Polyelectrolyte Complex Microgels for Split End Repair

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Solution Overview

Problem

Current hair repair compositions are inadequate in effectively mending split ends and assessing the permanence of the repair, as existing methods either focus on prevention or provide insufficient evidence of mending efficacy.

Innovation Solution

A hair care composition comprising a polyelectrolyte complex (PEC) formed between a cationic polyquaternium polymer and an anionic copolymer at specific charge ratios, which creates microgels that infiltrate split ends, bind damaged hair fibers, and form a durable seal upon drying, capable of withstanding combing stress.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If conventional hair repair compositions are used, then split end mending is attempted, but the effectiveness and permanence of repair is insufficient

Engineering Contradiction:
Improvesplit end mending effectivenessVSAvoidrepair permanence
Core Design Contradiction:
ReliabilityVSManufacturing precision

Solution Approach 1:

The patent employs polyelectrolyte complexes formed by combining cationic polyquaternium polymers with anionic copolymers containing mono-, di- or tri-acid groups. This composite material approach creates a synergistic effect where the complex structure provides both immediate mending capability and durable repair, resolving the contradiction between effectiveness and permanence of split end repair

Inventive Principle:
Principle #40Composite materials

Solution Approach 2:

The patent specifies precise charge ratios between the cationic and anionic polymers (0.82 to 1.80, preferably 0.90 to 1.50) to optimize the formation of polyelectrolyte complexes. By controlling this critical parameter, the invention achieves maximum mending efficacy while ensuring long-lasting repair, directly addressing the reliability-permanence contradiction

Inventive Principle:
Principle #35Parameter changes

2Measurement precision

If existing assessment methods are used, then split end repair is evaluated, but the methodology is inadequate for assessing permanence

Engineering Contradiction:
Improverepair assessment accuracyVSAvoidpermanence detection
Core Design Contradiction:
Measurement precisionVSDifficulty of detecting and measuring

Solution Approach 1:

The patent replaces conventional visual assessment methods with stereomicroscopy for evaluating split end repair. This scientific instrumentation enables precise detection and measurement of repair permanence by allowing detailed observation of fiber structure at microscopic levels, thereby resolving the difficulty in measuring durability

Inventive Principle:
Principle #28Mechanics substitution (Replace mechanical system)

Solution Approach 2:

The patent establishes a systematic assessment methodology that provides feedback on repair effectiveness and permanence. By using stereomicroscopy to objectively measure and evaluate repair outcomes, the method enables continuous improvement and accurate determination of both immediate mending and long-term durability

Inventive Principle:
Principle #23Feedback

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The PEC microgels achieve at least 30% mending before combing and maintain at least 15% durability after combing, providing a high percentage of effective split end repair and improved assessment methodology using stereomicroscopy.

Implementation Method 1

a polyelectrolyte complex (PEC) formed between a cationic polyquaternium polymer and an anionic copolymer at specific charge ratios

Methodology Applied
Scientific EffectElectrostatic attraction: Electrostatics

Implementation Method 2

form a durable seal upon drying, capable of withstanding combing stress

Methodology Applied
Scientific EffectAdhesion: Adhesive

Data Source

PatentUS7837983B2Mending hair damage with polyelectrolyte complexes
Publication Date: 2010.11.23 ISP INVESTMENTS LLC
  • US7837983B2 patent drawing
  • US7837983B2 patent drawing
  • US7837983B2 patent drawing

AI summary

Polyelectrolyte complexes between anionic and cationic polymers are used to mend damaged hair fibers, especially damage exhibited by split ends. An improved test method designed for the assessment of the degree of split end repair is described which consists of tagging hair fibers and observing the repair process by stereomicroscopy.