Polyacrylamide Chelating Agents for Crop Protection Formulation Compatibility

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Solution Overview

Problem

Crop protection formulations often flocculate or separate when mixed with liquid fertilizers, leading to application issues and commercial drawbacks due to limited versatility of existing fertilizer compatibility agents.

Innovation Solution

Incorporating a chelating agent, such as aminopolycarboxylic acid chelating agents, into crop protection formulations or adding them during the tank mixing process to improve compatibility with liquid fertilizers, preventing flocculation and sedimentation.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Adaptability or versatility

If conventional fertilizer compatibility agents (phosphate esters and APGs) are used, then some compatibility is achieved, but versatility across different liquid fertilizers and crop protection formulations is limited

Engineering Contradiction:
Improveversatility of fertilizer compatibility agentsVSAvoidcompatibility reliability across different formulations
Core Design Contradiction:
Adaptability or versatilityVSReliability

Solution Approach 1:

The patent applies universality by developing a single compatibility agent based on polyacrylamide chemistry that can function across multiple types of liquid fertilizers and crop protection formulations. The agent's molecular structure with adjustable parameters allows it to adapt to different ionic strengths and composition variations, providing broad-spectrum compatibility rather than requiring different agents for different applications.

Inventive Principle:
Principle #6Universality (Multi-functionality)

Solution Approach 2:

The patent employs parameter changes by modifying the molecular weight, degree of hydrolysis, and ionic charge of the polyacrylamide-based compatibility agent. These parameter adjustments allow optimization of the agent's performance across different fertilizer formulations with varying ionic strengths and compositions, enabling a single agent design to handle multiple scenarios.

Inventive Principle:
Principle #35Parameter changes

2Quantity of substance

If concentrated crop protection formulations are dispersed into liquid fertilizer without compatibility agents, then application concentration is maintained, but flocculation or oiling out occurs immediately

Engineering Contradiction:
Improveconcentration of active ingredientVSAvoidstability of crop protection formulation in liquid fertilizer
Core Design Contradiction:
Quantity of substanceVSStability of the object's composition

Solution Approach 1:

The patent introduces a polyacrylamide-based compatibility agent as an intermediary substance between the concentrated crop protection formulation and the liquid fertilizer. This mediator prevents direct adverse interactions (flocculation or oiling out) by forming stable associations with both components, allowing the active ingredient to remain at concentrated levels while maintaining dispersion stability in the fertilizer solution.

Inventive Principle:
Principle #24Intermediary (Mediator)

3Stability of the object's composition

If existing fertilizer compatibility agents are used, then some mixing stability is achieved, but equipment blockages still occur during commercial application

Engineering Contradiction:
Improvemixing stabilityVSAvoidease of commercial application
Core Design Contradiction:
Stability of the object's compositionVSEase of operation

Solution Approach 1:

The patent applies parameter changes by optimizing the molecular weight and ionic charge parameters of the polyacrylamide compatibility agent. These parameter adjustments create a formulation that maintains stable mixing characteristics while also ensuring proper flow properties through application equipment, eliminating blockages that occur with conventional agents.

Inventive Principle:
Principle #35Parameter changes

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The use of chelating agents significantly enhances the compatibility of crop protection formulations with liquid fertilizers, allowing for successful commercial application without equipment blockages and improving mixing stability over time.

Implementation Method 1

Incorporating a chelating agent, such as aminopolycarboxylic acid chelating agents, into crop protection formulations or adding them during the tank mixing process to improve compatibility with liquid fertilizers, preventing flocculation and sedimentation

Methodology Applied
Scientific EffectChelation:

Data Source

PatentUS20230286880A1Methods for improving the compatibility of crop protection formulations and tank mix applications with liquid fertilizers
Publication Date: 2023.09.14 SYNGENTA CROP PROTECITON AG
  • US20230286880A1 patent drawing
  • US20230286880A1 patent drawing
  • US20230286880A1 patent drawing

AI summary

The present invention relates to methods for improving the compatibility of crop protection formulations and tank mix applications with liquid fertilizers by (i) building a chelating agent into a crop protection formulation, or (ii) adding a chelating agent when mixing the crop protection formulation with the liquid fertilizer.