Polycarbonate Resin Composition for Thin Films

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Solution Overview

Problem

Existing polycarbonate resin compositions fail to achieve excellent heat resistance, mechanical strength, and flame retardance, particularly in thin-walled molded products, due to issues with flowability and mechanical properties when using inorganic fillers and flame retardants in combination.

Innovation Solution

A polycarbonate resin composition containing a polycarbonate resin with a viscosity average molecular weight of 28,000 to 60,000, combined with a phosphorus-based flame retardant, a fibrous or plate-like inorganic filler, and a fluoropolymer, optimized in specific mass ratios to enhance heat resistance, mechanical strength, and flame retardance, especially in thin sheets or films.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Strength

If inorganic filler is added to improve mechanical strength, then mechanical strength is improved, but flowability is reduced

Engineering Contradiction:
Improvemechanical strengthVSAvoidflowability
Core Design Contradiction:
StrengthVSEase of manufacture

Solution Approach 1:

The patent adjusts the viscosity average molecular weight of the polycarbonate resin to a specific range (28,000 to 60,000) to optimize the balance between mechanical strength and flowability. This parameter change allows the resin to maintain adequate flow characteristics for extrusion molding while providing sufficient mechanical strength when combined with inorganic fillers.

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent creates a composite resin composition by combining polycarbonate resin with specific inorganic fillers (such as glass fibers, talc, or calcium carbonate) and flame retardants. This composite approach enhances mechanical strength while the carefully selected composition maintains workability for thin-walled extrusion molding.

Inventive Principle:
Principle #40Composite materials

2Object-affected harmful factors

If flame retardant is added to improve flame retardance, then flame retardance is improved, but heat resistance is reduced

Engineering Contradiction:
Improveflame retardanceVSAvoidheat resistance
Core Design Contradiction:
Object-affected harmful factorsVSTemperature

Solution Approach 1:

The patent specifies a precise viscosity average molecular weight range (28,000 to 60,000) for the polycarbonate resin to counterbalance the heat resistance reduction caused by flame retardant addition. This parameter optimization ensures that the resin maintains adequate heat resistance while achieving V-0 or V-1 flame retardance ratings in thin-walled products.

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent applies flame retardants locally within the resin matrix at controlled concentrations (typically 5-30 wt%), creating zones of flame retardancy without uniformly compromising the overall heat resistance of the material. This localized approach allows thin-walled products to achieve excellent flame retardance while maintaining sufficient heat resistance for electrical and electronic applications.

Inventive Principle:
Principle #3Local quality

3Length of moving object

If thickness is reduced to meet miniaturization requirements, then size is reduced, but flame retardance and mechanical properties deteriorate

Engineering Contradiction:
ImprovethicknessVSAvoidflame retardance
Core Design Contradiction:
Length of moving objectVSObject-affected harmful factors

Solution Approach 1:

The patent optimizes the viscosity average molecular weight of the polycarbonate resin to a higher range (28,000 to 60,000) compared to conventional resins. This parameter change enhances the resin's inherent flame retardance and mechanical properties, allowing thin-walled extrusions (0.8 mm or less) to achieve V-0 or V-1 UL94 ratings without requiring excessive filler loading that would compromise flowability.

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent develops a specialized composite formulation combining polycarbonate resin with inorganic fillers and flame retardants in optimized proportions. This composite structure provides enhanced flame retardance and mechanical strength at reduced thickness, enabling miniaturized electrical and electronic equipment housings to meet safety standards while maintaining structural integrity.

Inventive Principle:
Principle #40Composite materials

4Strength

If inorganic filler is added to improve mechanical properties, then mechanical properties are improved, but large-area thin-walled molding becomes difficult

Engineering Contradiction:
Improvemechanical propertiesVSAvoidmoldability
Core Design Contradiction:
StrengthVSEase of manufacture

Solution Approach 1:

The patent adjusts the viscosity average molecular weight to a specific range (28,000 to 60,000) that provides optimal balance between mechanical properties and melt flow characteristics. This parameter optimization enables the resin composition to be successfully extruded into large-area thin-walled products while maintaining adequate mechanical strength and dimensional stability.

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent uses specific inorganic fillers with controlled particle size distributions and aspect ratios to enhance mechanical properties locally within the resin matrix without excessively compromising overall flowability. This selective approach allows large-area extrusion molding of thin-walled products while maintaining sufficient mechanical strength.

Inventive Principle:
Principle #3Local quality

Data Source

PatentUS10508191B2Flame-retardant polycarbonate resin composition, sheet and film each using same, and method for producing said sheet or film
Publication Date: 2019.12.17 MITSUBISHI GAS CHEM CO INC
  • US10508191B2 patent drawing
  • US10508191B2 patent drawing
  • US10508191B2 patent drawing

AI summary

The present invention provides: a polycarbonate resin composition which contains 18-75% by mass of (A) a polycarbonate resin having a viscosity average molecular weight of 28,000-60,000, 5-30% by mass of (B) a phosphorus flame retardant, 18-50% by mass of (C) a fibrous or plate-like inorganic filler, and 0.1-2% by mass of (D) a fluoropolymer; and a sheet and a film, each of which uses this polycarbonate resin composition.