Poly(meth)acrylate Treated Cellulosic Material for Dimensional Stability

Resolve Bottlenecks,
Find Innovative Solutions
Generate Solutions

Solution Overview

Problem

Current preservation methods for cellulosic materials like wood fail to adequately address termite resistance and dimensional stability, leading to issues such as splitting, warping, and degradation due to water absorption and insect damage.

Innovation Solution

A treated cellulosic material is developed by impregnating a cellulosic material with an aqueous dispersion containing a poly(meth)acrylate polymer, which enhances hydrophobicity, dimensional stability, and resistance to insects, fungi, and mold, using a method that includes pressure treatment and optional modifying agents to improve penetration and durability.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If pressure treatment with chemical compounds is used to preserve cellulosic material, then water resistance and dimensional stability are improved, but the material becomes susceptible to internal stresses, splitting, and warping due to non-uniform water absorption

Engineering Contradiction:
Improvewater resistanceVSAvoiddimensional stability
Core Design Contradiction:
ReliabilityVSStability of the object's composition

Solution Approach 1:

The patent changes the chemical composition parameters by introducing poly(meth)acrylate polymer with specific molecular weight ranges (10,000-1,000,000 g/mol) and controlled glass transition temperatures (-50°C to 0°C), which fundamentally alters how the material interacts with water, providing both water resistance and dimensional stability simultaneously

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent creates a composite system by combining poly(meth)acrylate polymer with cellulosic material, where the polymer forms a protective network within the porous structure that modifies water absorption behavior and provides both waterproofing and dimensional stability without the harmful effects of conventional chemical treatments

Inventive Principle:
Principle #40Composite materials

2Object-affected harmful factors

If conventional preservative treatments are applied to provide termite resistance, then insect damage is reduced, but the treatment requires high percentage weight gains and provides limited durability

Engineering Contradiction:
Improvetermite resistanceVSAvoiddurability
Core Design Contradiction:
Object-affected harmful factorsVSReliability

Solution Approach 1:

The patent employs a polymer that can be applied in small amounts (low weight gain) and provides long-lasting protection. The poly(meth)acrylate polymer forms a durable protective layer that maintains termite resistance over time without requiring high concentrations or frequent reapplication, effectively replacing the need for heavy-duty, short-lived conventional preservatives

Inventive Principle:
Principle #27Cheap short-living objects (Disposable)

3Stability of the object's composition

If water absorption is increased to improve dimensional stability, then the material becomes more resistant to splitting and warping, but water serves as a pathway for organisms that degrade the cellulosic material

Engineering Contradiction:
Improvedimensional stabilityVSAvoidbiodegradation
Core Design Contradiction:
Stability of the object's compositionVSObject-affected harmful factors

Solution Approach 1:

The patent converts the harmful effect of water absorption into a beneficial one by using poly(meth)acrylate polymer to create a hydrophobic protective network. This network allows the material to maintain dimensional stability while simultaneously preventing water from penetrating deep enough to serve as a pathway for biodegrading organisms, effectively turning water absorption into a protective mechanism

Inventive Principle:
Principle #22Blessing in disguise (Convert harm into benefit)

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The treated cellulosic material exhibits significant reduction in water absorption, improved dimensional stability, and enhanced resistance to insects and fungi, as demonstrated by reduced swelling and increased hardness, effectively addressing the limitations of existing preservation methods.

Implementation Method 1

Pressure treatment typically allows the treating agent to penetrate throughout the porous structure of the cellulosic material

Methodology Applied
Scientific EffectPressure treatment: Pressurisation

Implementation Method 2

The treating agent is typically a chemical compound selected to impart the desired physical properties to the cellulosic material

Methodology Applied
Scientific EffectAbsorption: Absorption (physical)

Implementation Method 3

The treated cellulosic material exhibits significant reduction in water absorption, improved dimensional stability

Methodology Applied
Scientific EffectHydrophobicity: Hydrophobe

Implementation Method 4

Porous materials, such as cellulosic materials, need to be protected from mold growth, insect attack, rot and water impregnation

Methodology Applied
Scientific EffectPreservation: Preservative

Data Source

PatentUS10322524B2Treated porous material
Publication Date: 2019.06.18 DOW GLOBAL TECHNOLOGIES LLC

AI summary

A treated cellulosic material comprising a cellulosic material having a porous structure defining a plurality of pores, at least a portion of the pores containing a treating agent comprising a polymer comprising a poly(meth)acrylate polymer. The present further describes a method for preparing a treated cellulosic material comprising (a) providing a cellulosic material; and (b) a first treatment protocol comprising impregnating the cellulosic material with an aqueous dispersion comprising a polymer, the polymer comprising a poly(meth)acrylate polymer.