Corrosion Resistant Metallic Honeycomb with Polyamideimide Coating

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Solution Overview

Problem

Existing metallic honeycombs face challenges in achieving both high strength and corrosion resistance, especially when used in corrosive environments, due to limitations in adhesive bonding and corrosion protection methods, which can lead to structural failure.

Innovation Solution

A corrosion-resistant coating composed of polyamideimide is applied to the edges and walls of metallic honeycombs to enhance adhesion and protect against corrosion, effectively sealing micro-cracks and maintaining bond strength with face sheets.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Object-affected harmful factors

If traditional corrosion resistant coatings (chromate, epoxy, phenolic) are applied to aluminum honeycomb, then corrosion resistance is improved, but adhesion strength and reliability in harsh environments deteriorate

Engineering Contradiction:
Improvecorrosion resistanceVSAvoidadhesion strength
Core Design Contradiction:
Object-affected harmful factorsVSReliability

Solution Approach 1:

The patent applies a composite coating system consisting of multiple layers: a primer layer (epoxy or phenolic) applied first, followed by a topcoat layer (polyurethane or polysiloxane) applied second. This multi-layer composite structure combines the corrosion-blocking capabilities of the primer with the environmental resistance and adhesion properties of the topcoat, resolving the contradiction between corrosion resistance and adhesion strength that plagues single-coat systems.

Inventive Principle:
Principle #40Composite materials

2Strength

If aluminum sheets are treated with surface coatings to enhance adhesive bonding, then peel strength is improved, but corrosion protection capability worsens

Engineering Contradiction:
Improvepeel strengthVSAvoidcorrosion protection
Core Design Contradiction:
StrengthVSObject-affected harmful factors

Solution Approach 1:

The coating system is segmented into functionally distinct layers: the primer layer serves as the corrosion barrier and bonding interface with the aluminum substrate, while the topcoat layer provides environmental resistance and maintains adhesion. This segmentation allows each layer to optimize its specific function without compromising the other, overcoming the trade-off between peel strength and corrosion protection.

Inventive Principle:
Principle #1Segmentation

3Strength

If honeycomb structures are made from thick aluminum sheets or certain alloys to increase strength, then structural strength is improved, but ease of manufacture using expansion process worsens

Engineering Contradiction:
Improvestructural strengthVSAvoidexpandability
Core Design Contradiction:
StrengthVSEase of manufacture

Solution Approach 1:

Instead of attempting to expand thick or stiff aluminum sheets (which is difficult or impossible), the patent inverts the manufacturing approach by using the corrugation process: aluminum sheets are first formed into corrugated configurations, then bonded together along node lines to create the honeycomb structure. This inversion of the manufacturing sequence makes it feasible to produce high-strength honeycomb from materials that would otherwise be unmanufacturable using traditional expansion methods.

Inventive Principle:
Principle #13The other way round (Inversion)

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The polyamideimide coating significantly increases corrosion resistance and maintains strong skin-core bonding characteristics, even in harsh environments, as demonstrated by reduced corrosion spots and holes in salt spray testing.

Implementation Method 1

effectively sealing micro-cracks and maintaining bond strength

Methodology Applied
Scientific EffectSealing:

Implementation Method 2

enhance adhesion and protect against corrosion

Methodology Applied
Scientific EffectAdhesion: Adhesive

Data Source

PatentEP2032272B1Corrosion resistant honeycomb
Publication Date: 2014.07.16 HEXCEL CORP
  • EP2032272B1 patent drawingFigure 1
  • EP2032272B1 patent drawingFigure 2~3

AI summary

Corrosion resistant metallic honeycomb composed of a plurality of honeycomb cells having cell walls that include cell edges that form the edge of the honeycomb. A corrosion resistant coating that contains polyamideimide is used to cover the cell walls and cell edges. The corrosion resistant coating is preferably applied after the honeycomb structure has been formed.