Polyamide Tank Composition for Fluid Barrier Injection Molding

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Solution Overview

Problem

Current methods for enhancing the barrier properties of plastic materials, such as extrusion-blow molding and multilayer articles, are costly and prone to delamination issues, and struggle to achieve effective impermeability while maintaining mechanical and processability properties.

Innovation Solution

A specific polyamide composition with impact modifiers is used in injection molding to produce tanks with high barrier properties, characterized by suitable viscosity and permeability, allowing for the manufacture of tanks with excellent fluid barrier and mechanical properties without the constraints of extrusion-blow molding.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If multilayer articles are used to enhance barrier properties, then permeability to fluids is reduced, but manufacturing cost increases and delamination problems occur

Engineering Contradiction:
Improvebarrier propertiesVSAvoidmanufacturing cost and complexity
Core Design Contradiction:
ReliabilityVSEase of manufacture

Solution Approach 1:

The patent changes the chemical composition parameters of the polyamide by incorporating specific additives (cyclodextrins, silicas, binding fillers) that modify the material's inherent barrier properties. This allows achieving high barrier performance through compositional modification rather than structural complexity, resolving the contradiction between barrier properties and manufacturing ease.

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent creates a composite polyamide material by combining base polyamide with functional additives (cyclodextrins for molecular inclusion, silicas for barrier enhancement, binding fillers for structural integrity). This composite approach achieves multilayer-like barrier properties in a single homogeneous material, avoiding delamination while maintaining manufacturing simplicity.

Inventive Principle:
Principle #40Composite materials

2Reliability

If nanofillers are added to reduce permeability, then barrier properties improve, but manufacturing complexity increases due to exfoliation requirements

Engineering Contradiction:
Improvepermeability reductionVSAvoidprocessing complexity
Core Design Contradiction:
ReliabilityVSDevice complexity

Solution Approach 1:

The patent uses binding fillers as intermediary materials that facilitate the dispersion and exfoliation of nanofillers within the polyamide matrix. These binding agents act as mediators between the nanofillers and the base polymer, enabling effective barrier properties without requiring complex external processing equipment or procedures.

Inventive Principle:
Principle #24Intermediary (Mediator)

Solution Approach 2:

The patent modifies the processing parameters by incorporating intercalation agents that enable exfoliation of nanofillers at standard processing temperatures and shear conditions. This transforms the complex exfoliation process into a routine part of normal injection molding, resolving the contradiction between barrier enhancement and processing simplicity.

Inventive Principle:
Principle #35Parameter changes

3Reliability

If surface treatment layers are deposited to reduce permeation, then barrier properties are enhanced, but manufacturing cost and process complexity increase

Engineering Contradiction:
Improvepermeation resistanceVSAvoiddeposition process complexity
Core Design Contradiction:
ReliabilityVSDevice complexity

Solution Approach 1:

The patent merges the barrier function with the base polyamide material itself by incorporating barrier-enhancing additives directly into the polymer matrix during compounding. This eliminates the need for separate surface deposition processes, combining the structural and barrier functions into a single integrated material solution.

Inventive Principle:
Principle #5Merging (Combining)

4Reliability

If extrusion-blow molding is used to manufacture tanks, then barrier properties can be achieved, but production of complex geometries and inserts is restricted

Engineering Contradiction:
Improvebarrier propertiesVSAvoidgeometric complexity
Core Design Contradiction:
ReliabilityVSAdaptability or versatility

Solution Approach 1:

The patent changes the material parameters by developing a polyamide composition with optimized rheological properties (viscosity, melt flow) that are specifically suited for injection molding. This allows the material to be processed into complex geometries and incorporate inserts while maintaining the barrier properties that would otherwise require extrusion-blow molding.

Inventive Principle:
Principle #35Parameter changes

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The process enables the production of tanks with improved mechanical and barrier properties, including low permeability to fluids, complex shapes, and reduced cycle times, while avoiding the drawbacks of existing methods like delamination and high costs.

Implementation Method 1

The polyamide composition exhibits an appropriate and sufficient viscosity and permeability to gasoline which makes possible the manufacture of tanks having an excellent compromise between the barrier properties toward fluids and the mechanical properties

Methodology Applied
Scientific EffectPermeation: Permeation

Data Source

PatentUS10364351B2Process for the manufacture of tanks having high barrier properties toward fluids
Publication Date: 2019.07.30 PERFORMANCE POLYAMIDES SAS

AI summary

The invention relates to a method for producing a tank having high fluid-barrier properties. According to the invention, a specific polyamide composition containing impact-resistance modifying agents is used in a first step to produce components by means of injection moulding and, subsequently, said components are assembled in order to obtain the tank. The viscosity and gasoline permeability of the polyamide composition are sufficient to allow the production of tanks that provide an excellent trade-off between fluid-barrier properties and mechanical properties.