Polyester Polyamine Corrosion Inhibitors for Metal Surfaces

Solution Overview

Problem

Current corrosion inhibitors for metal surfaces in oil and gas fields lack effective environmental properties, such as biodegradability and low bioaccumulation, while also requiring improved technical performance, especially in stringent regulatory environments.

Innovation Solution

The development of polyesteramine or polyester polyquaternary ammonium compounds through the condensation of fatty acids, dicarboxylic acids, and alkanolamines, with optional quaternization, which are used as corrosion inhibitors for metal surfaces, providing a method to protect metal surfaces from corrosion.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If conventional nitrogen-containing compounds (fatty amines, alkoxylated fatty amines, amidoamines, quarternary ammonium compounds) are used as corrosion inhibitors, then corrosion protection is achieved, but environmental properties (biodegradability, low bioaccumulation) are insufficient

Engineering Contradiction:
Core Design Contradiction:
ReliabilityVSObject-affected harmful factors

Solution Approach 1:

The patent changes the chemical structure parameters by using polyester polyamines and polyester polyquaternary ammonium compounds with specific molecular weights (100-10,000 g/mol) and degrees of polymerization (1-50), which fundamentally alters the environmental properties while maintaining corrosion inhibition effectiveness

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The invention creates composite molecular structures by combining polyester chains with amine or quaternary ammonium groups, resulting in compounds that integrate both the corrosion protection functionality and improved environmental characteristics through their unique polymeric architecture

Inventive Principle:
Principle #40Composite materials

2Reliability

If existing corrosion inhibitors are used in stringent regulatory environments, then corrosion protection is provided, but regulatory compliance regarding environmental properties is insufficient

Engineering Contradiction:
Core Design Contradiction:
ReliabilityVSAdaptability or versatility

Solution Approach 1:

The patent adjusts key parameters including molecular weight (100-10,000 g/mol), degree of polymerization (1-50), and chemical structure to ensure compliance with stringent environmental regulations while preserving corrosion inhibition performance

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The polyester polyamine and polyquaternary ammonium compounds are designed to be biodegradable and environmentally friendly, allowing them to decompose naturally in the environment rather than persisting as harmful substances, thus meeting regulatory requirements for environmental safety

Inventive Principle:
Principle #27Cheap short-living objects (Disposable)

3Object-affected harmful factors

If new polyester polyamine/polyquaternary ammonium compounds are developed to improve environmental properties, then biodegradability and low bioaccumulation are achieved, but technical performance (corrosion inhibition efficacy) must be validated

Engineering Contradiction:
Core Design Contradiction:
Object-affected harmful factorsVSReliability

Solution Approach 1:

The invention develops composite molecular structures combining polyester backbones with nitrogen-containing functional groups, where the polyester framework provides structural stability and the amine/quaternary ammonium groups provide corrosion inhibition activity, achieving both environmental and technical performance goals

Inventive Principle:
Principle #40Composite materials

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

These compounds demonstrate high efficacy in corrosion inhibition, excellent environmental properties, and are effective in a wide range of salt concentrations, offering protection for metal surfaces in harsh environments while meeting regulatory requirements for biodegradability and bioaccumulation.

Implementation Method 1

Different types of nitrogen-containing compounds, such as e.g. fatty amines, alkoxylated fatty amines, amidoamines, and quarternary ammonium compounds, are well-known bases for corrosion inhibitor formulations

Methodology Applied
Scientific EffectAdsorption: Adsorption

Data Source

PatentUS8940227B2Use of polyester polyamine and polyester polyquaternary ammonium compounds as corrosion inhibitors
Publication Date: 2015.01.27
  • US8940227B2 patent drawing
  • US8940227B2 patent drawing
  • US8940227B2 patent drawing

AI summary

The present invention relates to the use of a polyesteramine or a polyester polyquaternary ammonium compound as a corrosion inhibitor for metal surfaces, and to a method for protecting a metal surface from corrosion by contacting the metal surface with said corrosion inhibitor.