Polycrystalline Seed Layer for STT-MRAM Thermal Stability

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Solution Overview

Problem

The existing magnetic tunnel junctions in STT-MRAM devices have low crystallinity and thermal stability, leading to slow magnetization changes and reduced read/write operation speed, which hinders the development of high-speed memory devices.

Innovation Solution

A memory device structure is developed with a polycrystalline capping layer and seed layer, including tungsten, and synthetic antiferromagnetic layers with Pt, which maintains perpendicular magnetic anisotropy even at high temperatures, improving crystallinity and thermal stability through heat treatment.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Ease of manufacture

If amorphous seed layer and amorphous magnetic tunnel junction are used, then device structure is simple and manufacturing is easier, but crystallinity is low leading to slow magnetization changes and reduced read/write speed

Engineering Contradiction:
Improveease of manufactureVSAvoidread/write operation speed
Core Design Contradiction:
Ease of manufactureVSProductivity

Solution Approach 1:

The invention changes the physical state parameter of the seed layer from amorphous to polycrystalline through heat treatment at 400-500°C. This parameter change transforms the magnetic tunnel junction from amorphous to crystalline, enabling rapid magnetization switching while maintaining manufacturing feasibility through a single heat treatment step

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The invention utilizes the phase transition of the seed layer from amorphous to polycrystalline state during heat treatment. This phase transition induces corresponding phase transition in the magnetic tunnel junction from amorphous to crystalline, achieving high-speed magnetization switching through controlled thermal processing

Inventive Principle:
Principle #36Phase transitions

2Device complexity

If conventional materials are used for seed layer and capping layer, then manufacturing process is simpler, but thermal stability is poor causing perpendicular magnetic anisotropy to deteriorate at high temperatures

Engineering Contradiction:
Improvedevice complexityVSAvoidthermal stability
Core Design Contradiction:
Device complexityVSStability of the object's composition

Solution Approach 1:

The invention employs composite material selection where tungsten (W) is used for both the seed layer and capping layer. This composite approach ensures thermal stability throughout the magnetic tunnel junction structure, as tungsten maintains perpendicular magnetic anisotropy at high temperatures and prevents degradation of magnetic properties during heat treatment and device operation

Inventive Principle:
Principle #40Composite materials

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The improved crystallinity and thermal stability enable rapid magnetization direction changes, enhancing read/write operation speed and reliability of the memory device.

Implementation Method 1

the magnetization directions must change only in the direction perpendicular to a substrate. Therefore, the free layer and the pinned layer must have perpendicular magnetization values. When the perpendicular magnetization values are symmetrical with respect to 0 according to the intensity and direction of a magnetic field, and a squareness (S) shape becomes clear (S=1), perpendicular magnetic anisotropy (PMA) is considered to be excellent.

Methodology Applied
Scientific EffectPerpendicular magnetic anisotropy: Anisotropy

Implementation Method 2

a spin-transfer torque magnetic random access memory (STT-MRAM) device that inverts magnetization using a spin-transfer torque (STT) phenomenon generated by electron injection and discriminates a resistance difference before and after magnetization inversion

Methodology Applied
Scientific EffectSpin-transfer torque:

Implementation Method 3

the magnetic tunnel junction, which consists of a pinned layer and a free layer, each formed of a ferromagnetic material, and a tunnel barrier disposed therebetween. In the magnetic tunnel junction, when the magnetization directions of the free layer and the pinned layer are the same (that is, parallel), current flow is easy and consequently the magnetic tunnel junction is in a low resistance state. On the other hand, when the magnetization directions are different (that is, antiparallel), current is reduced and consequently the magnetic tunnel junction is in a high resistance state.

Methodology Applied
Scientific EffectMagnetoresistance: Magnetoresistance

Data Source

PatentUS11050014B2Memory device
Publication Date: 2021.06.29 INDUSTRY UNIVERSITY COOPERATION FOUNDATION HANYANG UNIVERSITY
  • US11050014B2 patent drawing
  • US11050014B2 patent drawing
  • US11050014B2 patent drawing

AI summary

A memory device contains lower electrodes, a buffer layer, a seed layer, a magnetic tunnel junction, a capping layer, synthetic antiferromagnetic layers, and an upper electrode, which are formed on a substrate in a laminated manner. In the memory device, the lower electrodes and the seed layer are formed of a polycrystalline conductive material, and the perpendicular magnetic anisotropy of the magnetic tunnel junction is maintained upon heat treatment at a high temperature of 400° C. or more.