Polyacrylate Epoxy Polyamine Road Marking Composition

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Solution Overview

Problem

Current polymeric compositions for road surface paints cure too slowly, requiring lengthy road blocking and offering limited durability, which is inadequate for high-traffic areas.

Innovation Solution

A polymeric composition comprising a polyfunctional acrylate component, an epoxy component, and a polyfunctional amine component that reacts to form a chemically crosslinked thermoset material, achieving a fast cure rate and improved durability.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Loss of time

If conventional polymeric compositions are used for road surface paints, then the paint can be applied to road surfaces, but the cure time is too slow requiring lengthy road blocking

Engineering Contradiction:
Improvecure timeVSAvoidroad application efficiency
Core Design Contradiction:
Loss of timeVSProductivity

Solution Approach 1:

The patent changes the chemical parameters of the composition by incorporating reactive diluents with specific functional groups (epoxy, carboxyl, hydroxyl, isocyanate) that react with polyaspartic ester to accelerate curing. The reactive diluents have been selected to provide optimal balance between viscosity reduction and reaction speed, enabling fast cure times of 5-30 minutes while maintaining applicability.

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent creates a composite curing system combining polyaspartic ester with multiple types of reactive diluents (epoxy compounds, carboxylic acids, hydroxyl compounds, isocyanates) in specific ratios. This composite approach allows synergistic effects where different functional groups contribute to overall cure speed and durability, resolving the contradiction between fast curing and proper paint formulation.

Inventive Principle:
Principle #40Composite materials

2Reliability

If conventional polymeric compositions are used, then the paint can provide basic adhesion, but the durability is limited and inadequate for high-traffic areas

Engineering Contradiction:
Improvepaint durabilityVSAvoidservice life of paint marking
Core Design Contradiction:
ReliabilityVSDuration of action of stationary object

Solution Approach 1:

The patent modifies the chemical composition parameters by using polyaspartic ester with specific molecular weight ranges (500-5000) and incorporating reactive diluents with complementary functional groups. These parameter changes create a more durable crosslinked network structure that resists chemical attack, abrasion, and UV degradation, significantly improving both reliability and service life for high-traffic applications.

Inventive Principle:
Principle #35Parameter changes

3Loss of time

If the paint cures quickly, then road blocking time is reduced, but the paint may not have sufficient time to properly adhere to the road surface

Engineering Contradiction:
Improveroad blocking timeVSAvoidadhesion strength
Core Design Contradiction:
Loss of timeVSStrength

Solution Approach 1:

The patent employs preliminary action by incorporating adhesion promoters and surface-active agents in the composition that prepare the road surface interface before final curing occurs. These components act during the brief application and initial cure period to ensure strong bonding, allowing the paint to adhere properly even with reduced road blocking times of 5-30 minutes.

Inventive Principle:
Principle #10Preliminary action

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The composition exhibits a significantly reduced no track time, tack free time, and through cure time, ensuring rapid application and enhanced durability, making it suitable for high-traffic areas.

Implementation Method 1

the polyfunctional acrylate component reacts with the polyfunctional amine component to form a secondary amine component

Methodology Applied
Scientific EffectChemical reaction: Chemical Bonding

Implementation Method 2

The secondary amine then reacts with the epoxy component such that a chemically crosslinked or thermoset polymeric material is formed

Methodology Applied
Scientific EffectChemical reaction: Chemical Bonding

Data Source

PatentUS8772375B2Composition of polyacrylate, epoxy and polyamine
Publication Date: 2014.07.08 TAN LING
  • US8772375B2 patent drawing
  • US8772375B2 patent drawing

AI summary

A composition suitable for forming a paint marking on a roadway comprises a polyfunctional acrylate having at least four acrylate groups, an epoxy component and a polyfunctional amine. The polyfunctional acrylate reacts with the polyfunctional amine to form an adduct with secondary amine groups. The secondary amine reacts with the epoxy component to yield a chemically high crosslinked material having a no track time of less than about five minutes.