Polyether Polymer Terminal Cation for Nanocarbon Dispersion

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Solution Overview

Problem

Nanocarbon materials, such as carbon nanotubes, face challenges in uniform dispersion within polymer materials due to poor affinity, leading to inadequate enhancement of electrical conductivity and mechanical strength in polymer composites.

Innovation Solution

A polyether-based polymer composition incorporating an oxirane monomer unit with a cationic group at one terminal of the polymer chain is used to stabilize and uniformly disperse nanocarbon materials, enhancing their dispersion and conductivity.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Strength

If nanocarbon material is blended into polymer material, then electrical conductivity and mechanical strength are improved, but uniform dispersion is difficult due to poor affinity

Engineering Contradiction:
Improvemechanical strengthVSAvoiduniform dispersion
Core Design Contradiction:
StrengthVSStability of the object's composition

Solution Approach 1:

The patent modifies the chemical structure of the polymer by introducing a cationic group at the terminal position, changing the electrical charge parameter of the polymer chain. This parameter change enables electrostatic interaction with the nanocarbon material, resolving the affinity problem and achieving uniform dispersion while maintaining mechanical strength enhancement.

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The cationic group acts as an intermediary between the polymer matrix and the nanocarbon material. It mediates the interaction by providing a chemical bridge that enhances compatibility and dispersion of the nanocarbon material within the polymer, solving the affinity issue without compromising the reinforcing effect.

Inventive Principle:
Principle #24Intermediary (Mediator)

2Reliability

If nanocarbon material is blended into polymer material, then electrical conductivity is improved, but uniform dispersion is difficult due to poor affinity

Engineering Contradiction:
Improveelectrical conductivityVSAvoiduniform dispersion
Core Design Contradiction:
ReliabilityVSStability of the object's composition

Solution Approach 1:

By introducing a cationic group at the polymer terminal, the electrical charge parameter is modified, enabling electrostatic attraction to the nanocarbon material. This parameter change ensures both uniform dispersion and effective electrical conductivity enhancement by maximizing the interaction between polymer and nanocarbon material.

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent creates a composite system where the polymer with cationic terminal group and nanocarbon material form a synergistic combination. The cationic-modified polymer composite achieves both uniform dispersion and high electrical conductivity by combining the structural benefits of the polymer matrix with the conductive properties of nanocarbon material enhanced by electrostatic interaction.

Inventive Principle:
Principle #40Composite materials

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The polyether-based polymer composition effectively disperses nanocarbon materials, improving electrical conductivity and mechanical strength in polymer composites, making them suitable for various applications.

Implementation Method 1

a polyether-based polymer including an oxirane monomer unit and having one cationic group substantially only at one terminal of a polymer chain

Methodology Applied
Scientific EffectElectrostatic attraction: Ion Repulsion/Attraction

Data Source

PatentEP3275937B1Polyether-based polymer composition
Publication Date: 2020.01.08 ZEON CORP
  • EP3275937B1 patent drawingFigure 1
  • EP3275937B1 patent drawing
  • EP3275937B1 patent drawing

AI summary

The present invention is a polyether-based polymer composition comprising; a polyether-based polymer including an oxirane monomer unit and having one cationic group substantially only at one terminal of a polymer chain, and a nanocarbon material. The polyether-based polymer composition of the present invention can be suitably used, (e.g.,) as a bucky gel or as a master batch for preparing a nanocarbon material aqueous dispersion in which a nanocarbon material is favorably dispersed.