Platinum Organometallic Complex for OLED Efficiency and Lifetime

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Solution Overview

Problem

Organic electroluminescence (EL) devices face challenges such as burn-in, efficiency reduction, and durability issues, particularly due to deterioration of emission center substances and surrounding materials, which affect their performance and longevity.

Innovation Solution

Development of a novel organometallic complex with a specific molecular structure, including a platinum-based compound with a cyano group and bulky substituents, that inhibits exciplex formation and enhances stability in the excited state, reducing roll-off and improving emission efficiency.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If conventional organometallic complexes are used as light-emitting materials, then light emission can be obtained, but emission efficiency reduces over time due to deterioration and exciplex formation

Engineering Contradiction:
Improveemission efficiency stabilityVSAvoiddriving lifetime
Core Design Contradiction:
ReliabilityVSDuration of action of moving object

Solution Approach 1:

The patent modifies the molecular structure parameters of the organometallic complex by introducing a cyano group at a specific position and adding bulky substituents. These parameter changes in the molecular structure prevent exciplex formation and reduce deterioration, thereby maintaining emission efficiency stability and extending driving lifetime.

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent creates a composite molecular structure combining the organometallic complex core with specific functional groups (cyano group and bulky substituents). This composite structure achieves both high initial emission efficiency and long-term stability by preventing molecular aggregation and exciplex formation that cause efficiency roll-off.

Inventive Principle:
Principle #40Composite materials

2Reliability

If complex molecular structures are designed to improve emission characteristics, then emission efficiency increases, but synthesis complexity and manufacturing costs increase

Engineering Contradiction:
Improveemission efficiencyVSAvoidsynthesis complexity
Core Design Contradiction:
ReliabilityVSEase of manufacture

Solution Approach 1:

The patent segments the molecular design into distinct functional components: the organometallic complex core, the cyano group positioning, and the bulky substituent structures. This segmentation allows for modular synthesis approaches where each component can be prepared and characterized separately, then assembled into the final complex, reducing overall synthesis complexity.

Inventive Principle:
Principle #1Segmentation

Solution Approach 2:

The patent applies local quality by introducing specific functional groups (cyano group and bulky substituents) at particular positions on the molecular structure rather than uniformly modifying the entire molecule. This targeted approach achieves the desired emission characteristics and stability improvement while minimizing the complexity increase, as only specific locations require modification.

Inventive Principle:
Principle #3Local quality

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The novel organometallic complex leads to a light-emitting device with increased emission efficiency, reduced voltage change during operation, and extended driving lifetime, while also simplifying synthesis and reducing manufacturing costs.

Implementation Method 1

Organic electroluminescence (EL) devices (organic EL elements) typified by light-emitting devices, light-receiving devices, and light-emitting and light-receiving devices, which utilize EL with an organic compound such as an organometallic complex

Methodology Applied
Scientific EffectElectroluminescence: Electroluminescence

Implementation Method 2

an organic compound layer containing a photoelectric conversion material (an active layer) is located between a pair of electrodes. This device absorbs light energy to generate carriers, whereby electrons from the photoelectric conversion material can be obtained

Methodology Applied
Scientific EffectPhotoelectric conversion: Photoelectric Effect

Data Source

PatentUS20240174706A1Organometallic complex and light-emitting device
Publication Date: 2024.05.30 SEMICON ENERGY LAB CO LTD
  • US20240174706A1 patent drawing
  • US20240174706A1 patent drawing
  • US20240174706A1 patent drawing

AI summary

A novel organometallic complex that is highly convenient, useful, or reliable, and a light-emitting device are provided. The organometallic complex is represented by General Formula (G2). In General Formula (G2), each of R1 to R6, R8 to R22, and R31 to R34 independently represents hydrogen (including deuterium), an alkyl group having 1 to 10 carbon atoms, or a substituted or unsubstituted aryl group having 6 to 18 carbon atoms, at least one of R31 to R34 represents an alkyl group having 1 to 10 carbon atoms or a substituted or unsubstituted aryl group having 6 to 18 carbon atoms, and n is an integer of 1 to 4.