Polycyclic Aromatic Compound Electrolyte for Lithium Ion Battery Stability

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Solution Overview

Problem

Lithium ion secondary batteries face challenges in achieving optimal battery characteristics, particularly in severe environments, due to decomposition reactions and gas generation in the electrolytic solution, which affect their performance and longevity.

Innovation Solution

Incorporating a polycyclic aromatic compound in the electrolytic solution, which improves chemical stability and suppresses decomposition reactions, enhancing battery characteristics by stabilizing the electrolyte and preventing gas generation, especially under extreme temperature conditions.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If conventional electrolytic solution composition is used, then basic battery operation is maintained, but decomposition reactions occur and gas is generated in severe environments, deteriorating battery characteristics

Engineering Contradiction:
Improvebattery characteristicsVSAvoiddecomposition reactions and gas generation
Core Design Contradiction:
ReliabilityVSObject-generated harmful factors

Solution Approach 1:

The patent introduces a polycyclic aromatic compound with specific molecular structure parameters (multiple fused aromatic rings) into the electrolytic solution. This chemical parameter change modifies the electrolyte's properties to suppress decomposition reactions and gas generation, thereby improving battery reliability in severe environments without compromising basic operation

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent creates a composite electrolytic solution system by combining the polycyclic aromatic compound with conventional electrolyte components (lithium salt, cyclic carbonate, chain carbonate). This composite approach leverages the stabilizing effect of the polycyclic aromatic compound while maintaining the essential functions of the conventional electrolyte, resolving the contradiction between basic operation and suppression of harmful factors

Inventive Principle:
Principle #40Composite materials

2Use of energy by moving object

If battery capacity is increased for high energy density, then power source performance improves, but battery characteristics deteriorate in severe environments due to electrolyte instability

Engineering Contradiction:
Improveenergy densityVSAvoidelectrolyte stability
Core Design Contradiction:
Use of energy by moving objectVSStability of the object's composition

Solution Approach 1:

The polycyclic aromatic compound acts as an intermediary substance in the electrolytic solution. It mediates between the high energy density requirements (which demand increased battery capacity) and electrolyte stability requirements (which are compromised in severe environments). The compound stabilizes the electrolyte composition without interfering with the lithium ion transfer processes that enable high capacity operation

Inventive Principle:
Principle #24Intermediary (Mediator)

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The use of a polycyclic aromatic compound in the electrolytic solution significantly improves the battery characteristics of lithium ion secondary batteries by reducing decomposition and gas generation, leading to enhanced performance and extended lifespan, even in harsh environments.

Implementation Method 1

Incorporating a polycyclic aromatic compound in the electrolytic solution, which improves chemical stability and suppresses decomposition reactions

Methodology Applied
Scientific EffectChemical stability enhancement:

Data Source

PatentUS11482730B2Electrolyte for lithium ion secondary battery, lithium ion secondary battery, battery pack, electric vehicle, electric power storage system, electric tool and electronic device
Publication Date: 2022.10.25 MURATA MFG CO LTD
  • US11482730B2 patent drawing
  • US11482730B2 patent drawing
  • US11482730B2 patent drawing

AI summary

A lithium ion secondary battery includes a positive electrode, a negative electrode, and an electrolytic solution containing a polycyclic aromatic compound.