Polycyclic Compound for OLED Emission Efficiency

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Solution Overview

Problem

Current organic electroluminescence devices face challenges in reducing driving voltage, increasing emission efficiency, and extending lifespan, particularly in achieving high efficiency and stability in thermally activated delayed fluorescence (TADF) materials.

Innovation Solution

Incorporating a polycyclic compound represented by a specific formula into the organic electroluminescence device structure, including it in the emission layer, hole transport region, and electron transport region, to enhance emission efficiency and electron transport properties, and improve the device's lifespan.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Productivity

If conventional organic electroluminescence materials are used, then the device can operate, but the emission efficiency and lifespan are insufficient

Engineering Contradiction:
Improveemission efficiencyVSAvoidlifespan
Core Design Contradiction:
ProductivityVSReliability

Solution Approach 1:

The patent modifies the molecular structure parameters of organic compounds by introducing specific polycyclic frameworks (such as dibenzofuran, dibenzothiophene, carbazole units) and substituent groups to optimize the HOMO-LUMO energy gap, triplet energy levels, and charge transport properties. This structural parameter optimization simultaneously enhances emission efficiency and device lifespan.

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The invention employs composite organic materials combining multiple functional moieties within single molecules (e.g., compounds containing both electron-donating and electron-withdrawing groups, or multiple heterocyclic rings fused together). These composite structures enable simultaneous achievement of high quantum efficiency and improved stability/lifespan.

Inventive Principle:
Principle #40Composite materials

2Use of energy by moving object

If the driving voltage is reduced, then power consumption decreases, but emission efficiency and lifespan are compromised

Engineering Contradiction:
Improvepower consumptionVSAvoidemission efficiency
Core Design Contradiction:
Use of energy by moving objectVSProductivity

Solution Approach 1:

The patent optimizes the energy level parameters of organic compounds to achieve lower driving voltages while maintaining high emission efficiency. By adjusting HOMO/LUMO levels, triplet energy (ET), and charge mobility through molecular design, the device operates at reduced voltages without sacrificing efficiency.

Inventive Principle:
Principle #35Parameter changes

3Productivity

If phosphorescence or TADF materials are used to improve efficiency, then emission efficiency increases, but material stability and lifespan remain challenging

Engineering Contradiction:
Improveemission efficiencyVSAvoidmaterial stability
Core Design Contradiction:
ProductivityVSReliability

Solution Approach 1:

The patent introduces specific local structural features (such as rigid polycyclic cores, strategic placement of heteroatoms, and controlled substitution patterns) that locally enhance molecular stability and resistance to degradation while maintaining the desired photophysical properties for high-efficiency emission.

Inventive Principle:
Principle #3Local quality

Solution Approach 2:

The invention designs composite molecules integrating multiple functional units (e.g., combining TADF donor-acceptor structures with stable polycyclic frameworks) that simultaneously achieve high emission efficiency and improved material stability for extended device lifespan.

Inventive Principle:
Principle #40Composite materials

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The use of the polycyclic compound improves the external quantum efficiency and extends the lifespan of the organic electroluminescence device, particularly in the blue wavelength region, by activating multiple resonance effects and optimizing the transition dipole moment orientation in the emission layer.

Implementation Method 1

development on a material for thermally activated delayed fluorescence (TADF) utilizing delayed fluorescence phenomenon is being conducted

Methodology Applied
Scientific EffectThermally activated delayed fluorescence (TADF): Fluorescence

Implementation Method 2

holes and electrons injected from a first electrode and a second electrode recombine in an emission layer, and a light-emitting material including an organic compound in the emission layer emits light

Methodology Applied
Scientific EffectElectroluminescence: Electroluminescence

Data Source

PatentUS11800793B2Organic electroluminescence device and polycyclic compound for organic electroluminescence device
Publication Date: 2023.10.24 SAMSUNG DISPLAY CO LTD
  • US11800793B2 patent drawing
  • US11800793B2 patent drawing
  • US11800793B2 patent drawing

AI summary

An organic electroluminescence device includes a first electrode, an organic layer disposed on the first electrode, and a second electrode disposed on the organic layer, wherein the organic layer includes a polycyclic compound represented by Formula 1. The organic electroluminescence device may have high emission efficiency.