Polyalkylene Carbonate Resin Composition for Eco-Friendly Decorative Materials

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Solution Overview

Problem

Existing synthetic resin-based decorating materials, such as PVC, pose environmental concerns due to the generation of harmful gases and pollutants during burning and disposal, and lack shape retention performance at high temperatures.

Innovation Solution

A polyalkylene carbonate resin composition is developed, comprising a base resin of polyalkylene carbonate and a thermoplastic resin, with added compatibilizers, plasticizers, crosslinking agents, heat stabilizers, and processing aids, which improves shape retention, dimensional stability, and processability while reducing harmful emissions.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Object-affected harmful factors

If polyalkylene carbonate resin alone is used for wallpaper production, then environment-friendliness is improved, but shape retention at room temperature deteriorates

Engineering Contradiction:
Improveharmful emissions during burningVSAvoidshape retention at room temperature
Core Design Contradiction:
Object-affected harmful factorsVSShape

Solution Approach 1:

The patent uses a composite material system consisting of polyalkylene carbonate resin as the base polymer combined with specific additives including crosslinking agents (silane compounds), chain extenders (carboxylic acid compounds), and plasticizers. This composite approach allows the material to maintain the environmental benefits of polyalkylene carbonate while gaining improved shape retention and dimensional stability through the synergistic effects of the additives.

Inventive Principle:
Principle #40Composite materials

Solution Approach 2:

The patent changes the chemical and physical parameters of the polyalkylene carbonate resin by controlling the molecular weight (10,000 to 1,000,000), incorporating specific ratios of crosslinking agents (0.1-10 parts by weight per 100 parts resin) and chain extenders (0.1-10 parts by weight per 100 parts resin). These parameter adjustments enable the resin to achieve both environmental friendliness and adequate shape retention performance.

Inventive Principle:
Principle #35Parameter changes

2Ease of manufacture

If PVC resin is used for decorating materials, then processability is improved, but harmful gas generation during burning increases

Engineering Contradiction:
ImproveprocessabilityVSAvoidharmful gas generation during burning
Core Design Contradiction:
Ease of manufactureVSObject-generated harmful factors

Solution Approach 1:

The patent converts the potential harm of using conventional PVC by replacing it with polyalkylene carbonate resin, which is derived from renewable resources and produces minimal harmful emissions when burned. The resin maintains adequate processability through the addition of plasticizers and processing aids, thereby converting an environmentally harmful material into an eco-friendly alternative without sacrificing manufacturing ease.

Inventive Principle:
Principle #22Blessing in disguise (Convert harm into benefit)

Solution Approach 2:

The patent changes the base material from PVC to polyalkylene carbonate resin and adjusts the compositional parameters by incorporating specific amounts of plasticizers (5-50 parts by weight per 100 parts resin) and processing aids (0.1-5 parts by weight per 100 parts resin). These parameter changes ensure that the new material achieves processability comparable to PVC while eliminating the harmful gas generation issue.

Inventive Principle:
Principle #35Parameter changes

3Shape

If polyalkylene carbonate resin composition is optimized for shape retention, then dimensional stability at high temperature is improved, but manufacturing complexity increases

Engineering Contradiction:
Improvedimensional stability at high temperatureVSAvoidmanufacturing process complexity
Core Design Contradiction:
ShapeVSDevice complexity

Solution Approach 1:

The patent applies preliminary action by incorporating crosslinking agents and chain extenders during the resin composition formulation stage, which pre-establish the molecular network structure necessary for high-temperature dimensional stability. The silane crosslinking agents form three-dimensional networks that lock the molecular structure, while chain extenders increase molecular weight and reduce chain mobility. This preliminary structuring ensures shape retention is built into the material itself, reducing the need for complex post-processing controls.

Inventive Principle:
Principle #10Preliminary action

Solution Approach 2:

The patent uses silane crosslinking agents as intermediaries that bridge polymer chains to form a three-dimensional network structure. These crosslinking agents act as mediators between the polyalkylene carbonate resin molecules, creating strong intermolecular bonds that provide dimensional stability at high temperatures without requiring complex manufacturing processes. The crosslinking reaction occurs during processing, automatically establishing the stable structure.

Inventive Principle:
Principle #24Intermediary (Mediator)

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The composition provides an environment-friendly decorating material with excellent shape retention and heat stability, minimizing harmful emissions during production, use, and disposal, and enhancing processability.

Implementation Method 1

0.01 to 10 parts by weight of a crosslinking agent, a chain extender, or a mixture thereof (D)

Methodology Applied
Scientific EffectCrosslinking reaction: Chemical Bonding

Implementation Method 2

0.01 to 10 parts by weight of a crosslinking agent, a chain extender, or a mixture thereof (D)

Methodology Applied
Scientific EffectChain extension reaction: Chemical Bonding

Implementation Method 3

1 to 80 parts by weight of a plasticizer (C)

Methodology Applied
Scientific EffectGlass transition: Phase Change

Implementation Method 4

0.01 to 5 parts by weight of a heat stabilizer (E)

Methodology Applied
Scientific EffectThermal degradation prevention: Heat Treatment

Data Source

PatentEP2668235B1Polymer blend composition based on carbon dioxide and environment-friendly decorating materials produced therefrom
Publication Date: 2020.07.29 SK INNOVATION CO LTD
  • EP2668235B1 patent drawingFigure 1
  • EP2668235B1 patent drawing
  • EP2668235B1 patent drawing

AI summary

Provided is a polyalkylene carbonate resin composition for producing a decorating material and an environment-friendly polyalkylene carbonate resin decorating material produced therefrom, and more particularly to polyalkylene carbonate resin composition for producing a decorating material in which a polymer additive is input to impart heat resistance and shape stability of the decorating material, a crosslinker and a chain extender is input to improve the processability at a processing temperature, and a flame retardant agent is added to impart a flame retardant effect, and an environment-friendly polyalkylene carbonate resin decorating material produced therefrom. An environment-friendly polyalkylene carbonate resin decorating material having excellent thermal stability, processability, and dimensional stability can be produced by using the composition according to the present invention.