Platinum Layer Patterning via Chloride-Fluoride Etching

Resolve Bottlenecks,
Find Innovative Solutions
Generate Solutions

Solution Overview

Problem

The formation of fence polymer byproducts during the dry etching of platinum layers in MEMS fabrication is challenging, as they are difficult to remove and cause deformations in the formed structures, necessitating an effective patterning method to avoid these residues.

Innovation Solution

A method involving an etchant comprising a chloride-containing gas and a fluoride-containing gas is used to pattern the platinum layer, with a gas ratio of chloride to fluoride adjusted to be substantially equal to or lower than 1, to minimize fence polymer formation and optimize the etching process.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Productivity

If chloride-containing gas is used in the etching process, then the removing rate of the platinum layer is improved, but fence polymer byproducts are formed that are hard to remove

Engineering Contradiction:
Improveremoving rate of platinum layerVSAvoidfence polymer byproducts
Core Design Contradiction:
ProductivityVSObject-generated harmful factors

Solution Approach 1:

The patent applies this principle by introducing fluoride-containing gas to convert the harmful fence polymer byproducts into volatile compounds that can be easily removed. The fluoride reacts with the polymer residues formed by chloride etching, transforming the difficult-to-remove harmful byproducts into volatile substances that evaporate during or after the etching process, thus eliminating the harmful effect while maintaining the high removing rate benefit

Inventive Principle:
Principle #22Blessing in disguise (Convert harm into benefit)

Solution Approach 2:

The patent uses a composite etchant system combining chloride-containing gas and fluoride-containing gas. This composite approach allows the chloride component to provide high etching speed while the fluoride component simultaneously suppresses polymer formation and removes residues. The synergistic interaction between the two gases creates an etching environment that achieves both high productivity and clean patterning without requiring separate process steps

Inventive Principle:
Principle #40Composite materials

2Object-generated harmful factors

If fluoride-containing gas is used in the etching process, then volatile byproducts are formed that are easy to remove, but the removing rate of the platinum layer decreases

Engineering Contradiction:
Improvevolatile byproducts formationVSAvoidremoving rate of platinum layer
Core Design Contradiction:
Object-generated harmful factorsVSProductivity

Solution Approach 1:

The patent merges the functions of chloride-containing gas (high removing rate) and fluoride-containing gas (volatile byproduct formation) into a single etching process. By combining these two gases in the etchant, the patent achieves both the high productivity benefit of chloride etching and the clean patterning benefit of fluoride etching, with the composite etchant system providing synergistic effects that neither gas could achieve alone

Inventive Principle:
Principle #5Merging (Combining)

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

This approach effectively reduces polymer residues and improves the patterning of platinum layers, enhancing the quality and reliability of MEMS structures by controlling the etching process and preventing unwanted byproduct formation.

Implementation Method 1

an etchant used in the etching process includes at least a chloride-containing gas and at least a fluoride-containing gas

Methodology Applied
Scientific EffectChemical reaction: Chemical Bonding

Implementation Method 2

The fluoride-containing gas used in the etching process may cause the formation of volatile byproducts that can be easily removed

Methodology Applied
Scientific EffectVolatile byproduct formation: Evaporation

Implementation Method 3

an etching process is performed to pattern the platinum layer

Methodology Applied
Scientific EffectPlasma: Plasma

Data Source

PatentUS9006105B2Method of patterning platinum layer
Publication Date: 2015.04.14 UNITED MICROELECTRONICS CORP
  • US9006105B2 patent drawing
  • US9006105B2 patent drawing
  • US9006105B2 patent drawing

AI summary

A method of patterning a platinum layer includes the following steps. A substrate is provided. A platinum layer is formed on the substrate. An etching process is performed to pattern the platinum layer, wherein an etchant used in the etching process simultaneously includes at least a chloride-containing gas and at least a fluoride-containing gas.