Polyether Polyester Dye Transfer Inhibition

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Solution Overview

Problem

Conventional detergents often cause dye transfer from dyed textiles to undyed or differently colored textiles during washing, leading to unwanted color changes and losses, due to the high affinity of polymers for dyes.

Innovation Solution

The use of polyether polyesters, synthesized by reacting dicarboxylic compounds, polyol compounds with multiple hydroxyl groups, water-soluble alkylene oxide addition products, and diol compounds, which are incorporated into detergents to inhibit dye transfer by forming a repellent action on dye molecules during the washing process.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Object-affected harmful factors

If conventional polymers with high affinity for dyes are used in detergents, then dye transfer inhibition should be improved, but actually greater colour losses occur from washed textiles

Engineering Contradiction:
Improvedye transfer inhibitionVSAvoidcolour loss
Core Design Contradiction:
Object-affected harmful factorsVSLoss of substance

Solution Approach 1:

The patent changes the chemical parameters of the polymer by specifying precise compositional ratios: 20-50 mole% dicarboxylic acid, 10.1-50 mole% polyol with at least 3 OH-groups, 10.1-50 mole% alkylene oxide addition product, and 0-30 mole% diol. These parameter changes create a polymer with optimized dye interaction properties that inhibit transfer without causing excessive colour loss.

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The invention uses a composite polymer structure combining multiple functional components: dicarboxylic acid units, polyol units with multiple hydroxyl groups, alkylene oxide addition products, and diol units. This composite material approach creates a detergent additive with balanced properties for dye transfer inhibition while minimizing harmful effects on textile coloration.

Inventive Principle:
Principle #40Composite materials

2Stability of the object's composition

If polymers are added to detergents to prevent dye dissolution and deposition, then colour appearance stability should be improved, but the complexity of detergent formulation increases

Engineering Contradiction:
Improvecolour appearance stabilityVSAvoiddetergent formulation complexity
Core Design Contradiction:
Stability of the object's compositionVSDevice complexity

Solution Approach 1:

The polymer composition serves multiple functions simultaneously: it acts as a dye transfer inhibitor, a washing auxiliary, and a color protection agent. The same compositional formula (with specified ranges of dicarboxylic acid, polyol, alkylene oxide addition product, and diol) provides comprehensive color protection throughout the washing process, reducing the need for multiple separate additives.

Inventive Principle:
Principle #6Universality (Multi-functionality)

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The polyether polyesters effectively reduce dye transfer and fading, maintaining color consistency, particularly when washing cotton and synthetic fibers, with a pronounced effect on preventing staining of white textiles.

Implementation Method 1

It is conceivable that the polyether polyesters attach themselves to the textiles during washing and have a repellent action on the dye molecules present in the liquor.

Methodology Applied
Scientific EffectAdsorption: Adsorption

Implementation Method 2

have a repellent action on the dye molecules present in the liquor

Methodology Applied
Scientific EffectRepellent action: Hydrophobe

Data Source

PatentEP3680317B1Colour protection detergents
Publication Date: 2022.08.24 HENKEL KGAA
  • EP3680317B1 patent drawing

AI summary

The present invention improves dye transfer inhibition in the washing of textiles by the use of suitable polyether polyesters.