Polycyclic Compound Emitter for OLED Efficiency and Lifetime

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Solution Overview

Problem

Current organic electroluminescence display devices face challenges in achieving low driving voltage, high luminous efficiency, and long service life, particularly in developing materials that consistently meet these criteria for stable performance.

Innovation Solution

A light emitting device is designed with a polycyclic compound represented by specific formulas, incorporated into the emission layer, which includes a combination of compounds to enhance luminous efficiency and service life, utilizing a structure that includes a first electrode, a second electrode, and functional layers such as a hole transport region and an electron transport region.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Productivity

If conventional materials are used in organic electroluminescence display devices, then the device structure can be maintained, but luminous efficiency and service life are insufficient

Engineering Contradiction:
Improveluminous efficiencyVSAvoidservice life
Core Design Contradiction:
ProductivityVSReliability

Solution Approach 1:

The patent modifies the molecular structure parameters of the emitter compound by introducing specific substituents (Ra-Rd groups) at defined positions (a, b, c, d) on the core structure. This structural parameter change enables the compound to achieve both high luminous efficiency and long service life by optimizing electron-hole recombination and exciton management properties.

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent employs a composite material system consisting of the polycyclic compound (Formula 1) as the core emitter, combined with specific host materials (Formula HT and Formula ET) in the emission layer. This composite approach allows the emitter to benefit from enhanced stability and efficiency through synergistic interactions with the host materials, resolving the contradiction between luminous efficiency and service life.

Inventive Principle:
Principle #40Composite materials

2Productivity

If materials for high luminous efficiency are developed, then luminous efficiency improves, but achieving stable performance with long service life remains challenging

Engineering Contradiction:
Improveluminous efficiencyVSAvoidperformance stability
Core Design Contradiction:
ProductivityVSStability of the object's composition

Solution Approach 1:

The patent systematically varies structural parameters (substituent types Ra-Rd, positions a-d, heteroatom X) to optimize the balance between luminous efficiency and performance stability. The defined parameter ranges ensure reproducible synthesis and consistent performance across different device batches.

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent introduces specific functional groups (Ra-Rd) at localized positions on the molecular structure to enhance stability without compromising overall luminous efficiency. The core structure maintains its efficiency-generating properties while localized substituents provide stability enhancement.

Inventive Principle:
Principle #3Local quality

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The proposed solution improves luminous efficiency and extends the service life of the light emitting device, achieving better performance in terms of efficiency and durability compared to existing technologies.

Implementation Method 1

delayed fluorescence emission which uses the generating phenomenon of singlet excitons by the collision of triplet excitons (triplet-triplet annihilation, TTA)

Methodology Applied
Scientific EffectTriplet-triplet annihilation (TTA):

Implementation Method 2

delayed fluorescence emission which uses the generating phenomenon of singlet excitons by the collision of triplet excitons

Methodology Applied
Scientific EffectDelayed fluorescence:

Data Source

PatentUS20240215446A1Light emitting device and polycyclic compound for the same
Publication Date: 2024.06.27 SAMSUNG DISPLAY CO LTD
  • US20240215446A1 patent drawing
  • US20240215446A1 patent drawing
  • US20240215446A1 patent drawing

AI summary

Embodiments provide a light emitting device that includes a first electrode, a second electrode facing the first electrode, and at least one functional layer disposed between the first electrode and the second electrode, wherein the at least one functional layer includes a first compound represented by Formula 1, and at least one of a second compound represented by Formula HT and a third compound represented by Formula ET, and wherein Formula 1, Formula HT, and Formula ET are each explained in the specification.