Polysilicon TFT Fabrication via Metal Diffusion Control

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Solution Overview

Problem

Existing methods for crystallizing amorphous silicon (a-Si) into polycrystalline silicon (poly-Si) for thin film transistors (TFTs) face challenges such as substrate damage from high-temperature annealing, expensive laser equipment, and contamination from crystallization-inducing metals, which degrade device characteristics and require ineffective gettering processes.

Innovation Solution

A method involving a capping layer and controlled diffusion of crystallization-inducing metals like Ni, Pd, or Ag to form poly-Si, followed by patterning and the formation of additional gettering sites to effectively remove residual metals from channel regions, improving electrical characteristics like leakage current.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If solid phase crystallization (SPC) process is used to crystallize a-Si layer, then poly-Si layer can be formed, but substrate is damaged due to high temperature annealing for long period

Engineering Contradiction:
Improvesubstrate integrityVSAvoidannealing temperature
Core Design Contradiction:
ReliabilityVSTemperature

Solution Approach 1:

A capping layer is introduced as an intermediary between the a-Si layer and the crystallization-inducing metal layer. This capping layer controls the diffusion of metal atoms into the a-Si layer, enabling crystallization at lower temperatures while preventing excessive metal contamination that would require aggressive gettering processes which could damage the substrate.

Inventive Principle:
Principle #24Intermediary (Mediator)

Solution Approach 2:

The invention changes the crystallization parameters by using metal-induced crystallization (MIC) or metal-induced lateral crystallization (MILC) processes that operate at lower temperatures compared to SPC. By controlling the type and amount of crystallization-inducing metal and using a capping layer, the crystallization temperature is reduced, preventing substrate damage.

Inventive Principle:
Principle #35Parameter changes

2Productivity

If excimer laser annealing (ELA) process is used to crystallize a-Si layer, then poly-Si layer can be formed quickly, but expensive laser apparatus is required and crystallized surface is damaged

Engineering Contradiction:
Improvecrystallization speedVSAvoidlaser apparatus
Core Design Contradiction:
ProductivityVSDevice complexity

Solution Approach 1:

The invention replaces expensive laser apparatus with a more economical approach using crystallization-inducing metal layers that can be deposited using standard thin film deposition techniques. The metal layer serves as a temporary crystallization catalyst that is subsequently removed or retained in controlled amounts, providing a cost-effective alternative to ELA while achieving similar crystallization results.

Inventive Principle:
Principle #27Cheap short-living objects (Disposable)

3Temperature

If crystallization-inducing metal is used to crystallize a-Si layer, then crystallization can be performed at lower temperature, but device characteristics are degraded due to metal contamination

Engineering Contradiction:
Improvecrystallization temperatureVSAvoiddevice characteristics
Core Design Contradiction:
TemperatureVSReliability

Solution Approach 1:

The capping layer acts as a mediator that controls the interaction between crystallization-inducing metal and a-Si layer. It allows sufficient metal diffusion to induce crystallization at low temperatures while limiting excessive metal contamination in the channel region, thereby maintaining device characteristics.

Inventive Principle:
Principle #24Intermediary (Mediator)

Solution Approach 2:

The invention applies local quality by creating different regions with different metal concentrations. The capping layer ensures that metal is present in sufficient amounts to induce crystallization in the a-Si layer, while the channel region maintains lower metal concentrations to preserve device characteristics. Gettering sites are strategically placed to concentrate metal away from critical regions.

Inventive Principle:
Principle #3Local quality

4Reliability

If contact hole gettering site is used to remove crystallization-inducing metal, then some metal can be removed, but gettering is ineffective when distance between channel region and contact hole is increased

Engineering Contradiction:
Improvegettering effectivenessVSAvoiddistance from channel to contact hole
Core Design Contradiction:
ReliabilityVSLength of stationary object

Solution Approach 1:

The invention segments the gettering function by creating multiple gettering sites distributed across the semiconductor layer, not relying on a single contact hole. This includes using the contact hole region, the crystallization-inducing metal layer itself, and the capping layer as separate gettering regions, ensuring effective metal removal even when contact holes are positioned far from the channel region.

Inventive Principle:
Principle #1Segmentation

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

This approach enhances the electrical characteristics of TFTs by effectively removing crystallization-inducing metals, reducing leakage currents, and preventing substrate damage, while maintaining cost-effective and efficient fabrication processes.

Implementation Method 1

controlled diffusion of crystallization-inducing metals like Ni, Pd, or Ag to form poly-Si

Methodology Applied
Scientific EffectDiffusion: Diffusion

Implementation Method 2

crystallized using a crystallization-inducing metal

Methodology Applied
Scientific EffectCrystallization: Crystallisation

Implementation Method 3

phase-change the a-Si layer into a poly-Si layer

Methodology Applied
Scientific EffectPhase change: Phase Change

Implementation Method 4

A crystallization-inducing metal can be effectively gettered from channel regions of the semiconductor layer

Methodology Applied
Scientific EffectGettering: Gettering

Data Source

PatentEP2146371B1Method of fabricating thin film transistor
Publication Date: 2016.06.29 SAMSUNG DISPLAY CO LTD
  • EP2146371B1 patent drawingFigure 1A~1D
  • EP2146371B1 patent drawingFigure 2A
  • EP2146371B1 patent drawingFigure 2B

AI summary

A thin film transistor (TFT), a method of fabricating the same, and an organic light emitting diode (OLED) display device having the TFT. The TFT includes: a substrate; a polycrystalline silicon (poly-Si) semiconductor layer disposed on the substrate, including source, drain, and channel regions, a crystallization-inducing metal, first gettering sites disposed on opposing edges of the semiconductor layer, and a second gettering site spaced apart from the first gettering sites; a gate insulating layer disposed on the semiconductor layer; a gate electrode disposed on the gate insulating layer; an interlayer insulating layer disposed on the gate electrode; and source and drain electrodes disposed on the interlayer insulating layer and electrically connected to the source and drain regions of the semiconductor layer.