Polydiorganosiloxane Polyamide Multi-Component Fibers

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Solution Overview

Problem

Existing fiber technologies lack materials with high thermal stability, low surface energy, and excellent adhesive properties suitable for nonwoven webs, particularly for applications requiring breathability and adhesion to irregular surfaces.

Innovation Solution

Development of multi-component fibers comprising a polydiorganosiloxane polyamide copolymer as the outer layer and a second melt processable polymer core, which are processed using melt-blowing to create microfibers with high shear adhesion holding power and pressure-sensitive adhesive properties.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If a polydiorganosiloxane polyamide copolymer is used as the outer layer, then adhesive properties and thermal stability are improved, but melt processability and fiber formation become more difficult

Engineering Contradiction:
Improveadhesive propertiesVSAvoidmelt processability
Core Design Contradiction:
ReliabilityVSEase of manufacture

Solution Approach 1:

The invention uses a multi-component fiber structure where the outer layer is composed of a polydiorganosiloxane polyamide copolymer blend containing both polar and nonpolar components. This composite approach allows the material to exhibit enhanced adhesive properties from the polar polyamide segments while the nonpolar segments provide melt processability and fiber formation characteristics, resolving the contradiction between adhesive performance and manufacturability.

Inventive Principle:
Principle #40Composite materials

2Adaptability or versatility

If the fiber structure is made more complex with multiple components, then adhesion to irregular surfaces is improved, but manufacturing complexity increases

Engineering Contradiction:
Improveadhesion to irregular surfacesVSAvoidfiber structure
Core Design Contradiction:
Adaptability or versatilityVSDevice complexity

Solution Approach 1:

The invention applies local quality by creating a multi-component fiber structure where specific segments of the fiber have specific properties. The outer layer contains polydiorganosiloxane polyamide copolymer with both polar (for adhesion) and nonpolar (for processability) components, while the core may contain different polymers. This localized differentiation of material properties within the fiber structure enables adhesion to irregular surfaces without requiring complex external processing or multiple separate components.

Inventive Principle:
Principle #3Local quality

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The resulting nonwoven webs exhibit high surface area, porosity, breathability, and excellent adhesion characteristics with reduced adhesion build over time, making them suitable for various applications including medical articles and skin contact.

Implementation Method 1

melt-blowing the composition to form a fibrous web

Methodology Applied
Scientific EffectMelt-blowing: Melting

Implementation Method 2

a complex viscosity ranging from 500 to 5000 poise at a temperature ranging from 200° C. to 300° C. and a shear rate of 1 hertz

Methodology Applied
Scientific EffectShear thinning: Shear Thinning

Data Source

PatentUS9617668B2Nonwoven webs and multi-component fibers comprising a polydiorganosiloxane polyamide and methods of melt blowing
Publication Date: 2017.04.11 3M INNOVATIVE PROPERTIES CO
  • US9617668B2 patent drawing
  • US9617668B2 patent drawing
  • US9617668B2 patent drawing

AI summary

The present invention pertains to nonwoven webs, and multi-component fibers comprising polydiorganosiloxane polyamide as well as method of making microfibers and multi-component fibers comprising a polydiorganosiloxane polyamide copolymer.