Polycyclic Compound Hole Transport Organic Electroluminescence Device

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Solution Overview

Problem

Current organic electroluminescence devices face challenges in achieving high emission efficiency and low driving voltage due to limitations in hole transport materials that inhibit the diffusion of triplet excitons.

Innovation Solution

A polycyclic compound represented by Formula 1 is used in the hole transport region of an organic electroluminescence device, which has a high level of lowest triplet excitation energy and high occupied molecular orbital (HOMO) energy, facilitating efficient hole transport and inhibiting triplet exciton diffusion.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Productivity

If conventional hole transport materials are used, then the device structure is simple, but emission efficiency is low and driving voltage is high due to triplet exciton diffusion

Engineering Contradiction:
Improveemission efficiencyVSAvoiddevice complexity
Core Design Contradiction:
ProductivityVSDevice complexity

Solution Approach 1:

The patent modifies the molecular structure of hole transport materials by introducing specific polycyclic frameworks with high triplet excitation energy levels. This parameter change in the material's energy levels prevents triplet exciton diffusion while maintaining device structure simplicity, thereby resolving the contradiction between emission efficiency and device complexity

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent employs composite material design by combining polycyclic aromatic hydrocarbons with electron-transporting moieties to create hybrid hole transport materials. These composite materials exhibit both high hole mobility and elevated triplet excitation energy, achieving high emission efficiency without complicating the overall device architecture

Inventive Principle:
Principle #40Composite materials

2Speed

If hole transport materials with high hole mobility are used, then hole transport is efficient, but triplet exciton diffusion is not effectively inhibited

Engineering Contradiction:
Improvehole transport speedVSAvoidtriplet exciton confinement
Core Design Contradiction:
SpeedVSReliability

Solution Approach 1:

The patent applies local quality by designing hole transport materials with spatially differentiated properties: the polycyclic core provides high hole mobility while peripheral substituents or specific molecular arrangements create high triplet excitation energy zones. This local differentiation enables simultaneous achievement of fast hole transport and effective triplet exciton confinement

Inventive Principle:
Principle #3Local quality

Solution Approach 2:

The patent changes the energy level parameters of the hole transport material by selecting polycyclic compounds with inherently high triplet excitation energy. This parameter change creates an energy barrier that confines triplet excitons to the emission layer while maintaining high hole mobility through the material's optimized molecular structure

Inventive Principle:
Principle #35Parameter changes

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The polycyclic compound ensures high emission efficiency and low driving voltage in organic electroluminescence devices by enhancing hole transport properties and preventing triplet exciton diffusion into the hole transport region.

Implementation Method 1

facilitating efficient hole transport

Methodology Applied
Scientific EffectCharge carrier transport: Conduction (electrical)

Implementation Method 2

inhibiting the diffusion of triplet excitons

Methodology Applied
Scientific EffectEnergy barrier effect: Diffusion Barrier

Data Source

PatentUS10787467B2Polycyclic compound and organic electroluminescence device including the same
Publication Date: 2020.09.29 SAMSUNG DISPLAY CO LTD
  • US10787467B2 patent drawing
  • US10787467B2 patent drawing
  • US10787467B2 patent drawing

AI summary

A polycyclic compound and an organic electroluminescence device, the polycyclic compound being represented by Formula 1: