Polycarbonate Resin Composition for ID Card Durability

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Solution Overview

Problem

Conventional resin compositions for cards, such as PVC and PET-G, lack sufficient mechanical strength and heat resistance, and polyester resin compositions exhibit poor transparency and reduced print resolution.

Innovation Solution

A resin composition containing 2-9% aliphatic polyester compound and 90% or more polycarbonate resin, with a glass transition temperature of 100-135°C, incorporating a white pigment and laser color former, specifically using ε-polycaprolactone and metal oxide-based laser color former for enhanced durability, heat resistance, and transparency.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Strength

If polyester resin composition is used to improve heat resistance and impact resistance, then mechanical strength is improved, but transparency deteriorates and print resolution is reduced

Engineering Contradiction:
Improvemechanical strengthVSAvoidtransparency
Core Design Contradiction:
StrengthVSIllumination intensity

Solution Approach 1:

The patent changes the chemical composition parameters by using polycarbonate resin as the base material instead of polyester resin, and precisely controls the content of aliphatic polyester compound to 2-9% by mass. This parameter optimization maintains mechanical strength while preserving transparency and print resolution, resolving the contradiction between strength improvement and transparency maintenance.

Inventive Principle:
Principle #35Parameter changes

2Ease of manufacture

If conventional resins like PVC or PET-G are used, then ease of processing is maintained, but durability and heat resistance are insufficient

Engineering Contradiction:
Improveease of processingVSAvoiddurability
Core Design Contradiction:
Ease of manufactureVSReliability

Solution Approach 1:

The patent creates a composite resin composition by combining polycarbonate resin (90% or more) with aliphatic polyester compound (2-9%). This composite structure leverages the high durability and heat resistance of polycarbonate while incorporating the processing advantages of polyester compounds, achieving both reliability and ease of manufacture simultaneously.

Inventive Principle:
Principle #40Composite materials

3Reliability

If polycarbonate resin composition is used to improve durability and heat resistance, then mechanical properties are enhanced, but processing difficulty increases

Engineering Contradiction:
ImprovedurabilityVSAvoidease of processing
Core Design Contradiction:
ReliabilityVSEase of manufacture

Solution Approach 1:

The patent optimizes the compositional parameters by limiting aliphatic polyester compound content to 2-9% by mass and controlling glass transition temperature to 100-135°C. These parameter changes modify the processing characteristics of polycarbonate resin, making it easier to process while maintaining high durability and heat resistance.

Inventive Principle:
Principle #35Parameter changes

4Manufacturing precision

If white pigment is added to improve opacity and printability, then transparency is reduced, but print resolution is improved

Engineering Contradiction:
Improveprint resolutionVSAvoidtransparency
Core Design Contradiction:
Manufacturing precisionVSIllumination intensity

Solution Approach 1:

The patent optimizes the white pigment content parameter to 10-30% by mass based on the total resin composition. This precise parameter control ensures sufficient print resolution and opacity while minimizing the impact on transparency, achieving optimal balance for card manufacturing applications.

Inventive Principle:
Principle #35Parameter changes

Data Source

PatentEP3778775B1Resin composition, resin sheet for card containing resin composition, and multilayer sheet
Publication Date: 2023.09.27 MITSUBISHI GAS CHEM CO INC
  • EP3778775B1 patent drawingFigure 1
  • EP3778775B1 patent drawing
  • EP3778775B1 patent drawing

AI summary

The present invention provides a resin composition, which contains: 2% by mass or more but less than 9% by mass of an aliphatic polyester compound; and a polycarbonate resin, wherein the resin composition further contains a white pigment in an amount of 10 to 30% by mass based on the mass of the whole resin composition.