Polyether-Polyol Dendrimer Trapping Pollutants

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Solution Overview

Problem

Current dendrimers synthesized from renewable resources have limited trapping capacity for chemical compounds, particularly pollutants, while also posing cytotoxicity and ecotoxicity concerns.

Innovation Solution

Development of polyether-polyol type dendrimer compounds of generation (n) with a central glycerol unit and specific structural layers, capable of trapping pollutants through reversible interactions, allowing for recycling and improved environmental compatibility.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Object-affected harmful factors

If dendrimers are synthesized from renewable resources (glycerol, polyether-polyol derivatives), then environmental compatibility (low cytotoxicity and ecotoxicity) is improved, but trapping capacity for chemical compounds deteriorates

Engineering Contradiction:
Improvecytotoxicity and ecotoxicityVSAvoidtrapping capacity
Core Design Contradiction:
Object-affected harmful factorsVSQuantity of substance

Solution Approach 1:

The patent changes the chemical structure parameters of the dendrimer by incorporating polyether-polyol derivatives with specific molecular weights (200-2000 g/mol) and controlling the generation number (n=1-12). This structural parameter optimization enables the dendrimer to achieve both low toxicity and high trapping capacity through improved cavity formation and functional group arrangement

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The invention creates a composite dendrimer structure combining polyether-polyol derivatives with specific architectural features (central unit, internal generation layers, outer layer). This composite approach integrates the biocompatibility of renewable resources with the trapping efficiency of optimized dendritic architecture, resolving the contradiction between environmental safety and functional performance

Inventive Principle:
Principle #40Composite materials

2Ease of operation

If dendrimers are modified at the periphery by hydrophilic entities from agro-resources, then physiological tolerance and water solubility are improved, but trapping capacity deteriorates

Engineering Contradiction:
Improvewater solubility and physiological toleranceVSAvoidtrapping capacity
Core Design Contradiction:
Ease of operationVSQuantity of substance

Solution Approach 1:

The patent applies local quality by differentiating the functional characteristics of different dendrimer regions. The polyether-polyol derivative structure provides hydrophilic peripheral groups for solubility and biocompatibility, while the internal dendritic architecture maintains cavity structures for effective trapping. This spatial differentiation of functions resolves the contradiction between solubility enhancement and trapping capacity preservation

Inventive Principle:
Principle #3Local quality

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

These dendrimer compounds demonstrate enhanced trapping capacities for metals and organic pollutants with low cytotoxicity and ecotoxicity, enabling effective pollutant removal and potential recycling in environmental applications.

Implementation Method 1

capable of trapping pollutants through reversible interactions, allowing for recycling and improved environmental compatibility

Methodology Applied
Scientific EffectReversible interactions: Absorption (physical)

Data Source

PatentEP3826985B1Dendrimer-type compounds, methods for producing same, and uses thereof
Publication Date: 2022.05.04 UNIV DE REIMS CHAMPAGNE ARDENNE
  • EP3826985B1 patent drawingFigure 1~2
  • EP3826985B1 patent drawing
  • EP3826985B1 patent drawing

AI summary

The present invention relates to the use of compounds of the generation (n) dendrimer type or the salts thereof, comprising: a central unit of valency 3 having formula (I), (n-1) inner generation layers consisting of repeat units having formula (II) and arranged in a tree structure around the central unit, and an outer layer consisting of units represented by formula (III), with n being an integer between 1 and 12, for trapping at least one chemical compound contained in a liquid sample.