Polydopamine Cover Layers for Crack-Resistant Multilayer Capacitors

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Solution Overview

Problem

The miniaturization of multilayer ceramic capacitors to increase capacitance per unit volume has led to a reduction in the mechanical strength of the cover portion, making them more susceptible to cracks and reducing their moisture resistance reliability.

Innovation Solution

Incorporating polydopamine into the cover portion of the multilayer electronic component, which forms nitrogen-doped carbonized polydopamine upon firing, enhances the mechanical strength and toughness of the component by preventing crack propagation and acting as a barrier against moisture penetration.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Quantity of substance

If the thickness of the cover portion is reduced to increase capacitance per unit volume, then the capacitance density is improved, but the mechanical strength of the multilayer ceramic capacitor weakens

Engineering Contradiction:
Improvecapacitance per unit volumeVSAvoidmechanical strength of cover portion
Core Design Contradiction:
Quantity of substanceVSStrength

Solution Approach 1:

The patent applies composite materials by incorporating polydopamine into the cover portion material. The cover portion is formed as a composite of ceramic material and polydopamine, where the polydopamine acts as a reinforcing agent that enhances mechanical strength while allowing the cover thickness to be reduced. This composite structure resolves the contradiction by providing both the reduced thickness needed for high capacitance density and the enhanced mechanical strength from the polydopamine reinforcement.

Inventive Principle:
Principle #40Composite materials

Solution Approach 2:

The patent changes the material composition parameters of the cover portion by adding polydopamine. This parameter change (compositional modification) alters the mechanical properties of the cover material, enabling it to maintain or improve strength even when thickness is reduced. The polydopamine content and distribution are controlled to optimize the balance between mechanical strength and capacitance density.

Inventive Principle:
Principle #35Parameter changes

2Quantity of substance

If the thickness of the cover portion is reduced, then the capacitance per unit volume increases, but the moisture resistance reliability decreases

Engineering Contradiction:
Improvecapacitance per unit volumeVSAvoidmoisture resistance reliability
Core Design Contradiction:
Quantity of substanceVSReliability

Solution Approach 1:

The polydopamine composite structure serves as a barrier against moisture penetration. The polydopamine forms a dense, hydrophobic network within the cover portion that blocks moisture pathways, thereby maintaining moisture resistance reliability even when the cover thickness is reduced to increase capacitance density.

Inventive Principle:
Principle #40Composite materials

Solution Approach 2:

The polydopamine acts as an intermediary barrier between the external environment (moisture) and the internal capacitance formation portion. It provides a protective interface that prevents moisture from reaching the sensitive internal electrodes and dielectric layers, thus maintaining reliability despite reduced cover thickness.

Inventive Principle:
Principle #24Intermediary (Mediator)

3Quantity of substance

If the thickness of the cover portion is reduced, then the capacitance per unit volume increases, but the toughness of the cover portion decreases

Engineering Contradiction:
Improvecapacitance per unit volumeVSAvoidtoughness of cover portion
Core Design Contradiction:
Quantity of substanceVSStability of the object's composition

Solution Approach 1:

The polydopamine-ceramic composite structure enhances toughness by creating a heterogeneous material system where polydopamine domains are distributed within the ceramic matrix. This composite architecture provides crack deflection and energy dissipation mechanisms, maintaining toughness even when the overall cover thickness is reduced for higher capacitance density.

Inventive Principle:
Principle #40Composite materials

Solution Approach 2:

The polydopamine is locally distributed within the cover portion to provide targeted reinforcement. The local concentration and distribution of polydopamine are optimized to enhance toughness in critical regions while maintaining the overall thin profile needed for high capacitance per unit volume.

Inventive Principle:
Principle #3Local quality

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The use of polydopamine in the cover portion significantly improves the mechanical strength and moisture resistance reliability of the multilayer electronic component, reducing the risk of cracks and enhancing its overall performance.

Implementation Method 1

Incorporating polydopamine into the cover portion of the multilayer electronic component, which forms nitrogen-doped carbonized polydopamine upon firing

Methodology Applied
Scientific EffectCarbonization: Pyrolysis

Implementation Method 2

forms nitrogen-doped carbonized polydopamine upon firing

Methodology Applied
Scientific EffectNitrogen doping: Dopants

Implementation Method 3

acting as a barrier against moisture penetration

Methodology Applied
Scientific EffectHydrophobic barrier: Hydrophobe

Implementation Method 4

preventing crack propagation

Methodology Applied
Scientific EffectCrack propagation inhibition: Fracture Mechanics

Data Source

PatentUS20250029787A1Multilayer electronic component
Publication Date: 2025.01.23 SAMSUNG ELECTRO MECHANICS CO LTD
  • US20250029787A1 patent drawing
  • US20250029787A1 patent drawing
  • US20250029787A1 patent drawing

AI summary

A multilayer electronic component includes a body including a capacitance formation portion including a dielectric layer and internal electrodes alternately disposed in a first direction, and a cover portion disposed on both surfaces of the capacitance formation portion opposing each other in the first direction; and an external electrode disposed on the body and connected to the internal electrode, wherein the cover portion includes polydopamine.