Polyamideimide Resin Composition Storage Stability

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Solution Overview

Problem

Aqueous polyamideimide resin compositions exhibit poor storage stability due to water being a poor solvent for polyamideimide resins, leading to challenges in maintaining working environment properties and coating film adhesion.

Innovation Solution

Incorporating 3-alkoxy-N,N-dimethylpropanamide as a solvent in combination with water to create a polyamideimide resin composition that enhances storage stability and working environment properties, while also forming a coating film with excellent adhesion.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Object-affected harmful factors

If water is used as the solvent medium in polyamideimide resin compositions, then working environment properties are improved, but storage stability deteriorates

Engineering Contradiction:
Improveworking environment propertiesVSAvoidstorage stability
Core Design Contradiction:
Object-affected harmful factorsVSStability of the object's composition

Solution Approach 1:

The patent introduces 3-alkoxy-N,N-dimethylpropanamide as an intermediary substance that mediates between water and polyamideimide resin. This intermediary solvent improves the compatibility between water and the resin, enabling the formation of stable aqueous resin compositions that maintain both working environment properties and storage stability.

Inventive Principle:
Principle #24Intermediary (Mediator)

Solution Approach 2:

The patent creates a composite solvent system combining water with 3-alkoxy-N,N-dimethylpropanamide. This composite approach leverages the advantages of both solvents: water provides excellent working environment properties while the 3-alkoxy-N,N-dimethylpropanamide component ensures storage stability by preventing resin precipitation and maintaining uniform dispersion.

Inventive Principle:
Principle #40Composite materials

2Stability of the object's composition

If conventional solvents like N-methyl-2-pyrrolidone are used, then solubility of polyamideimide resin is improved, but environmental safety and working environment properties deteriorate

Engineering Contradiction:
ImprovesolubilityVSAvoidenvironmental safety
Core Design Contradiction:
Stability of the object's compositionVSObject-affected harmful factors

Solution Approach 1:

The patent changes the chemical parameters of the solvent system by replacing conventional organic solvents with an aqueous system containing 3-alkoxy-N,N-dimethylpropanamide. This parameter change maintains the necessary solubility and stability characteristics while fundamentally improving environmental safety by eliminating harmful organic volatile compounds.

Inventive Principle:
Principle #35Parameter changes

3Object-affected harmful factors

If aqueous resin solutions are used to improve environmental safety, then storage stability deteriorates due to poor solvent properties

Engineering Contradiction:
Improveenvironmental safetyVSAvoidstorage stability
Core Design Contradiction:
Object-affected harmful factorsVSStability of the object's composition

Solution Approach 1:

The patent introduces 3-alkoxy-N,N-dimethylpropanamide as an intermediary substance that mediates between water and polyamideimide resin. This intermediary solvent improves the compatibility between water and the resin, enabling the formation of stable aqueous resin compositions that maintain both working environment properties and storage stability.

Inventive Principle:
Principle #24Intermediary (Mediator)

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The use of 3-alkoxy-N,N-dimethylpropanamide in the polyamideimide resin composition results in an aqueous resin system with improved storage stability and adhesion, suitable for use as a fluorine-based coating material, particularly in household electrical appliances and kitchen utensils.

Implementation Method 1

by using a 3-alkoxy-N,N-dimethylpropanamide as a solvent (synthesis solvent and coating material solvent), an aqueous polyamideimide resin composition (resin varnish) that provides excellent working environment properties and also exhibits excellent storage stability could be obtained

Methodology Applied
Scientific EffectSolvation: Solvation

Data Source

PatentUS11674039B2Polyamideimide resin composition and flourine-based coating material
Publication Date: 2023.06.13 RESONAC CORP

AI summary

Disclosed are a polyamideimide resin composition comprising (A) a polyamideimide resin, (B) a 3-alkoxy-N,N-dimethylpropanamide, and (C) water; and a fluorine-based coating material comprising the polyamideimide resin composition and a fluororesin.