Poly(siloxane-etherimide) Compositions for Electrical Tracking Resistance

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Solution Overview

Problem

There is a need for poly(siloxane-etherimide) compositions with excellent electrical tracking resistance without compromising material cost, processability, or mechanical properties, as existing materials often fail to provide sufficient resistance while maintaining these factors.

Innovation Solution

Incorporating a polyester or fillers like talc and calcium carbonate into poly(siloxane-etherimide) compositions, which significantly improves electrical tracking resistance while maintaining acceptable mechanical properties.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Strength

If poly(siloxane-etherimide) is used as a high performance material, then mechanical properties and chemical resistance are improved, but electrical tracking resistance is insufficient

Engineering Contradiction:
Improvemechanical propertiesVSAvoidelectrical tracking resistance
Core Design Contradiction:
StrengthVSReliability

Solution Approach 1:

The patent creates a composite material system by combining poly(siloxane-etherimide) base polymer with specific additives including polyesters (such as PBT, PET), fillers (talc, calcium carbonate), and inorganic compounds (boron compounds, zinc compounds). This composite approach allows the material to achieve both high mechanical properties from the base polymer and improved electrical tracking resistance through the synergistic effect of the additives, resolving the contradiction between mechanical strength and electrical tracking resistance.

Inventive Principle:
Principle #40Composite materials

2Reliability

If additives are added to improve electrical tracking resistance, then CTI rating is improved, but material cost and processability may be affected

Engineering Contradiction:
Improveelectrical tracking resistanceVSAvoidprocessability
Core Design Contradiction:
ReliabilityVSEase of manufacture

Solution Approach 1:

The patent optimizes the concentration ranges of various additives to achieve the desired electrical tracking resistance while maintaining processability. Specifically, it specifies polyesters at 1-30 wt%, fillers at 1-50 wt%, and inorganic compounds at 1-20 wt% of the total composition. These parameter optimizations ensure that the material achieves CTI rating improvements without excessive viscosity increase or processing difficulty, balancing electrical performance with manufacturing ease.

Inventive Principle:
Principle #35Parameter changes

3Reliability

If high concentration of additives is used to achieve excellent electrical tracking resistance, then CTI rating increases, but mechanical properties may deteriorate

Engineering Contradiction:
Improveelectrical tracking resistanceVSAvoidmechanical properties
Core Design Contradiction:
ReliabilityVSStrength

Solution Approach 1:

The patent employs a multi-component additive strategy where different additives serve specific functions: polyesters provide electrical tracking resistance improvement, fillers like talc and calcium carbonate enhance mechanical properties and cost-effectiveness, and inorganic compounds provide additional electrical resistance. This localized functional assignment ensures that each component contributes to specific properties, allowing the material to achieve excellent electrical tracking resistance while maintaining or even improving mechanical properties through the synergistic combination rather than relying on high concentrations of a single additive.

Inventive Principle:
Principle #3Local quality

Data Source

PatentEP3262123B1Electrical tracking resistance compositions, articles formed therefrom, and methods of manufacture thereof
Publication Date: 2019.04.17 SABIC GLOBAL TECHNOLOGIES BV
  • EP3262123B1 patent drawing
  • EP3262123B1 patent drawing
  • EP3262123B1 patent drawing

AI summary

A poly(siloxane-etherimide) composition comprising, based on the total weight of the composition, 70 to 90 wt% of a poly(siloxane-etherimide); and an additive comprising a polyester, a filler, or a combination thereof; wherein the filler comprises talc, calcium carbonate, or a combination comprising at least one of the foregoing; and wherein the composition has a number of drops to tracking at 250 volts of greater than or equal to 50 drops determined according to ASTM D-3638-85.