Reinforced Polycarbonate Sheet Surface Smoothness via Fiber Morphology

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Solution Overview

Problem

Conventional methods for producing aromatic polycarbonate resin sheets and films with glass reinforcing materials result in surface roughness and poor adhesiveness, affecting designability and appearance, especially during thermal shaping and painting.

Innovation Solution

Adjusting extrusion conditions and using a specific composition of aromatic polycarbonate resin, thermoplastic resin, and E-glass reinforcing material with a flat or elliptic cross-sectional shape, and optimizing processing parameters like barrel and roll temperatures in air-pressure or thermal press molding.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Strength

If glass fiber is blended into aromatic polycarbonate resin to improve mechanical properties, then bending strength and rigidity are improved, but surface roughness increases and transparency decreases

Engineering Contradiction:
Improvebending strengthVSAvoidsurface smoothness
Core Design Contradiction:
StrengthVSManufacturing precision

Solution Approach 1:

The patent changes the physical parameters of the glass fiber by specifying a particular length range (3-5mm) and cross-sectional shape (flat or elliptic) to optimize both mechanical reinforcement and surface finish. This parameter optimization allows the glass fiber to provide strength while minimizing surface roughness during extrusion and molding processes.

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent creates a composite material system combining aromatic polycarbonate resin with specifically shaped glass fibers. The composite achieves enhanced bending strength while the controlled morphology of the glass fiber dispersion maintains surface smoothness, resolving the contradiction between reinforcement and surface quality.

Inventive Principle:
Principle #40Composite materials

2Strength

If glass cloth is impregnated in organic solvent to produce reinforced resin sheet, then mechanical properties are improved, but productivity decreases due to solvent collection requirements

Engineering Contradiction:
ImproverigidityVSAvoidproduction efficiency
Core Design Contradiction:
StrengthVSProductivity

Solution Approach 1:

The patent extracts and eliminates the organic solvent impregnation step from the manufacturing process. Instead, it uses direct blending of glass fibers with aromatic polycarbonate resin in the melt state, thereby removing the productivity-limiting solvent collection requirement while still achieving reinforced mechanical properties.

Inventive Principle:
Principle #2Taking out (Extraction)

Solution Approach 2:

The patent replaces the chemical impregnation method (using organic solvents) with a mechanical mixing method in the melt state. This substitution eliminates the need for solvent handling and collection apparatus, improving productivity while maintaining the reinforcement effect through proper glass fiber selection.

Inventive Principle:
Principle #28Mechanics substitution (Replace mechanical system)

3Ease of manufacture

If non-reinforced layer is laminated to glass-reinforced sheet to improve punching workability, then workability is improved, but elastic modulus decreases

Engineering Contradiction:
Improvepunching workabilityVSAvoidelastic modulus
Core Design Contradiction:
Ease of manufactureVSStrength

Solution Approach 1:

The patent changes the physical parameters of the glass fiber (length and cross-sectional shape) to achieve optimal reinforcement efficiency. The specific parameters (3-5mm length, flat or elliptic cross-section) enable the glass fiber to provide sufficient elastic modulus while the resin matrix maintains adequate punching workability, eliminating the need for laminating non-reinforced layers.

Inventive Principle:
Principle #35Parameter changes

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The solution achieves sheets and films with improved bending characteristics, surface smoothness, and adhesiveness, enabling the production of high-quality, thermally shaped products suitable for electronic and electric apparatus housings.

Implementation Method 1

a fourth step of compressing the molten resin composition molded into a sheet with a cooling roll

Methodology Applied
Scientific EffectThermal conduction: Conduction (thermal)

Implementation Method 2

a third step of molding the molten resin composition into a sheet

Methodology Applied
Scientific EffectPlastic deformation: Plasticity

Data Source

PatentEP3133109B1Reinforced aromatic polycarbonate resin sheet or film and method for producing said sheet or film
Publication Date: 2019.08.14 MITSUBISHI GAS CHEM CO INC
  • EP3133109B1 patent drawingFigure 1
  • EP3133109B1 patent drawing
  • EP3133109B1 patent drawing

AI summary

Provided is an aromatic polycarbonate resin sheet/film which has excellent bending characteristics and surface smoothness. It is found that a sheet having excellent surface smoothness, which cannot be achieved by conventional sheets, can be obtained by adjusting sheet extrusion conditions for a polycarbonate resin sheet/film into which a reinforcing filler is blended. It is also found that a thermally shaped article having excellent appearance can be obtained by using this sheet in pressure molding or in thermal press molding.