced mechanical strength in specific regions while maintaining amorphous or low-crystallinity regions that preserve hydrolysable capability. This spatial differentiation resolves the contradiction between strength and biodegradability.

Inventive Principle:
Principle #3Local quality

Solution Approach 2:

The patent creates a composite structure where highly crystalline regions provide mechanical strength and amorphous or low-crystallinity regions maintain hydrolysable capability. The composite architecture allows both properties to coexist, with the crystalline phases reinforcing the material and the amorphous phases facilitating hydrolysis and biodegradation.

Inventive Principle:
Principle #40Composite materials

4Reliability

If low crystallinity polylactic acid is used, then hydrolysable capability is improved, but mechanical strength deteriorates

Engineering Contradiction:
Improvehydrolysable capabilityVSAvoidmechanical strength
Core Design Contradiction:
ReliabilityVSStrength

Solution Approach 1:

The patent creates a composite material system where low-crystallinity or amorphous polylactic acid provides hydrolysable capability while incorporated reinforcing components (such as cellulose fibers, starch, or other biodegradable fillers) provide the necessary mechanical strength. This composite approach allows both properties to be simultaneously achieved.

Inventive Principle:
Principle #40Composite materials

Solution Approach 2:

The patent applies local quality by creating a heterogeneous structure where amorphous regions provide hydrolysable capability and specific dispersed phases or reinforced zones provide mechanical strength. The non-uniform distribution of properties within the material allows simultaneous optimization of both hydrolysis and mechanical performance.

Inventive Principle:
Principle #3Local quality

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The composition achieves efficient mechanical pulverization into fine granules with high yield, maintaining hydrolysable capability and reducing costs, suitable for use in aqueous dispersion solutions for drilling.

Implementation Method 1

the polylactic acid composition works to promote the hydrolysable capability and exhibits excellent pulverizablity, and can be atomized by the mechanical pulverization

Methodology Applied
Scientific EffectMechanical pulverization: Abrasion

Implementation Method 2

the polylactic acid undergoes the hydrolysis and loses the form of the resin. Therefore, spaces (or cracks) form in the portions where the polylactic acid has permeated

Methodology Applied
Scientific EffectHydrolysis: Hydrolysis

Implementation Method 3

it remains under the ground, is decomposed by water or enzyme in the ground and does not adversely affect the environment

Methodology Applied
Scientific EffectEnzymatic degradation: Enzyme

Data Source

PatentUS10626246B2Polylactic acid composition
Publication Date: 2020.04.21 TOYO SEIKAN GRP HLDG LTD
  • US10626246B2 patent drawing
  • US10626246B2 patent drawing

AI summary

A polylactic acid composition of a dispersion structure using, as a matrix, a lowly crystalline or amorphous polylactic acid having a crystallinity of not more than 40%, the matrix containing, as a pulverization promotor dispersed therein, an organically modified polysaccharide or a lamellar silicate that is swollen or that is treated to be swollen.The polylactic acid composition has excellent hydrolysable capability and property of being mechanically pulverized.