Polycrystalline Cutting Elements With Gradient Catalyst Leaching

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Solution Overview

Problem

Polycrystalline diamond cutting elements for earth-boring tools face issues with thermal stability and brittleness due to catalyst material, leading to vulnerability under shear, compressive, and tensile stresses, and challenges in securing fully leached diamond tables to substrates.

Innovation Solution

The development of cutting elements with a boundary between catalyst-containing and catalyst-free regions in the polycrystalline superabrasive materials, where the catalyst material is selectively removed, such as through acid leaching, to create a wear profile that prevents exposure of catalyst-containing material during wear, enhancing resistance to spalling and wear properties.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Stability of the object's composition

If catalyst material is completely removed from the diamond table through leaching, then thermal stability is improved, but the diamond table becomes more brittle and vulnerable to stresses

Engineering Contradiction:
Improvethermal stabilityVSAvoidresistance to shear, compressive, and tensile stresses
Core Design Contradiction:
Stability of the object's compositionVSStrength

Solution Approach 1:

The patent applies local quality by creating a gradient structure where the diamond table has varying catalyst content across its depth. The cutting face region is substantially free of catalyst material for thermal stability, while deeper regions retain catalyst material to provide structural support and reduce brittleness. This spatial variation in catalyst concentration allows simultaneous optimization of both thermal stability and mechanical strength.

Inventive Principle:
Principle #3Local quality

2Stability of the object's composition

If catalyst material is completely removed from the diamond table, then thermal stability is improved, but it becomes difficult to secure the diamond table to a supporting substrate

Engineering Contradiction:
Improvethermal stabilityVSAvoidease of securing diamond table to substrate
Core Design Contradiction:
Stability of the object's compositionVSEase of manufacture

Solution Approach 1:

The patent uses local quality by concentrating the catalyst-free region at the cutting face while preserving catalyst-containing material in the deeper regions that interface with the substrate. This localized approach maintains thermal stability where needed while preserving the bonding capability at the substrate interface.

Inventive Principle:
Principle #3Local quality

Solution Approach 2:

The patent applies preliminary action by controlling the leaching process to stop at a specific depth before complete removal, creating a pre-designed gradient structure that inherently provides both thermal stability and substrate bonding capability without requiring additional manufacturing steps.

Inventive Principle:
Principle #10Preliminary action

3Reliability

If a wear scar forms exposing catalyst-containing material through an aperture, then the cutting element's performance deteriorates, but preventing this requires specific boundary geometries

Engineering Contradiction:
Improvecutting element performanceVSAvoidboundary geometry complexity
Core Design Contradiction:
ReliabilityVSDevice complexity

Solution Approach 1:

The patent applies local quality by creating a specific boundary geometry between the catalyst-free and catalyst-containing regions. The boundary is configured with slopes greater than the contact back rake angle, which prevents wear scars from exposing catalyst material while maintaining relatively simple manufacturing requirements.

Inventive Principle:
Principle #3Local quality

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

This approach results in improved resistance to spalling and more favorable wear properties, allowing the cutting elements to maintain performance and durability by preventing radially discontinuous exposure of catalyst-containing material, thus extending the cutting element's lifespan and efficiency.

Implementation Method 1

the catalyst material is selectively removed, such as through acid leaching

Methodology Applied
Scientific EffectAcid leaching:

Data Source

PatentEP3167146B1Cutting elements comprising partially leached polycrystalline material, tools comprising such cutting elements, and methods of forming wellbores using such cutting elements
Publication Date: 2023.08.30 BAKER HUGHES CO
  • EP3167146B1 patent drawingFigure 1~2A
  • EP3167146B1 patent drawingFigure 2B~2C
  • EP3167146B1 patent drawingFigure 3

AI summary

An earth-boring tool includes a cutting element having a first volume of polycrystalline material including catalyst material and a second volume free of catalyst material. A boundary between the first volume and the second volume is nonlinear in a cross-sectional plane that includes a centerline of the cutting element and an anticipated point of contact of the cutting element with the surface of the formation to be cut. Each line tangent the boundary in the cross-sectional plane forms an angle with the centerline of the cutting element greater than the contact back rake angle of the cutting element. In some cutting elements, some portions of the boundary may have another selected shape. Some cutting elements have a boundary wherein tangent lines form angles of greater than 20° with the centerline of the cutting element. Methods of forming wellbores are also disclosed.