Polyamide Coated Filter Membrane for Acidic Liquid Purity

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Solution Overview

Problem

Nylon filter membranes used in microelectronic device processing are ineffective or sub-optimal due to metal ion extraction from acidic liquids and limited solvent compatibility, leading to contamination and reduced purity of filtered liquids.

Innovation Solution

A coated filter membrane with a porous polymeric layer and a crosslinked polyamide film coating, using a solvent like propanol for polyamide coating that is non-acidic and non-ionic, avoiding the use of formic acid and calcium chloride, which enhances filtration performance and stability in acidic environments.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If nylon filter membranes are used for filtering acidic liquids in microelectronic device processing, then filtration function is provided, but metal ions are extracted from the nylon into the acidic liquid causing contamination

Engineering Contradiction:
Improvefiltration effectivenessVSAvoidmetal ion extraction
Core Design Contradiction:
ReliabilityVSObject-generated harmful factors

Solution Approach 1:

The patent removes the problematic metal catalyst (magnesium) from the filter membrane structure by using a metal-catalyst-free polymerization method to create the polyamide coating. This eliminates the source of metal ion extraction that contaminates acidic liquids during filtration.

Inventive Principle:
Principle #2Taking out (Extraction)

Solution Approach 2:

The patent changes the chemical composition parameters of the filter membrane by using specific polyamide polymers with controlled metal content (less than 10 ppm, preferably less than 1 ppm) and adjusting the coating formulation to exclude metal catalysts, thereby preventing metal ion extraction into acidic liquids.

Inventive Principle:
Principle #35Parameter changes

2Ease of manufacture

If traditional solvents like formic acid or calcium chloride are used for polyamide coating, then coating is achieved, but solvent residues contaminate the filtered liquid and reduce purity

Engineering Contradiction:
Improvecoating processabilityVSAvoidliquid purity
Core Design Contradiction:
Ease of manufactureVSReliability

Solution Approach 1:

The patent removes harmful solvent residues by replacing traditional solvents (formic acid, calcium chloride) with alternative solvents that do not leave contaminating residues, thereby maintaining liquid purity in microelectronic device processing applications.

Inventive Principle:
Principle #2Taking out (Extraction)

Solution Approach 2:

The patent changes the solvent system parameters by using solvents with appropriate boiling points and volatility characteristics that allow complete evaporation without residue, or solvents that are compatible with the filtration application and do not contaminate the filtered liquid.

Inventive Principle:
Principle #35Parameter changes

3Stability of the object's composition

If nylon filter membranes are used to provide inertness and solvent resistance, then durability is improved, but solvent compatibility is limited reducing preparation options

Engineering Contradiction:
Improvechemical inertnessVSAvoidsolvent compatibility
Core Design Contradiction:
Stability of the object's compositionVSAdaptability or versatility

Solution Approach 1:

The patent changes the chemical parameter of the filter membrane by using polyamide polymers with specific functional groups and chemical structures that provide both chemical stability and broad solvent compatibility, allowing the membrane to withstand various solvents used in microelectronic device processing without degradation.

Inventive Principle:
Principle #35Parameter changes

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The coated filter membrane effectively removes contaminants and impurities from acidic liquids, maintaining high purity and reducing metal ion extraction, thereby improving the reliability of microelectronic device processing.

Implementation Method 1

a porous polymeric filter layer that is coated with a layer that contains cross-linked polyamide polymer... to filter a fluid such as a liquid chemical to remove unwanted material from the fluid

Methodology Applied
Scientific EffectFiltration: Filter (physical)

Implementation Method 2

Exposing that type of nylon of a filter membrane to an acidic liquid can tend to cause the metal (e.g., magnesium) to be extracted from the nylon into the acidic fluid that is being filtered... maintaining high purity and reducing metal ion extraction

Methodology Applied
Scientific EffectChemical resistance:

Implementation Method 3

coated with a layer that contains cross-linked polyamide polymer... crosslinking the polyamide

Methodology Applied
Scientific EffectCrosslinking:

Data Source

PatentUS11413586B2Polyamide coated filter membrane, filters, and methods
Publication Date: 2022.08.16 ENTEGRIS INC
  • US11413586B2 patent drawing
  • US11413586B2 patent drawing
  • US11413586B2 patent drawing

AI summary

Described are filter membranes coated with a polyamide, filters and filter cartridges that include the filter membranes, and methods of using and making the filter membranes.