Polyamide Inliner Melt Stiffness for Pipeline Reliability

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Solution Overview

Problem

Existing pipeline materials, particularly those based on polyethylene, face issues such as poor swelling and diffusion behavior, susceptibility to stress-cracking, and inadequate adhesion with hardening plastics, limiting their effectiveness and durability for transporting fluids like crude oil and waste water, and are restricted to low operating temperatures and small diameters due to production challenges with polyamide materials.

Innovation Solution

A polyamide moulding composition with increased molecular weight via the addition of a compound containing at least two carbonate units is used to create an inliner with improved melt stiffness, allowing for reliable production of large-dimension pipelines with uniform wall thickness and enhanced processing efficiency.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Ease of manufacture

If polyethylene is used as inliner material, then ease of manufacture is improved, but reliability deteriorates due to poor swelling behavior, poor diffusion behavior, stress-cracking susceptibility, and inadequate adhesion

Engineering Contradiction:
Improveease of manufactureVSAvoidreliability
Core Design Contradiction:
Ease of manufactureVSReliability

Solution Approach 1:

The patent changes the material parameters by switching from polyethylene to polyamide as the base polymer, and by controlling the molecular weight through condensation processes. This parameter change resolves the contradiction by providing a material that maintains manufacturability while significantly improving reliability through better swelling behavior, diffusion behavior, stress-cracking resistance, and adhesion properties.

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent employs composite material strategies by combining polyamide with specific additives and controlling molecular weight through condensation with compounds containing carbonate units. This creates a composite structure that leverages the advantages of polyamide while mitigating its disadvantages, achieving both ease of manufacture and high reliability simultaneously.

Inventive Principle:
Principle #40Composite materials

2Reliability

If polyamide is used to produce large-dimension pipelines, then reliability is improved, but device complexity worsens due to production challenges

Engineering Contradiction:
ImprovereliabilityVSAvoiddevice complexity
Core Design Contradiction:
ReliabilityVSDevice complexity

Solution Approach 1:

The patent resolves the production complexity issue by changing the molecular weight parameters of the polyamide through controlled condensation processes. By optimizing the molecular weight and using specific compounds containing carbonate units, the patent achieves uniform wall thickness and reliable large-dimension pipeline production without excessive complexity.

Inventive Principle:
Principle #35Parameter changes

3Ease of operation

If polyethylene inliner is used, then ease of operation is improved, but productivity deteriorates due to restriction to low operating temperatures and small diameters

Engineering Contradiction:
Improveease of operationVSAvoidproductivity
Core Design Contradiction:
Ease of operationVSProductivity

Solution Approach 1:

The patent changes the operating temperature parameter by switching to polyamide material, which enables operation at higher temperatures compared to polyethylene. This parameter change simultaneously improves productivity by allowing larger diameter pipelines to be used, while maintaining ease of operation through the material's inherent properties.

Inventive Principle:
Principle #35Parameter changes

4Reliability

If conventional polyamide is used for large-dimension pipelines, then reliability is improved, but manufacturing precision deteriorates due to inadequate melt stiffness

Engineering Contradiction:
ImprovereliabilityVSAvoidmanufacturing precision
Core Design Contradiction:
ReliabilityVSManufacturing precision

Solution Approach 1:

The patent resolves the manufacturing precision issue by changing the molecular weight parameters of the polyamide through controlled condensation processes. By optimizing the molecular weight and using specific compounds containing carbonate units, the patent achieves uniform wall thickness and consistent dimensional accuracy, thereby improving manufacturing precision while maintaining reliability.

Inventive Principle:
Principle #35Parameter changes

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The increased melt stiffness of the polyamide composition results in lower motor load and higher processing throughputs, enabling cost-effective production of large-dimension pipelines with improved durability and performance across a range of operating conditions.

Implementation Method 1

whose molecular weight has been increased by condensation, via addition of a compound having at least two carbonate units

Methodology Applied
Scientific EffectCondensation: Condensation

Data Source

PatentUS8679270B2Use of a shaped part made of a polyamide shaped component as an inliner for a conduit
Publication Date: 2014.03.25 EVONIK OPERATIONS GMBH

AI summary

A pipe or hose composed of a polyamide moulding composition whose molecular weight has been increased by condensation, via addition of a compound having at least two carbonate units in a quantitative proportion of from 0.005 to 10% by weight, based on polyamide, wherea) a starting polyamide moulding composition was provided,b) a mixture of the starting polyamide moulding composition and of the compound having at least two carbonate units was produced,c) the premix was, if desired, stored and/or transported, andd) the premix was then processed to give the moulding, this step being the first in which the increase of molecular weight by condensation occurred,the moulding being a pipe or hose whose external diameter is at least 25 mmis used as inliner for a pipeline.