Polyamide Sinter Powder Broadens Laser Sintering Window

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Solution Overview

Problem

Existing sinter powders for selective laser sintering have a reduced sintering window, leading to warpage issues in produced shaped bodies, which limits their usability and requires frequent recycling.

Innovation Solution

A sinter powder composition comprising at least one semicrystalline polyamide, nylon-6I/6T, and a polyaryl ether, which broadens the sintering window, reducing warpage and enhancing recyclability.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Manufacturing precision

If existing sinter powder compositions are used, then the sintering window is reduced, but warpage of shaped bodies increases

Engineering Contradiction:
Improvesintering windowVSAvoidwarpage of shaped bodies
Core Design Contradiction:
Manufacturing precisionVSShape

Solution Approach 1:

The patent applies composite materials by combining polyamide 6I/6T with specific additives (polyethylene glycol with Mn=1000 and zinc stearate) to create a sinter powder composition that achieves both a broad sintering window and minimal warpage. The composite formulation allows the material to maintain structural integrity during sintering while enabling precise dimensional control of the shaped bodies.

Inventive Principle:
Principle #40Composite materials

2Reliability

If existing sinter powder compositions are used, then warpage occurs frequently, but recyclability of sinter powder is reduced

Engineering Contradiction:
Improverecyclability of sinter powderVSAvoidwarpage of shaped bodies
Core Design Contradiction:
ReliabilityVSShape

Solution Approach 1:

The patent implements discarding and recovering by formulating a sinter powder composition that maintains high recyclability through careful selection of additives that do not degrade during thermal cycling. The polyethylene glycol and zinc stearate components allow the powder to be reused multiple times without significant loss of sintering performance or increase in warpage, enabling efficient recovery and reuse of the sinter powder.

Inventive Principle:
Principle #34Discarding and recovering

3Productivity

If sintering window is reduced, then production efficiency decreases, but process complexity increases due to frequent recycling

Engineering Contradiction:
Improveproduction efficiencyVSAvoidprocess complexity
Core Design Contradiction:
ProductivityVSDevice complexity

Solution Approach 1:

The patent applies parameter changes by optimizing the chemical composition of the sinter powder, specifically adjusting the ratios of polyamide 6I/6T, polyethylene glycol (Mn=1000), and zinc stearate to achieve ideal sintering characteristics. This compositional parameter optimization broadens the sintering window and reduces warpage, thereby improving production efficiency and simplifying the overall manufacturing process.

Inventive Principle:
Principle #35Parameter changes

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The proposed sinter powder composition significantly reduces warpage in shaped bodies, improves elongation at break, and maintains high recyclability even after thermal aging, resulting in improved mechanical properties and process efficiency.

Implementation Method 1

selectively exposing a polymer powder in a chamber to a laser beam. The powder melts, and the molten particles coalesce and solidify again.

Methodology Applied
Scientific EffectLaser heating: Laser

Implementation Method 2

The powder melts, and the molten particles coalesce and solidify again.

Methodology Applied
Scientific EffectMelting: Melting

Implementation Method 3

The powder melts, and the molten particles coalesce and solidify again.

Methodology Applied
Scientific EffectCoalescence: Cohesion

Data Source

PatentUS12214548B2Processes for producing a shaped body using polyamide blends containing a polyarylether
Publication Date: 2025.02.04 BASF SE
  • US12214548B2 patent drawing
  • US12214548B2 patent drawing
  • US12214548B2 patent drawing

AI summary

The present invention relates to a process for producing a shaped body by selective laser sintering of a sinter powder (SP). The sinter powder (SP) comprises at least one semicrystalline polyamide, at least one nylon-6I/6T and at least one polyaryl ether. The present invention further relates to a shaped body obtainable by the process of the invention and to the use of a polyaryl ether in a sinter powder (SP) for broadening the sintering window (WSP) of the sinter powder (SP).