Polycyclic Aromatic Compound for Organic EL Efficiency

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Solution Overview

Problem

Current organic electroluminescent elements lack diverse material combinations for light emitting layers, limiting the optimization of luminescence characteristics beyond specific host and dopant combinations, and thus, there is a need for new materials to enhance quantum efficiency and element lifetime.

Innovation Solution

A polycyclic aromatic compound with multiple aromatic rings connected by boron, oxygen, sulfur, or selenium atoms is developed, used in the light emitting layer of an organic electroluminescent element to improve quantum efficiency and element lifetime.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Adaptability or versatility

If conventional host and dopant combinations are used in the light emitting layer, then the organic EL element structure is simple, but the luminescence characteristics cannot be optimized beyond specific combinations

Engineering Contradiction:
Improvematerial combination optionsVSAvoidmaterial system complexity
Core Design Contradiction:
Adaptability or versatilityVSDevice complexity

Solution Approach 1:

The patent changes the chemical structure parameters of the dopant material by introducing a novel polycyclic aromatic compound with specific ring structures and substituents. This structural parameter change enables new luminescence characteristics while maintaining compatibility with conventional host materials, thus expanding material combination options without proportionally increasing system complexity

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent creates a composite material system by combining the newly developed polycyclic aromatic dopant with conventional host materials. This composite approach allows the dopant to provide enhanced luminescence properties while the host material maintains the established device structure and charge transport functions, resolving the contradiction between versatility and complexity

Inventive Principle:
Principle #40Composite materials

2Reliability

If new material combinations are developed to improve luminescence characteristics, then quantum efficiency and element lifetime can be enhanced, but the development time and research complexity increase

Engineering Contradiction:
Improveelement lifetimeVSAvoiddevelopment time
Core Design Contradiction:
ReliabilityVSLoss of time

Solution Approach 1:

The patent performs preliminary structural design of the dopant molecule with pre-optimized features including specific fused ring systems, electron-donating or electron-withdrawing substituents, and steric hindrance groups. This preliminary action ensures that the developed material inherently possesses improved stability and luminescence properties, reducing the need for extensive iterative optimization and thus shortening overall development time

Inventive Principle:
Principle #10Preliminary action

Solution Approach 2:

The patent applies local quality modifications by introducing specific functional groups and substituents at particular positions on the aromatic rings. These localized structural changes target specific properties such as HOMO-LUMO gap, charge distribution, and molecular packing, enabling precise control over luminescence characteristics and device performance without requiring complete redesign of the entire molecular structure

Inventive Principle:
Principle #3Local quality

3Illumination intensity

If specific host and dopant combinations are used, then the light emitting layer composition is simple, but the luminescence characteristics are limited

Engineering Contradiction:
Improveluminescence characteristicsVSAvoidmaterial diversity
Core Design Contradiction:
Illumination intensityVSQuantity of substance

Solution Approach 1:

The patent designs the polycyclic aromatic dopant with universal applicability by incorporating structural features that can interact with multiple types of host materials. The dopant's electron-deficient or electron-rich character, along with its steric and electronic properties, allows it to function effectively across different host systems, thereby improving luminescence characteristics without requiring an equivalent increase in material diversity

Inventive Principle:
Principle #6Universality (Multi-functionality)

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The use of this polycyclic aromatic compound in the light emitting layer of an organic electroluminescent element results in enhanced quantum efficiency and extended element lifetime, achieving optimal luminescence characteristics.

Implementation Method 1

an organic electroluminescent element (hereinafter, referred to as an organic EL element) formed from an organic material has been studied actively

Methodology Applied
Scientific EffectElectroluminescence: Electroluminescence

Data Source

PatentUS11248009B2Polycyclic aromatic compound, material for an organic device, organic electroluminescent element, display apparatus and lighting apparatus
Publication Date: 2022.02.15 SK MATERIALS JNC CO LTD
  • US11248009B2 patent drawing
  • US11248009B2 patent drawing
  • US11248009B2 patent drawing

AI summary

A polycyclic aromatic compound in which a plurality of aromatic rings are connected by a boron atom and an oxygen atom, a sulfur atom or a selenium atom and substituted by a specific aryl such as anthracene, is useful as a material for an organic device. By the polycyclic aromatic compound, an organic EL device having at least one of efficiency and device life can be provided.