Plastic Surface Modification via Mold Pre-Functionalization

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Solution Overview

Problem

Existing methods for modifying plastic surfaces are costly, time-consuming, and lack long-term stability and sufficient adhesion for subsequent coatings, often affecting the mechanical properties of plastics and being environmentally harmful.

Innovation Solution

A method involving applying a solution or dispersion with modifier substances and auxiliaries to the mold surface, where the modifier substances form covalent bonds with the plastic during molding, creating cavities and improving adhesion, using environmentally friendly materials and processes.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Strength

If plasma or corona treatment is used to activate plastic surfaces, then adhesion is improved, but the process becomes time-consuming and costly

Engineering Contradiction:
ImproveadhesionVSAvoidprocess time
Core Design Contradiction:
StrengthVSLoss of time

Solution Approach 1:

The mold surface is pre-modified with modifier substances before the plastic molding process. This preliminary action ensures that the plastic surface becomes activated during molding itself, eliminating the need for separate post-treatment steps like plasma or corona discharge, thus reducing process time while maintaining adhesion improvement

Inventive Principle:
Principle #10Preliminary action

Solution Approach 2:

The surface activation function is merged with the molding process. The modifier substances are applied to the mold, and during the molding process, they transfer to and activate the plastic surface simultaneously with shaping the plastic, combining two operations into one

Inventive Principle:
Principle #5Merging (Combining)

2Strength

If plasma or corona treatment is used to activate plastic surfaces, then adhesion is improved, but the effects are not permanent over long periods

Engineering Contradiction:
ImproveadhesionVSAvoidstability of pretreatment
Core Design Contradiction:
StrengthVSDuration of action of stationary object

Solution Approach 1:

The mold surface is pre-modified with modifier substances before the plastic molding process. This preliminary action ensures that the plastic surface becomes activated during molding itself, eliminating the need for separate post-treatment steps like plasma or corona discharge, thus reducing process time while maintaining adhesion improvement

Inventive Principle:
Principle #10Preliminary action

Solution Approach 2:

The plastic surface activates itself during the molding process through contact with the modifier substances on the mold surface. The high temperature and pressure conditions during molding enable the plastic to undergo self-activation without requiring external plasma or corona treatment, creating permanent adhesion properties

Inventive Principle:
Principle #25Self-service

3Strength

If primer is used for surface modification, then adhesion is improved, but solvents pollute the environment and the process becomes expensive

Engineering Contradiction:
ImproveadhesionVSAvoidenvironmental pollution
Core Design Contradiction:
StrengthVSObject-affected harmful factors

Solution Approach 1:

The chemical solvent-based primer system is replaced with a thermal and pressure-based activation system. During molding, the high temperature and pressure conditions enable direct chemical bonding between the plastic surface and the modifier substances on the mold, eliminating the need for solvent-based primers and their associated environmental pollution

Inventive Principle:
Principle #28Mechanics substitution (Replace mechanical system)

Solution Approach 2:

The process utilizes changes in temperature and pressure parameters during molding to achieve surface activation. The high temperature and pressure conditions during the molding process enable the plastic surface to react with and bond to the modifier substances, replacing the need for solvent-based chemical treatments

Inventive Principle:
Principle #35Parameter changes

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

This method provides a simple, cost-effective, and long-term stable surface modification with improved adhesion for subsequent coatings, maintaining the mechanical properties of plastics while being environmentally friendly.

Implementation Method 1

the modifier substances with the reactive groups forming covalent bonds with the plastic surface during the molding process

Methodology Applied
Scientific EffectCovalent bonding: Chemical Bonding

Implementation Method 2

the auxiliary substance or substances are then at least partially removed from the surface of the molded plastic to produce at least one cavity

Methodology Applied
Scientific EffectDissolution: Solvation

Data Source

PatentEP3336136B1Method for modifying plastic surfaces and modified plastic surfaces having chemically functionalized microcavities
Publication Date: 2022.02.09 LEIBNIZ INST FUR POLYMERFORSCHUNG DRESDEN EV
  • EP3336136B1 patent drawingFigure 1A)~1C)

AI summary

The invention relates to the fields of chemistry and mechanical engineering and concerns a method for modifying plastic surfaces and modified plastic surfaces that can be used, for example, for coatings or for multi-component injection molding in the automotive industry or in mechanical engineering. The object of the present invention is to provide a method for modifying plastic surfaces that enables simple and cost-effective modification and results in long-term stable surface modifications.The object of the invention is solved by a method for modifying plastic surfaces in which at least one solution or dispersion is applied to the surface of a molding tool, followed by the removal of at least one solvent or dispersion agent from the molding tool, then at least one plastic is introduced into the molding tool as a melt, and then the additives are at least partially removed from the surface of the molded plastic.