Liquid Crystal Polarizer Composition Alignment Adhesiveness

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Solution Overview

Problem

Existing polarizer layers face challenges in achieving high alignment and adhesiveness when integrated into laminates, due to compatibility issues between polymer liquid crystal compounds and low-molecular-weight liquid crystal compounds.

Innovation Solution

A composition comprising a polymer liquid crystal compound with specific repeating units and a low-molecular-weight liquid crystal compound, where the compounds satisfy specific log P value and molecular length relationships, is used to form a polarizer layer with enhanced alignment and adhesiveness.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If a polymer liquid crystal compound and a low-molecular-weight liquid crystal compound are used in a polarizer layer, then the polarization function is achieved, but the adhesiveness between layers deteriorates due to compatibility issues

Engineering Contradiction:
Improvepolarization functionVSAvoidadhesiveness between layers
Core Design Contradiction:
ReliabilityVSStrength

Solution Approach 1:

The patent changes the chemical structure parameters of the polymer liquid crystal compound by introducing specific repeating units with particular molecular weight ranges and structural characteristics. This parameter optimization enables both high alignment (≥90%) and sufficient adhesiveness to coexist in the same polarizer layer, resolving the contradiction between polarization function and layer bonding.

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent creates a composite liquid crystal system by combining polymer liquid crystal compounds with specific repeating units and low-molecular-weight liquid crystal compounds in defined weight ratios (polymer: 1-40 wt%, low-molecular-weight: 60-99 wt%). This composite approach allows the synergistic interaction between different components to achieve both alignment and adhesiveness simultaneously.

Inventive Principle:
Principle #40Composite materials

2Manufacturing precision

If the polymer liquid crystal compound structure is optimized for alignment, then the degree of alignment improves, but the adhesiveness to other layers deteriorates

Engineering Contradiction:
Improvedegree of alignmentVSAvoidadhesiveness
Core Design Contradiction:
Manufacturing precisionVSStrength

Solution Approach 1:

The patent introduces specific repeating units with particular local structural characteristics (molecular weight 500-5000, specific functional groups) into the polymer liquid crystal compound. These localized structural modifications create regions with different properties: some regions favor alignment through rigid mesogenic groups, while other regions enhance adhesiveness through flexible spacer groups or polar functional groups.

Inventive Principle:
Principle #3Local quality

Solution Approach 2:

The patent optimizes specific structural parameters of the repeating units including molecular weight (500-5000), spacer group length (1-20 atoms), and functional group types. By precisely controlling these parameters, the patent achieves a balance where alignment is maintained at ≥90% while adhesiveness reaches sufficient levels for practical applications.

Inventive Principle:
Principle #35Parameter changes

3Reliability

If different liquid crystal compounds are used for alignment and adhesiveness, then each function can be optimized, but the device complexity increases

Engineering Contradiction:
Improvealignment and adhesiveness performanceVSAvoidcomposition complexity
Core Design Contradiction:
ReliabilityVSDevice complexity

Solution Approach 1:

The patent designs polymer liquid crystal compounds with repeating units that perform multiple functions simultaneously. The same repeating unit structure contributes to both alignment (through mesogenic groups) and adhesiveness (through spacer groups or polar functional groups). This multi-functionality eliminates the need for separate compounds for each function, reducing overall system complexity.

Inventive Principle:
Principle #6Universality (Multi-functionality)

Solution Approach 2:

The patent merges the alignment function and adhesiveness function into a single polymer liquid crystal compound structure. By incorporating both alignment-promoting moieties and adhesion-promoting moieties within the same polymer chain, the patent reduces the number of components needed while achieving both functions effectively.

Inventive Principle:
Principle #5Merging (Combining)

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The composition effectively forms a polarizer layer with improved alignment and adhesiveness, ensuring better integration and performance in laminates and image display devices.

Implementation Method 1

a polymer liquid crystal compound; a low-molecular-weight liquid crystal compound

Methodology Applied
Scientific EffectLiquid crystal phase ordering: Liquid Crystals

Implementation Method 2

a dichroic material

Methodology Applied
Scientific EffectDichroism: Dichroic Filter

Data Source

PatentUS20230062801A1Composition, polarizer layer, laminate, and image displaying device
Publication Date: 2023.03.02 FUJIFILM CORP
  • US20230062801A1 patent drawing
  • US20230062801A1 patent drawing
  • US20230062801A1 patent drawing

AI summary

Provided is a composition that is capable of forming a polarizer layer having an excellent degree of alignment and excellent adhesiveness to another layer in a case of being applied to a laminate, a polarizer layer, a laminate, and an image display device. The composition of the present invention is a composition including at least a polymer liquid crystal compound, a dichroic material, and a low-molecular-weight liquid crystal compound, in which the polymer liquid crystal compound is a copolymer having a repeating unit (1) represented by Formula (1), the low-molecular-weight liquid crystal compound is a compound represented by Formula (LC), and relationships represented by Expressions |log P(SP1)−log P(SPL1)|≤2.0 (11), |log P(MG1)−log P(SP1)|≥4.5 (12), and |log P(ML)−log P(SPL1)|≥4.0 (13) are satisfied.