Pressure-Dependent Foam Moulding of Poly(meth)acrylimide Particles

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Solution Overview

Problem

Existing processes for producing poly(meth)acrylimide (P(M)I) foams, such as in-mould foaming, face challenges with non-uniform pore structure, inhomogeneous density, and longer production cycles, leading to poorer mechanical properties and increased complexity.

Innovation Solution

A novel process involving heating P(M)I particles under pressure, followed by charging them into a mould for depressurization and cooling, which allows for rapid foaming within 2 minutes and uniform temperature distribution, resulting in a foam core with consistent pore size and density.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Loss of time

If in-mould foaming is used to produce P(M)I foam cores, then the production cycle time is reduced, but the pore structure becomes non-uniform and density becomes inhomogeneous

Engineering Contradiction:
Improveproduction cycle timeVSAvoidpore structure uniformity
Core Design Contradiction:
Loss of timeVSManufacturing precision

Solution Approach 1:

The granules are preheated to the foaming temperature before being charged into the mould. This preliminary heating ensures that when the granules are introduced into the mould and depressurized, the foaming reaction occurs uniformly and rapidly throughout all particles simultaneously, rather than having to heat them in the mould which would create temperature gradients and non-uniform pore structures.

Inventive Principle:
Principle #10Preliminary action

Solution Approach 2:

The process separates the heating step from the foaming step. Granules are heated individually in a preheating station before being charged into the mould in segments. This segmentation allows each granule to reach the required temperature uniformly before foaming, ensuring consistent pore structure throughout the final product while maintaining rapid production cycles.

Inventive Principle:
Principle #1Segmentation

2Strength

If adhesion promoter coating is applied to particles before in-mould foaming, then cohesion at interfaces is improved, but pore distribution remains non-uniform

Engineering Contradiction:
Improvecohesion at interfacesVSAvoidpore distribution uniformity
Core Design Contradiction:
StrengthVSManufacturing precision

Solution Approach 1:

The adhesion promoter coating is applied as a preliminary action before the foaming process. This coating prepares the particle surfaces to ensure good cohesion at interfaces during foaming. Combined with the preheating step, this ensures that when particles are charged into the mould and foam, they bond well while maintaining uniform pore distribution throughout the structure.

Inventive Principle:
Principle #10Preliminary action

3Productivity

If external heating is used to soften material before microwave foaming, then foaming is accelerated, but process complexity increases

Engineering Contradiction:
Improvefoaming speedVSAvoidprocess complexity
Core Design Contradiction:
ProductivityVSDevice complexity

Solution Approach 1:

The invention replaces the complex combination of external heating systems and microwave fields with a simpler preheating approach. By heating granules externally before charging them into the mould, the process achieves rapid foaming without requiring simultaneous external heating and microwave irradiation, thus reducing equipment complexity while maintaining high productivity.

Inventive Principle:
Principle #28Mechanics substitution (Replace mechanical system)

4Ease of manufacture

If granules are charged to mould at atmospheric pressure, then charging is simple, but temperature gradients cause density gradients in the foam core

Engineering Contradiction:
Improvecharging simplicityVSAvoiddensity uniformity
Core Design Contradiction:
Ease of manufactureVSManufacturing precision

Solution Approach 1:

The granules are preheated to the foaming temperature before charging into the mould. This preliminary action ensures that when granules are charged at atmospheric pressure, they are already at the required temperature, eliminating temperature gradients during foaming and preventing density gradients in the final foam core, while maintaining simple charging procedures.

Inventive Principle:
Principle #10Preliminary action

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

This process significantly reduces production cycle times, achieves uniform pore and density distribution, and enhances mechanical properties by allowing simultaneous foaming throughout the mould, producing high-quality, complex shapes with improved cohesion and stability.

Implementation Method 1

heating of P(M)I particles to an atmospheric-pressure-foaming temperature T1, where this takes place under a pressure p1

Methodology Applied
Scientific EffectHeating: Heating

Implementation Method 2

heating of P(M)I particles to an atmospheric-pressure-foaming temperature T1, where this takes place under a pressure p1

Methodology Applied
Scientific EffectPressure Increase: Pressure Increase

Implementation Method 3

depressurization of the space within the mould to a pressure p3 at a temperature T2, where foaming of the particles takes place

Methodology Applied
Scientific EffectDepressurisation: Depressurisation

Implementation Method 4

foaming of the particles takes place

Methodology Applied
Scientific EffectFoaming: Foam

Implementation Method 5

cooling of the space within the mould to a temperature T3

Methodology Applied
Scientific EffectCooling: Cooling

Data Source

PatentUS10207435B2Pressure-dependent foam moulding of poly(meth)acrylimide particles in closed moulds for producing rigid foam cores
Publication Date: 2019.02.19 EVONIK OPERATIONS GMBH

AI summary

The invention relates to a process for the production of mold-foamed poly(meth)acrylimide (P(M)I) cores, in particular of polymethacrylimide (PMI) cores, which can be used by way of example in automobile construction or aircraft construction. A feature of this process is that polymer granules or polymer powder preheated under pressure are moreover charged under pressure to a compression mold where they are foamed with depressurization. In particular, a feature of the process is that it optionally uses a preferably two-shell compression mold for the heating and also for the cooling of the granules and, respectively, the rigid foam core formed therefrom.