Polycyclic Compound Emission Layers for OLED Efficiency and Service Life

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Solution Overview

Problem

Existing organic electroluminescence devices face challenges in reducing driving voltage and increasing emission efficiency and service life, necessitating the development of stable materials for improved performance.

Innovation Solution

Incorporation of a polycyclic compound in the emission layer of the organic electroluminescence device, which can facilitate thermally activated delayed fluorescence, enhancing efficiency and potentially extending the device's lifespan.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Productivity

If conventional materials are used in the emission layer, then the device structure remains simple, but emission efficiency and service life are insufficient

Engineering Contradiction:
Improveemission efficiencyVSAvoidservice life
Core Design Contradiction:
ProductivityVSReliability

Solution Approach 1:

The patent employs composite material strategy by combining the polycyclic compound (Formula 1) with host materials and dopants to create an emission layer composite system. This composite approach enables simultaneous achievement of high emission efficiency through TADF mechanism and extended service life through stable molecular structure, resolving the contradiction between productivity and reliability.

Inventive Principle:
Principle #40Composite materials

Solution Approach 2:

The patent applies parameter changes by modifying the molecular structure parameters of the emission layer materials using Formula 1 with variable substituents (X1, X2, Ar1, Y1, Y2, R1-R6, e-f, g-h, i-j). These structural parameter variations optimize the TADF characteristics and stability, enabling improved emission efficiency and service life without compromising device simplicity.

Inventive Principle:
Principle #35Parameter changes

2Productivity

If materials for higher emission efficiency are developed, then service life may be improved, but driving voltage reduction remains insufficient

Engineering Contradiction:
Improveemission efficiencyVSAvoiddriving voltage
Core Design Contradiction:
ProductivityVSUse of energy by moving object

Solution Approach 1:

The patent utilizes parameter changes in the polycyclic compound structure (Formula 1) to optimize the energy levels and HOMO-LUMO gap, which simultaneously addresses emission efficiency and driving voltage. By adjusting substituents and molecular parameters, the material achieves efficient TADF emission while maintaining appropriate energy levels for reduced driving voltage operation.

Inventive Principle:
Principle #35Parameter changes

3Reliability

If stable materials are used to extend service life, then emission efficiency may be compromised, but device complexity increases

Engineering Contradiction:
Improveservice lifeVSAvoidemission efficiency
Core Design Contradiction:
ReliabilityVSProductivity

Solution Approach 1:

The patent resolves this contradiction through composite material design where the polycyclic compound (Formula 1) serves as a stable TADF emitter combined with appropriate host and dopant materials. This composite system ensures both long service life through stable molecular structure and high emission efficiency through effective TADF mechanism, without increasing overall device complexity.

Inventive Principle:
Principle #40Composite materials

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The polycyclic compound enhances the emission efficiency and extends the service life of the organic electroluminescence device, achieving improved performance characteristics.

Implementation Method 1

Incorporation of a polycyclic compound in the emission layer of the organic electroluminescence device, which can facilitate thermally activated delayed fluorescence, enhancing efficiency and potentially extending the device's lifespan.

Methodology Applied
Scientific EffectThermally activated delayed fluorescence: Phosphorescence

Data Source

PatentUS12435267B2Organic electroluminescence device and polycyclic compound for organic electroluminescence device
Publication Date: 2025.10.07 SAMSUNG DISPLAY CO LTD
  • US12435267B2 patent drawing
  • US12435267B2 patent drawing
  • US12435267B2 patent drawing

AI summary

An organic electroluminescence device of an embodiment includes a first electrode, a hole transport region disposed on the first electrode, an emission layer disposed on the hole transport region, an electron transport region disposed on the emission layer, and a second electrode disposed on the electron transport region, wherein the emission layer includes a polycyclic compound represented by Formula 1, thereby exhibiting high emission efficiency.